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US4879253A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for fabricating a semiconductor device using a BPSG layer containing high concentrations of phosphorus and boron

Assignee: Oki Electric Industry Co Ltd
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Filing: 1988-09-27
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Granted: 1989-11-07
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Expires: 2008-09-27
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Abstract

Abstract A method for forming a smooth borophosphosilicate glass film on a semiconductor substrate is described, in which a semiconductor substrate having at least one stepped portion thereon is formed with one side of the substrate a borophosphosilicate glass layer having a defined boron content and a defined phosphorus content with a defined total content of the boron and phosphorus. The layer is subjected to thermal treatment under conditions of a temperature of not lower than 940° C. and a time of not shorter than 15 minutes in an atmospheric gas supplied at a flow rate of not lower than 19 liters/minute. As a result, the BPSG glass layer is smoothed on the surface thereof without formation of undesirable grains on the surface. This thermal treatment is particularly suitable for fabrication of a semiconductor element or device using an insulating film of the borophosphosilicate glass.

Inventors

  • 👤 Hidetoshi Wakamatsu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 05:08
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/69; H10P14/692; H10P14/6921; H10P14/6922; H10P14/6923; H10P14/65; H10P14/6516; H10P14/6529; H10W; H10W20/00; H10W20/01; H10W20/071; H10W20/092; Y; Y10; Y10S; Y10S148/00; Y10S148/133

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 148 words
A method for forming a smooth borophospholisilicate glass film on a semiconductor substrate, the method comprising the steps of: (a) providing a semiconductor substrate having at least one stepped portion thereon; (b) forming on one side of the substrate a borophosphosilicate glass layer having a boron content of about 2 to 5 wt % and a phosphorus content of about from 5 to 8 wt % provided that the total content of the boron and phosphorus is in the range of from 7 to 10 wt %; and (c) subjecting the layer to thermal treatment under conditions of a temperature of not lower than 940° C. and a time of not shorter than 15 minutes in an atmospheric gas supplied at flow rate of not lower than 19 liters/minute whereby the silicate glass layer is smoothed on the surface thereof without formation of undesirable grains on the surface.
Claim 2
Independent Claim 148 words
A method for forming a smooth borophospholisilicate glass film on a semiconductor substrate, the method comprising the steps of: (a) providing a semiconductor substrate having at least one stepped portion thereon; (b) forming on one side of the substrate a borophosphosilicate glass layer having a boron content of about 2 to 5 wt % and a phosphorus content of about from 5 to 8 wt % provided that the total content of the boron and phosphorus is in the range of from 7 to 10 wt %; and (c) subjecting the layer to thermal treatment under conditions of a temperature of not lower than 940° C. and a time of not shorter than 15 minutes in an atmospheric gas supplied at flow rate of not lower than 19 liters/minute whereby the silicate glass layer is smoothed on the surface thereof without formation of undesirable grains on the surface.
Claim 3
Dependent Claim 165 words
A method for forming a smooth borophosphosilicate glass film on a semiconductor substrate according to claim 1, wherein the thermal treatment comprises the steps of: (a) thermally treating the borophosphosilicate glass layer at a temperature of approximately 800° C. for 5 minutes in an atmosphere of N 2 at a flow rate of not lower than 19 liters/minute; (b) heating the borophosphosilicate glass layer at a rate of about 5° C./minute from 800° C. to 950° C. in an atmosphere of O 2 at a flow rate of not lower than about 19 liters/minute; (c) keeping the thus heated borophosphosilicate glass layer at 950° C. for at least in an atmosphere of N 2 at a flow rate of not lower than 19 liters/minute; and (d) cooling the borophosphosilicate glass layer from 950° C. to 800° C. at a cooling rate of about 2.5° C./minute and keeping at 800° C. for at least 5 minutes to make a borophosphosilicate glass layer with a smooth surface.
Claim 4
Dependent Claim 37 words
A method for forming a smooth borophosphosilicate glass film on a semiconductor substrate according to claim 1, wherein the borophosphosilicate glass layer has a boron content of 3 wt % and phosphorus content of 7 wt %.
Claim 5
Dependent Claim 25 words
A method for forming a smooth borophosphosilicate glass film on a semiconductor substrate according to claim 1, wherein the atmospheric gas is a nitrogen gas.
Claim 6
Dependent Claim 25 words
A method for forming a smooth borophosphosilicate glass film on a semiconductor substrate according to claim 1, wherein the atmospheric gas is an oxygen gas.
Claim 7
Independent Claim 226 words
A method for fabricating a semiconductor device including an insulating borophosphosilicate glass layer, the method comprising the steps of: (a) providing a semiconductor substrate having an element region and a separation region thereon by formation of a thermally oxidized SiO 2 film; (b) forming a gate insulating film on the element region; (c) forming a first conductive layer over the construction obtained in the above step; (d) removing the first conductive layer and the gate insulating layer selectively to expose part of the substrate; (e) forming a diffusion layer on the exposed portions of the semiconductor substrate; (f) forming, over the entire surface of the substrate obtained the above step, a borophosphosilicate glass layer which contains about 2 to 5 wt % of boron and about 5 to 8 wt % of phosphorus provided that the total content is in the range of from 7 to 10 wt %; (g) subjecting the substrate to thermal treatment at a temperature of not lower than 940° C. format least 15 minutes in an atmospheric gas supplied at a flow rate of not lower than 19 liters/minute so that the borophosphosilicate glass layer becomes smooth on the surface thereof without formation of undesirable grains on the surface; (h) forming an opening in the smooth borophosphosilicate layer; and (i) forming a second conductive layer on a region including the opening.
Claim 8
Independent Claim 226 words
A method for fabricating a semiconductor device including an insulating borophosphosilicate glass layer, the method comprising the steps of: (a) providing a semiconductor substrate having an element region and a separation region thereon by formation of a thermally oxidized SiO 2 film; (b) forming a gate insulating film on the element region; (c) forming a first conductive layer over the construction obtained in the above step; (d) removing the first conductive layer and the gate insulating layer selectively to expose part of the substrate; (e) forming a diffusion layer on the exposed portions of the semiconductor substrate; (f) forming, over the entire surface of the substrate obtained the above step, a borophosphosilicate glass layer which contains about 2 to 5 wt % of boron and about 5 to 8 wt % of phosphorus provided that the total content is in the range of from 7 to 10 wt %; (g) subjecting the substrate to thermal treatment at a temperature of not lower than 940° C. format least 15 minutes in an atmospheric gas supplied at a flow rate of not lower than 19 liters/minute so that the borophosphosilicate glass layer becomes smooth on the surface thereof without formation of undesirable grains on the surface; (h) forming an opening in the smooth borophosphosilicate layer; and (i) forming a second conductive layer on a region including the opening.
Claim 9
Dependent Claim 161 words
A method for fabricating a semiconductive device including an insulating borophosphosilicate glass layer according to claim 6, wherein the thermal treatment comprises the steps of: (a) thermally treating the borophosphosilicate glass layer-bearing substrate at a temperature of approximately 800° C. for 5 minutes in an atmosphere of N 2 at a flow rate of not lower than 19 liters/minute; (b) heating the substrate at a rate of about 5° C./minute from 800° C. to 950° C. in an atmosphere of O 2 at a flow rate of not lower than 19 liters/minute; (c) keeping the thus heated substrate at 950° C. for at least 15 minutes in an atmosphere of N 2 at a flow rate of not lower than 19 liters/minute; and (d) cooling the substrate from 950° C. to 800° C. at a cooling rate of about 2.5° C./minute and keeping at 800° C. for at least 5 minutes to make the borophosphosilicate glass layer with a smooth surface.
Claim 10
Dependent Claim 38 words
A method for fabricating a semiconductive device including an insulating borophosphosilicate glass layer according to claim 6, where in the first conductive layer includes a polycrystalline silicon layer to which phosphorus is added and a tungsten silicide layer.
Claim 11
Dependent Claim 46 words
A method for fabricating a semiconductive device including an insulating borophosphosilicate glass layer according to claim 6, wherein the borophosphosilicate glass layer is formed from SiH 4 , PH 3 , B 2 H 6 , and O 2 by a normal vapor phase growth technique.
Claim 12
Dependent Claim 29 words
A method for fabricating a semiconductive device including an insulating borophosphosilicate glass layer according to claim 6, wherein the borophosphosilicate glass layer has a thickness of about 7000 angstroms.

References Cited (Backward Citations)

US4535528A Cited
US4740480A Cited
US4740483A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-11-06 1993-05-08 1993-11-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-11-06 1997-05-08 1997-11-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-11-06 2001-05-08 2001-11-07 $7700.00 Window Closed / Lapsed

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