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US4877306A Expired / Lapsed US ⏱️ 0.0 years remaining

Coated optical waveguide fibers

Assignee: Corning Glass Works
•
Filing: 1987-09-30
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Granted: 1989-10-31
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Expires: 2007-09-30
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Abstract

Abstract An optical waveguide fiber is provided which comprises (a) a glass core; (b) a glass cladding which includes a barrier layer in the region of its outer surface which has an index of refraction and an absorption coefficient which are greater than the index of refraction and the absorption coefficient of the remainder of the cladding; and (c) a polymeric protective coating which is in direct contact with the outer surface of the cladding and which has an index of refraction which is less than the index of refraction of the barrier layer and less than the index of refraction of the remainder of the cladding. In certain preferred embodiments, the polymeric coating is selected from the group consisting of RTV silicone rubbers, UV curable silicones of the thio-ene type, UV curable silicone acrylates, and fluoropolymeric coatings.

Inventors

  • 👤 Gitimoy Kar

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 21:55
CPC Classifications
G; G02; G02B; G02B6/00; G02B6/10; G02B6/02; G02B6/036; G02B6/03616; G02B6/03638; G02B6/03644; G02B6/02395; G02B6/03605; G02B6/03611; G02B6/24; G02B6/26; G02B6/264; G02B6/266

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 101 words
An optical waveguide fiber comprising: (a) a glass core: (b) a glass cladding which includes a layer in the region of its outer surface which has an index of refraction and an absorption coefficient which are greater than the index of refraction and the absorption coefficient of the remainder of the cladding; and (c) a polymeric protective coating which is in direct contact with the outer surface of the cladding and which has an index of refraction which is less than the index of refraction of the layer and less than the index of refraction of the remainder of the cladding.
Claim 2
Dependent Claim 101 words
An optical waveguide fiber comprising: (a) a glass core: (b) a glass cladding which includes a layer in the region of its outer surface which has an index of refraction and an absorption coefficient which are greater than the index of refraction and the absorption coefficient of the remainder of the cladding; and (c) a polymeric protective coating which is in direct contact with the outer surface of the cladding and which has an index of refraction which is less than the index of refraction of the layer and less than the index of refraction of the remainder of the cladding.
Claim 3
Dependent Claim 19 words
The optical waveguide fiber of claim 1 wherein the layer is located at the outer surface of the cladding.
Claim 4
Dependent Claim 21 words
The optical waveguide fiber of claim 1 wherein the layer has a thickness of between about 2 and about 3 microns.
Claim 5
Dependent Claim 33 words
The optical waveguide fiber of claim 1 wherein the index of refraction of the layer is greater than 1.48 and the index of refraction of the remainder of the cladding is approximately 1.46.
Claim 6
Dependent Claim 52 words
The optical waveguide fiber of claim 1 wherein the layer comprises a silica glass which has been doped with a material selected from the group consisting of FeO, CdO, MO 3 , Cr 2 O 3 2, V 2 O 5 , CoO, Nb 2 O 5 , and TiO 2 .
Claim 7
Dependent Claim 14 words
The optical waveguide fiber of claim 5 wherein the dopant is TiO 2 .
Claim 8
Dependent Claim 23 words
The optical waveguide fiber of claim 6 wherein the layer includes an enriched concentration of titanium in its reduced, Ti 3+ , form.
Claim 9
Dependent Claim 16 words
The optical waveguide fiber of claim 1 wherein the polymeric protective coating is a silicone rubber.
Claim 10
Dependent Claim 36 words
The optical waveguide fiber of claim 1 wherein the polymeric protective coating is selected from the group consisting of RTV silicone rubbers, UV curable silicones of the thio-ene type, UV curable silicone acrylates, and fluoropolymeric coatings.
Claim 11
Dependent Claim 24 words
The optical waveguide fiber of claim 1 wherein the power carried by cladding modes decays to essentially zero in less than about 0.2 meters.
Claim 12
Dependent Claim 53 words
The optical waveguide fiber of claim 1 wherein the layer comprises a silica glass which has been doped with TiO 2 , includes an enriched concentration of titanium in its reduced, ti 3+ , form, has an index of refraction greater than 1.48, and is located at the outer surface of the cladding.
Claim 13
Dependent Claim 36 words
The optical waveguide fiber of claim 11 wherein the polymeric protective coating is selected from the group consisting of RTV silicone rubbers, UV curable silicones of the thio-ene type, UV curable silicone acrylates, and fluoropolymeric coatings.
Claim 14
Independent Claim 116 words
A method for coating an optical waveguide fiber with a low index of refraction coating comprising the steps of: (a) providing an optical waveguide fiber which comprises: (i) a glass core, and (ii) a glass cladding which includes a layer in the region of its outer surface which has an index of refraction and an absorption coefficient which are greater than the index of refraction and the absorption coefficient of the remainder of the cladding; and (b) coating the outside surface of the cladding with the low index of refraction coating, said coating having an index of refraction which is less than that of the layer and less than that of the remainder of the cladding.
Claim 15
Independent Claim 116 words
A method for coating an optical waveguide fiber with a low index of refraction coating comprising the steps of: (a) providing an optical waveguide fiber which comprises: (i) a glass core, and (ii) a glass cladding which includes a layer in the region of its outer surface which has an index of refraction and an absorption coefficient which are greater than the index of refraction and the absorption coefficient of the remainder of the cladding; and (b) coating the outside surface of the cladding with the low index of refraction coating, said coating having an index of refraction which is less than that of the layer and less than that of the remainder of the cladding.
Claim 16
Dependent Claim 49 words
The method of claim 13 wherein the layer is formed by doping a silica glass with a material selected from the group consisting of FeO, CdO, MoO 3 , Cr 2 O 3 , V 2 O 5 , CoO, Nb 2 O 5 , and TiO 2 .
Claim 17
Dependent Claim 14 words
The method of claim 14 wherein the layer is doped with TiO 2 .
Claim 18
Dependent Claim 16 words
The method of claim 13 wherein the low index of refraction coating is a silicone rubber.
Claim 19
Dependent Claim 36 words
The method of claim 13 wherein the low index of refraction coating is selected from the group consisting of RTV silicone rubbers, UV curable silicones of the thio-ene type, UV curable silicone acrylates, and fluoropolymeric coatings.

References Cited (Backward Citations)

US4113349A Cited
US4184860A Cited
US4243298A Cited
US4306767A Cited
US4385802A Cited
US4690502A Cited
EP0223466A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-10-30 1993-05-01 1993-10-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-10-30 1997-05-01 1997-10-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-10-30 2001-05-01 2001-10-31 $7700.00 Window Closed / Lapsed

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