US4877704A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for developing latent electrostatic image using toner containing polyester resin
Assignee: Konica Minolta Inc
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Filing: 1988-04-28
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Granted: 1989-10-31
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Expires: 2008-04-28
Abstract
Abstract Toner for developing an electrostatic latent image comprising (a) a polyester resin of a non-linear copolymer having, as its side chain, an aliphatic hydrocarbon group containing therein 3 to 22 carbon atoms, said copolymer being obtained from polymerization of an etherified bisphenol monomer, a di-carboxilic acid monomer, and a polyhydric alcohol of tri-hydric or more and/or a monomer component containing a polycarboxylic acid monomer of tricarboxylic acid or more carboxylic or more, and at least one compound selected from the group consisting of (b) an alkylene-bis-aliphatic acid amide compound represented by the general formula; ##STR1## wherein R 1 and R 2 are independently selected from saturated or unsaturated aliphatic hydrocarbon groups having not less than 10 carbon atoms, R 3 and R 4 are independently selected from a hydrogen atom and a group represented by --OCR 5 wherein R 5 is a saturated or unsaturated hydrocarbon group and n is a positive integer and (c) a wax containing not less than 20% by weight of ester component, the needle penetration degree of wax being not more than 4.
Inventors
- 👤 Hiroyuki Takagiwa
- 👤 Jiro Takahashi
- 👤 Meizo Shirose
- 👤 Kunio Akimoto
- 👤 Masafumi Uchida
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 08:28
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/087; G03G9/08742; G03G9/08755; G03G9/097; G03G9/09733; G03G9/09775; Y; Y10; Y10S; Y10S430/00; Y10S430/001; Y10S430/105
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
299 words
In a process of developing a latent electrostatic image with a toner, then transferring and fixing the developed image and wherein the fixing is accomplished by the use of a fixing unit having a heat roll fixing unit comprising a fluorinated resin surface and a pressure roller, the improvement wherein the toner comprises (a) a non-linear copolymer polyester resin having a side chain, said side chain comprising an aliphatic hydrocarbon group containing 3 to 22 carbon atoms, said copolymer being obtained by polymerization of (i) an etherified bisphenol monomer, (ii) a dicarboxylic acid monomer, (iii) at least one of a polyhydric alcohol monomer containing at least 3 hydroxy groups and a monomer component containing a polycarboxylic acid containing at least 3 carboxy groups and (iv) at least one monomer which forms said side chain selected from the group consisting of polyhydric alcohol monomers containing at least 2 hydroxy groups and containing a saturated or unsaturated hydrocarbon group containing 3 to 22 carbon atoms and polycarboxylic acid monomers containing at least 2 carboxy groups and containing a saturated or unsaturated hydrocarbon group containing 3 to 22 carbon atoms; and at least one compound selected from the group consisting of (b) and an alkylene-bis-aliphatic acid amide compound represented by the formula ##STR4## wherein R 1 and R 2 are independently selected from the group consisting of saturated and unsaturated aliphatic hydrocarbon groups having not less than 10 carbon atoms, R 3 and R 4 are independently selected from a hydrogen atom and a group represented by -OCR 5 wherein R 5 is a saturated or unsaturated hydrocarbon group and n is a positive integer, and (c) a wax containing not less than 20% by weight of an ester component, said wax having a needle penetration degree of not more than 4.
Claim 2
Dependent Claim
299 words
In a process of developing a latent electrostatic image with a toner, then transferring and fixing the developed image and wherein the fixing is accomplished by the use of a fixing unit having a heat roll fixing unit comprising a fluorinated resin surface and a pressure roller, the improvement wherein the toner comprises (a) a non-linear copolymer polyester resin having a side chain, said side chain comprising an aliphatic hydrocarbon group containing 3 to 22 carbon atoms, said copolymer being obtained by polymerization of (i) an etherified bisphenol monomer, (ii) a dicarboxylic acid monomer, (iii) at least one of a polyhydric alcohol monomer containing at least 3 hydroxy groups and a monomer component containing a polycarboxylic acid containing at least 3 carboxy groups and (iv) at least one monomer which forms said side chain selected from the group consisting of polyhydric alcohol monomers containing at least 2 hydroxy groups and containing a saturated or unsaturated hydrocarbon group containing 3 to 22 carbon atoms and polycarboxylic acid monomers containing at least 2 carboxy groups and containing a saturated or unsaturated hydrocarbon group containing 3 to 22 carbon atoms; and at least one compound selected from the group consisting of (b) and an alkylene-bis-aliphatic acid amide compound represented by the formula ##STR4## wherein R 1 and R 2 are independently selected from the group consisting of saturated and unsaturated aliphatic hydrocarbon groups having not less than 10 carbon atoms, R 3 and R 4 are independently selected from a hydrogen atom and a group represented by -OCR 5 wherein R 5 is a saturated or unsaturated hydrocarbon group and n is a positive integer, and (c) a wax containing not less than 20% by weight of an ester component, said wax having a needle penetration degree of not more than 4.
Claim 3
Dependent Claim
27 words
The process of claim 1, wherein the proportion of said dicarboxylic acid monomer with respect to the total acid component is from 10 to 90 molar %.
Claim 4
Dependent Claim
20 words
The process of claim 2, wherein said proportion of said dicarboxylic acid monomer is from 20 to 60 molar %.
Claim 5
Dependent Claim
36 words
The toner of claim 3, wherein said polyhydric alcohol monomer is selected from the group consisting of sorbitol, 1,2,3,6-hexanetetraol, 1,4-sorbitan, pentaerythritol, di-pentaerythritol, tripentaerythritol, saccharose, 1,2,4-butanetriol, 1,2,5-pentanetiol, glycerol, 2-methylpropanetriol, 2-methyl-1,2,4-butanetriol, trimethylol ethane, trimethylol propane and 1,3,5-trihydroxymethyl benzene.
Claim 6
Dependent Claim
27 words
The process of claim 1, wherein the proportion of said polyhydric alcohol monomer with respect to the total alcohol component is from 5 to 50 molar %.
Claim 7
Dependent Claim
19 words
The process of claim 5, wherein said proportion of said polyhydric alcohol is from 10 to 40 molar %.
Claim 8
Dependent Claim
46 words
The process of claim 1, wherein said polycarboxylic acid monomer is selected from the group consisting of 1,2,4-benzenetricarboxylic acid, 1,2,5-benzene tricarboxylic acid, 1,2,4-cyclohexanetricarboxylic acid, 2,5,7-naphthalenetricarboxylic acid, 1,2,4-naphthalenetricarboxylic acid, 1,2,4-butanetricarboxylic acid, 1,2,5-hexanetricarboxylic acid, 1,3-dicarboxyl-2-methyl-2-methylenecarboxylic-propane, tetra(methylenecalboxylic)methane, 1,2,7,8-octane-tetracarboxylic acid, empol trimer acid, and the acid anhydride of said acids.
Claim 9
Dependent Claim
26 words
The process of claim 1, wherein the proportion of said polycarboxylic acid with respect to the total acid component is from 5 to 50 molar %.
Claim 10
Dependent Claim
20 words
The process of claim 8, wherein said proportion of said polycarboxylic acid monomer is from 10 to 40 molar %.
Claim 11
Dependent Claim
39 words
The process of claim 1, wherein the total proportion of said polyhydric alcohol monomer and said dicarboxylic or polycarboxylic acid monomer containing a hydrocarbon group is from 1 to 50 molar % with respect to the toal monomer components.
Claim 12
Dependent Claim
28 words
The process of claim 10, wherein said total proportion of said polyhydric alcohol monomer and said dicarboxylic or polycarboxylic acid monomer is from 1 to 30 molar %.
Claim 13
Dependent Claim
19 words
The process of claim 1, wherein n of said general formula is a positive integer from 1 to 5.
Claim 14
Dependent Claim
19 words
The process of claim 1, wherein said alkylene-bis-aliphatic acid amide compound is selected from the group consisting of ##STR5##
Claim 15
Dependent Claim
20 words
The process of claim 1, wherein said alkylene-bis-aliphatic acid amide compound has a softening point of 100° to 180° C.
Claim 16
Dependent Claim
20 words
The process of claim 14, wherein said alkylene-bis-aliphatic acid amide compound has the softening point of 130° to 160° C.
Claim 17
Dependent Claim
26 words
The process of claim 1, wherein said ester component of said wax is an ester of fatty acid or the partially saponified product of said ester.
Claim 18
Dependent Claim
18 words
The process of claim 1, wherein said wax has a melting point of between 60° and 110° C.
Claim 19
Dependent Claim
27 words
The process of claim 1, wherein the ratio of said alkylene-bis-aliphatic acid amide compound and said wax used in combination is from 0.5:1 to 10:1 by weight.
Claim 20
Dependent Claim
22 words
The process of claim 1, wherein said ratio of said alkylene-bis-aliphatic acid amide compound and said wax is from 0.5:1 to 5:1.
Claim 21
Dependent Claim
22 words
The process of claim 1, wherein said etherifide bisphenol monomer is selected from the group consisting of polyoxypropylene(2.2)-2,2-bis(4-hydroxyphenyl)propane, polyoxyethylene(2)-2,2-bis(4-hydroxyphenyl)propane, polyoxypropylene(6)-2,2-bis(4-hydroxyphenyl)propane, and polyoxyproptrene(1.3)-2,2-bis(4-hydroxyphenyl)propane.
Claim 22
Dependent Claim
72 words
The process of claim 1, wherein said di-carboxylic acid monomer is selected from the group consisting of maleic acid, fumaric acid, metaconic acid, citraconic acid, itaconic acid, glutaconic acid, phthalic acid, iso-phthalic acid, terephthalic acid, cyclohexane-di-carboxylic acid, succinic acid, adipic acid, sebacic acid, malonic acid, n-dodecenyl succinic acid, iso-dodecenyl succinic acid, n-dodecyl succinic acid, iso-dodecyl succinic acid, iso-octyl succinic acid, n-octyl succinic acid, n-butyl succinic acid and the anhydrides of said acids.
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