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US4882083A Expired / Lapsed US ⏱️ 0.0 years remaining

Smectic liquid crystal mixture

Assignee: JNC Corp
•
Filing: 1988-05-27
•
Granted: 1989-11-21
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Expires: 2008-05-27
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Abstract

Abstract A smectic liquid crystal mixture having a broad smectic C phase temperature range including room temperature, a ferroelectric smectic liquid crystal mixture having a large spontaneous polarization, comprising the above smectic mixture and at least one optically active compound, and a liquid crystal display element having an improved response time, containing the above ferroelectric smectic liquid crystal mixture are provided, which smectic liquid crystal mixture comprises (1) at least two components at least one of which is a pyrimidine compound expressed by the formula <CHEM> wherein R<1> and R<2> each are a linear alkyl group having 1 -20 carbons; (2) at least one pyrimidine compound of the formula (I) and at least one pyrimidine compound expressed by the formula <CHEM> wherein R<3> and R<4> each are a linear alkyl group having 1 - 18 carbons; or (3) at least one pyrimidine compound of the formula (I) and at least one biphenylpyrimidine compound expressed by the formula <CHEM> wherein R<5> and R<6> each are a linear alkyl or alkoxy group each having 1 - 18 carbons. s

Inventors

  • 👤 Kanetsugu Terashima
  • 👤 Mitsuyoshi Ichihashi
  • 👤 Fusayuki Takeshita
  • 👤 Makoto Kikuchi
  • 👤 Kenji Furukawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 12:04
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/04; C09K19/06; C09K19/34; C09K19/3441; C09K19/345; C09K19/3458

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 58 words
A smectic C liquid crystal mixture comprising at least two components at least one of which is a 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase.
Claim 2
Dependent Claim 58 words
A smectic C liquid crystal mixture comprising at least two components at least one of which is a 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase.
Claim 3
Dependent Claim 96 words
A smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR100## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase; and at least one 5-alkyl-2-(4-alkoxyphenyl)pyrimidine compound expressed by the formula ##STR101## wherein R 3 represents a linear alkyl group of 6 to 12 carbon atoms and R 4 represents a linear alkyl group of 8 to 11 carbon atoms and having a smectic C phase.
Claim 4
Dependent Claim 96 words
A smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR100## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase; and at least one 5-alkyl-2-(4-alkoxyphenyl)pyrimidine compound expressed by the formula ##STR101## wherein R 3 represents a linear alkyl group of 6 to 12 carbon atoms and R 4 represents a linear alkyl group of 8 to 11 carbon atoms and having a smectic C phase.
Claim 5
Dependent Claim 87 words
A smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR102## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase; and at least one biphenylpyrimidine compound expressed by the formula ##STR103## wherein R 5 and R 6 each represent the same or different linear alkyl group or alkoxy group each of 1 to 18 carbon atoms.
Claim 6
Dependent Claim 87 words
A smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR102## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase; and at least one biphenylpyrimidine compound expressed by the formula ##STR103## wherein R 5 and R 6 each represent the same or different linear alkyl group or alkoxy group each of 1 to 18 carbon atoms.
Claim 7
Dependent Claim 59 words
A ferroelectric smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR104## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase; and at least one optically active compound.
Claim 8
Dependent Claim 59 words
A ferroelectric smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR104## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase; and at least one optically active compound.
Claim 9
Dependent Claim 103 words
A ferroelectric smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR105## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase; at least one 5-alkyl-2-(4-alkoxyphenyl)pyrimidine compound expressed by the formula ##STR106## wherein R 3 represents a linear alkyl group of 6 to 12 carbon atoms and R 4 represents a linear alkyl group of 8 to 11 carbon atoms and having a smectic C phase; and at least one optically active compound.
Claim 10
Dependent Claim 103 words
A ferroelectric smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR105## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase; at least one 5-alkyl-2-(4-alkoxyphenyl)pyrimidine compound expressed by the formula ##STR106## wherein R 3 represents a linear alkyl group of 6 to 12 carbon atoms and R 4 represents a linear alkyl group of 8 to 11 carbon atoms and having a smectic C phase; and at least one optically active compound.
Claim 11
Dependent Claim 93 words
A ferroelectric smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR107## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase; at least one biphenylpyrimidine compound expressed by the formula ##STR108## wherein R 5 and R 6 each represent the same or different linear alkyl group or alkoxy group each of 1 to 18 carbon atoms; at least one optically active compound.
Claim 12
Dependent Claim 93 words
A ferroelectric smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR107## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase; at least one biphenylpyrimidine compound expressed by the formula ##STR108## wherein R 5 and R 6 each represent the same or different linear alkyl group or alkoxy group each of 1 to 18 carbon atoms; at least one optically active compound.
Claim 13
Dependent Claim 65 words
A liquid crystal display element containing a ferroelectric smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR109## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase, and at least one optically active compound.
Claim 14
Dependent Claim 65 words
A liquid crystal display element containing a ferroelectric smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR109## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase, and at least one optically active compound.
Claim 15
Dependent Claim 108 words
A liquid crystal display element containing a ferroelectric smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR110## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase; at least one 5-alkyl-2-(4-alkoxyphenyl)pyrimidine expressed by the formula ##STR111## wherein R 3 represents a linear alkyl group of 6 to 12 carbon atoms and R 4 represents a linear alkyl group of 8 to 11 carbon atoms and having a smectic C phase; and at least one optically active compound.
Claim 16
Dependent Claim 108 words
A liquid crystal display element containing a ferroelectric smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR110## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase; at least one 5-alkyl-2-(4-alkoxyphenyl)pyrimidine expressed by the formula ##STR111## wherein R 3 represents a linear alkyl group of 6 to 12 carbon atoms and R 4 represents a linear alkyl group of 8 to 11 carbon atoms and having a smectic C phase; and at least one optically active compound.
Claim 17
Dependent Claim 100 words
A liquid crystal display element containing a ferroelectric smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR112## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase; at least one biphenylpyrimidine compound expressed by the formula ##STR113## wherein R 5 and R 6 each represent the same or different linear alkyl group or alkoxy group each of 1 to 18 carbon atoms; and at least one optically active compound.
Claim 18
Dependent Claim 100 words
A liquid crystal display element containing a ferroelectric smectic C liquid crystal mixture comprising at least one 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR112## wherein R 1 represents a linear alkyl group of 4 to 20 carbon atoms and R 2 represents a linear alkyl group of 7 to 20 carbon atoms, and having a smectic C phase; at least one biphenylpyrimidine compound expressed by the formula ##STR113## wherein R 5 and R 6 each represent the same or different linear alkyl group or alkoxy group each of 1 to 18 carbon atoms; and at least one optically active compound.
Claim 19
Dependent Claim 22 words
A smectic C liquid crystal mixture according to claim 3 wherein R 5 and R 6 contain 5 to 10 carbon atoms.
Claim 20
Dependent Claim 22 words
A smectic C liquid crystal mixture according to claim 3 wherein said at least one biphenylpyrimidine compound has a smectic C phase.
Claim 21
Dependent Claim 23 words
A ferroelectric smectic C liquid crystal mixture according to claim 6 wherein R 5 and R 6 contain 5 to 10 carbon atoms.
Claim 22
Dependent Claim 23 words
A ferroelectric smectic C liquid crystal mixture according to claim 6 wherein said at least one biphenylpyrimidine compound has a smectic C phase.
Claim 23
Dependent Claim 21 words
A liquid crystal display element according to claim 9 wherein R 5 and R 6 contain 5 to 10 carbon atoms.
Claim 24
Dependent Claim 21 words
A liquid crystal display element according to claim 9 wherein said at least one biphenylpyrimidine compound has a smectic C phase.

References Cited (Backward Citations)

DE2257588A1 Cited
JPS59199786A Cited
US4725688A Cited
US4780241A Cited
WO1986006401A1 Cited
EP0206228A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-11-20 1993-05-22 1993-11-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-11-20 1997-05-22 1997-11-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-11-20 2001-05-22 2001-11-21 $7700.00 Window Closed / Lapsed

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