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US4880599A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of making a ferrite composite containing silver metallization

Assignee: General Electric Co
•
Filing: 1988-03-25
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Granted: 1989-11-14
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Expires: 2008-03-25
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Abstract

Abstract A composite comprised of a sintered matrix of spinel ferrite and an electrically conductive phase of elemental silver is produced by co-firing a laminated structure of ferrite powder-containing tapes containing a silver metallization-forming material having two end portions wherein only the end portions are exposed.

Inventors

  • 👤 Richard J. Charles
  • 👤 Achuta R. Gaddipati

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 17:28
CPC Classifications
C; C04; C04B; C04B41/00; C04B41/009; C04B35/00; C04B35/01; C04B35/26; C04B35/2608; C04B41/45; C04B41/50; C04B41/51; C04B41/5194; C04B41/80; C04B41/81; C04B41/85; C04B41/88; C04B2111/00; C04B2111/00474; C04B2111/00844

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 256 words
A process for producing a solid composite comprised of a ferrite matrix containing a continuous silver metallization with only its end portions exposed to the ambient, said ferrite matrix having an electrical resistivity greater than 500 ohm-centimeters at a temperature ranging from about 20° C. to about 100° C., which comprises: (a) providing a ferrite powder; (b) admixing said ferrite powder with an organic binding material; (c) forming the resulting mixture into tape; (d) providing a silver metallization-forming material; (e) forming a layered structure of at least two of said tapes containing said silver metallization-forming material therewithin in a pattern with two end portions, said metallization-forming material being present in an amount sufficient to produce said silver metallization; (f) laminating the layered structure and forming a laminated structure wherein only said end portions of said pattern are exposed; (g) firing said laminated structure to thermally decompose its organic component at an elevated temperature below about 600° C. leaving no significant deleterious residue, said firing being carried out in an atmosphere or vacuum which has no significant deleterious effect on said composite; (h) sintering the resulting structure at a temperature ranging from about 1000° C. to about 1400° C. in an oxygen-containing atmosphere to produce a sintered product having the composition of said composite; and (i) cooling said sintered product to produce said composite, said sintering and cooling being carried out in an atmosphere which has no significant deleterious effect on said composite, said ferrite powder having a composition which forms said ferrite matrix in said process.
Claim 2
Dependent Claim 256 words
A process for producing a solid composite comprised of a ferrite matrix containing a continuous silver metallization with only its end portions exposed to the ambient, said ferrite matrix having an electrical resistivity greater than 500 ohm-centimeters at a temperature ranging from about 20° C. to about 100° C., which comprises: (a) providing a ferrite powder; (b) admixing said ferrite powder with an organic binding material; (c) forming the resulting mixture into tape; (d) providing a silver metallization-forming material; (e) forming a layered structure of at least two of said tapes containing said silver metallization-forming material therewithin in a pattern with two end portions, said metallization-forming material being present in an amount sufficient to produce said silver metallization; (f) laminating the layered structure and forming a laminated structure wherein only said end portions of said pattern are exposed; (g) firing said laminated structure to thermally decompose its organic component at an elevated temperature below about 600° C. leaving no significant deleterious residue, said firing being carried out in an atmosphere or vacuum which has no significant deleterious effect on said composite; (h) sintering the resulting structure at a temperature ranging from about 1000° C. to about 1400° C. in an oxygen-containing atmosphere to produce a sintered product having the composition of said composite; and (i) cooling said sintered product to produce said composite, said sintering and cooling being carried out in an atmosphere which has no significant deleterious effect on said composite, said ferrite powder having a composition which forms said ferrite matrix in said process.
Claim 3
Dependent Claim 12 words
The process according to claim 1 which is carried out in air.
Claim 4
Dependent Claim 18 words
The process according to claim 1 wherein said silver metallization-forming material is comprised of particulates of elemental silver.
Claim 5
Dependent Claim 20 words
The process according to claim 1 wherein said silver metallization-forming material is comprised of a solid body of elemental silver.
Claim 6
Dependent Claim 25 words
The process according to claim 1 wherein said ferrite matrix has a porosity ranging from about 5% to about 30% by volume of said matrix.
Claim 7
Dependent Claim 20 words
The process according to claim 1 wherein in said layered structure only the end portions of said pattern are exposed.
Claim 8
Dependent Claim 58 words
The process according to claim 1 wherein said ferrite matrix has a composition comprised of MO(Fe 2 O 3 ) 1 ±x where x has a value ranging from 0 to about 0.2 and where M is a divalent metal cation selected from the group consisting of Mg, Mn, Fe, Co, Ni, Zn, Cu and a combination thereof.
Claim 9
Dependent Claim 17 words
The process according to claim 1 wherein x has a value ranging from 0 to about 0.1.
Claim 10
Dependent Claim 22 words
The process according to claim 1 wherein before said firing, said laminated structure is shaped into a simple, hollow and/or complex form.
Claim 11
Dependent Claim 23 words
The process according to claim 1 wherein before said firing, said laminated structure is wound into a coil in substantially a single plane.
Claim 12
Dependent Claim 20 words
The process according to claim 1 wherein said laminated structure is wound into a spiral in a plurality of planes.
Claim 13
Dependent Claim 25 words
The process according to claim 1 wherein said laminated structure contains a plurality of said patterns, each of said patterns being separate from the other.
Claim 14
Dependent Claim 19 words
The process according to claim 1 wherein said sintering temperature ranges from about 1100° C. to about 1300° C.
Claim 15
Dependent Claim 31 words
The process according to claim 1 wherein before said firing, said laminated structure is placed in a container open to the atmosphere only sufficiently to enable the production of said composite.

References Cited (Backward Citations)

US3988498A Cited
US3996085A Cited
US4546037A Cited
US4548862A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-11-13 1993-05-15 1993-11-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-11-13 1997-05-15 1997-11-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-11-13 2001-05-15 2001-11-14 $7700.00 Window Closed / Lapsed

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