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US4877858A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid-crystalline polymer

Assignee: Idemitsu Kosan Co Ltd
•
Filing: 1988-11-16
•
Granted: 1989-10-31
•
Expires: 2008-11-16
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Abstract

Abstract A liquid-crystalline polymer comprising the repeating units of the general formula (I) ##STR1## in which: k is an integer from 1 to 30; and R 1 is ##STR2## where: X is --COO-- or --OCO--; and R 2 is --COOR 3 , OCOR 3 , or --OR 3 where: R 3 is ##STR3## R 4 and R 5 being each independently --CH 3 , a halogen radical, or --CN, m and n being each independently an integer from 0 to 10 with the proviso that n is not 0 when R 4 is --CH 3 , p being 0 or 1, and C marked with * being an asymmetric carbon atom. The polymers of the present invention exhibit a ferroelectricity even at temperatures around room temperature and as well such a high speed of response to external factors that they can be used for displaying motion pictures, and the polymers may also be advantageously used as display elements for large displays or curved displays.

Inventors

  • 👤 Satoshi Hachiya
  • 👤 Shunji Uchida
  • 👤 Kenji Hashimoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 05:49
CPC Classifications
C; C08; C08G; C08G65/00; C08G65/02; C08G65/04; C08G65/22; C09; C09K; C09K19/00; C09K19/04; C09K19/38; C09K19/3833; C09K19/3876; C09K19/388

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 104 words
A ferroelectric liquid-crystalline polymer comprising the repeating units of the general formula (I) ##STR140## in which: k is an interger from 1 to 30; and ##STR141## where: X is --COO-- or --OCO--; and R 2 is --COOR 3 , or --OR 3 where: R 3 is ##STR142## R 4 and R 5 being each independently --CH 3 , a halogen radical, or --CN, m and n being each independently an integer from 0 to 10 with the proviso that n is not 0 when R 4 is --CH 3 , p being 0 or 1, and C marked with being an asymmetric carbon atom.
Claim 2
Dependent Claim 104 words
A ferroelectric liquid-crystalline polymer comprising the repeating units of the general formula (I) ##STR140## in which: k is an interger from 1 to 30; and ##STR141## where: X is --COO-- or --OCO--; and R 2 is --COOR 3 , or --OR 3 where: R 3 is ##STR142## R 4 and R 5 being each independently --CH 3 , a halogen radical, or --CN, m and n being each independently an integer from 0 to 10 with the proviso that n is not 0 when R 4 is --CH 3 , p being 0 or 1, and C marked with being an asymmetric carbon atom.
Claim 3
Dependent Claim 22 words
The ferroelectric liquid-crystalline polymer of claim 1 wherein the number average molecular weight of the liquid-crystalline polymer is from 2,000 to 400,000.
Claim 4
Dependent Claim 26 words
The ferroelectric liquid-crystalline polymer of claim 1 wherein the number average molecular weight of the liquid-crystalline polymer is less than 2,000 and not less than 1,000.
Claim 5
Dependent Claim 18 words
The ferroelectric liquid-crystalline polymer of claims 2 or 3 wherein k is an integer from 4 to 10.
Claim 6
Dependent Claim 20 words
The ferroelectric liquid-crystalline polymer of claims 2 or 3 wherein R 1 is selected from the group consisting of ##STR143##
Claim 7
Dependent Claim 20 words
The ferroelectric liquid-crystalline polymer of claims 2 or 3 wherein R 3 is selected from the group consisting of ##STR144##
Claim 8
Dependent Claim 17 words
The ferroelectric liquid-crystalline polymer of claim 1, wherein k is an integre of from 4 to 10.
Claim 9
Dependent Claim 29 words
The ferroelectric liquid-crystalline polymer of claim 1 wherein R 1 is selected from the group consisting of ##STR145## and R 3 is selected from the group consisting of ##STR146##
Claim 10
Dependent Claim 32 words
The ferroelectric liquid-crystalline polymer of claim 2 or claim 3 wherein R 1 is selected from the group consisting of ##STR147## and R 3 is selected from the group consisting of ##STR148##
Claim 11
Dependent Claim 16 words
The ferroelectric liquid-crystalline polymer of claim 1 comprising the repeating units of the following formula ##STR149##
Claim 12
Dependent Claim 16 words
The ferroelectric liquid-crystalline polymer of claim 1 comprising the repeating units of the following formula ##STR150##
Claim 13
Dependent Claim 16 words
The ferroelectric liquid-crystalline polymer of claim 1 comprising the repeating units of the following formula ##STR151##
Claim 14
Dependent Claim 16 words
The ferroelectric liquid-crystalline polymer of claim 1 comprising the repeating units of the following formula ##STR152##
Claim 15
Dependent Claim 16 words
The ferroelectric liquid-crystalline polymer of claim 1 comprising the repeating units of the following formula ##STR153##
Claim 16
Dependent Claim 16 words
The ferroelectric liquid-crystalline polymer of claim 1 comprising the repeating units of the following formula ##STR154##
Claim 17
Dependent Claim 16 words
The ferroelectric liquid-crystalline polymer of claim 1 comprising the repeating units of the following formula ##STR155##
Claim 18
Dependent Claim 16 words
The ferroelectric liquid-crystalline polymer of claim 1 comprising the repeating units of the following formula ##STR156##
Claim 19
Dependent Claim 16 words
The ferroelectric liquid-crystalline polymer of claim 1 comprising the repeating units of the following formula ##STR157##
Claim 20
Dependent Claim 16 words
The ferroelectric liquid-crystalline polymer of claim 1 comprising the repeating units of the following formula ##STR158##
Claim 21
Dependent Claim 16 words
The ferroelectric liquid-crystalline polymer of claim 1 comprising the repeating units of the following formula ##STR159##
Claim 22
Dependent Claim 16 words
the ferroelectric liquid-crystalline polymer of claim 1 comprising the repeating units of the following formula ##STR160##
Claim 23
Dependent Claim 16 words
The ferroelectric liquid-crystalline polymer of claim 1 comprising the repeating units of the following formula ##STR161##
Claim 24
Dependent Claim 16 words
The ferroelectric liquid-crystalline polymer of claim 1 comprising the repeating units of the following formula ##STR162##

References Cited (Backward Citations)

US4728458A Cited
EP0231770A2 Cited
US4762912A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-10-30 1993-05-01 1993-10-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-10-30 1997-05-01 1997-10-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-10-30 2001-05-01 2001-10-31 $7700.00 Window Closed / Lapsed

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