US4876150A
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Langmuir blodgett films
Assignee: UK Secretary of State for Defence
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Filing: 1986-06-25
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Granted: 1989-10-24
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Expires: 2006-06-25
Abstract
Abstract Langmuir-Blodgett(LB) films of ABAB structure in which the compounds A and B are different and contain complementary groups which result in non-centrosymmetry of the layer plane. Three types of structures are described: (1) in which A and B have similar backbones with complementary chromophore groups, (2) in which A and B have similar backbones with complementary functional groups, and (3) in which A and B have related functional groups but complementary backbones.
Inventors
- 👤 Gilbert W. Smith
- 👤 Mervyn F. Daniel
- 👤 John W. Barton
- 👤 Norman M. Ratcliffe
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 21:58
CPC Classifications
G; G02; G02F; G02F1/00; G02F1/35; G02F1/355; G02F1/361; G02F1/3618; B; B82; B82Y; B82Y20/00; H; H10; H10N; H10N15/00; H10N15/10; H10N15/15; H10N30/00; H10N30/80; H10N30/85; H10N30/857; Y; Y10; Y10S; Y10S977/00; Y10S977/84; Y10S977/89; Y10S977/895; Y10T; Y10T428/00; Y10T428/31504
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
320 words
A Langmuir-Blodgett (LB) film of ABAB structure composed of a combination of compounds A and B which are different and which are selected from the group consisting of: AB combinations wherein A has the formula E-C-F and B has the formula E 1 -C 1 -F 1 , wherein E and E 1 are independently CH 3 (CH 2 ) i --where i is 2-20, F and F 1 are independently --(CH 2 ) j --COZ wherein j is 1-10 and Z is --OH, C 1-6 alkyl or NR 1 R 2 wherein R 1 and R 2 are independently H or C 1-6 alkyl, C and C 1 are independently ##STR18## where X and Y are each independently selected from the group consisting of ═NH, ═NR 3 , ═CO, ═CH.CN, ═CHONO, ═CH(Halogen), --COO--, --OOC--, ═CH(ONO)-- CO--NH--, --CO.NR 4 and --O-- where R 3 is C 1-4 alkyl and R 4 is C 1-6 alkyl; AB combinations wherein A is a long chain alkyl amine having the structure C n H 2n+1 ) --NH 2 where n is 16-26, and B is a long chain fatty acid having the structure R 5 (CH 2 ) m COOH where R 5 is selected from the group consisting of CH 3 and CH 2 ═CH and where m is 16-26; AB combinations wherein A is a long chain alkyl amine having the structure C n H.sub.(2n+1) --NH 2 where n is 16-26 and B is a compound of general structure: ##STR19## in which K is 2-20, 1 is 0 to 10, and X, Y and Z are as defined above; and AB combinations wherein A is a long chain carboxylic acid of the formula R 5 (CH 2 ) m COOH where R 5 and m are as defined above and B is a compound of the formula: ##STR20## where K, is 2-20 l, X, Y and Z are as defined above.
Claim 2
Dependent Claim
320 words
A Langmuir-Blodgett (LB) film of ABAB structure composed of a combination of compounds A and B which are different and which are selected from the group consisting of: AB combinations wherein A has the formula E-C-F and B has the formula E 1 -C 1 -F 1 , wherein E and E 1 are independently CH 3 (CH 2 ) i --where i is 2-20, F and F 1 are independently --(CH 2 ) j --COZ wherein j is 1-10 and Z is --OH, C 1-6 alkyl or NR 1 R 2 wherein R 1 and R 2 are independently H or C 1-6 alkyl, C and C 1 are independently ##STR18## where X and Y are each independently selected from the group consisting of ═NH, ═NR 3 , ═CO, ═CH.CN, ═CHONO, ═CH(Halogen), --COO--, --OOC--, ═CH(ONO)-- CO--NH--, --CO.NR 4 and --O-- where R 3 is C 1-4 alkyl and R 4 is C 1-6 alkyl; AB combinations wherein A is a long chain alkyl amine having the structure C n H 2n+1 ) --NH 2 where n is 16-26, and B is a long chain fatty acid having the structure R 5 (CH 2 ) m COOH where R 5 is selected from the group consisting of CH 3 and CH 2 ═CH and where m is 16-26; AB combinations wherein A is a long chain alkyl amine having the structure C n H.sub.(2n+1) --NH 2 where n is 16-26 and B is a compound of general structure: ##STR19## in which K is 2-20, 1 is 0 to 10, and X, Y and Z are as defined above; and AB combinations wherein A is a long chain carboxylic acid of the formula R 5 (CH 2 ) m COOH where R 5 and m are as defined above and B is a compound of the formula: ##STR20## where K, is 2-20 l, X, Y and Z are as defined above.
Claim 3
Dependent Claim
42 words
A LB film according to claim 1, wherein A has the formula E-C-F, and B has the formula E 1 -C 1 F 1 wherein E, C, F, E 1 , C 1 and F 1 are as defined in claim 1.
Claim 4
Dependent Claim
40 words
An LB film according to claim 2, wherein the layers A and B are additionally separated by at least one counter-layer of an alkyl amine of the formula CH 3 (CH 2 ) n NH 2 where n is 16-26.
Claim 5
Dependent Claim
44 words
An LB film according to claim 12 wherein A is: ##STR21## wherein E, E 1 , F, F 1 , X and Y are as defined in claim 1, the two X groups are the same and the two Y groups are the same.
Claim 6
Dependent Claim
11 words
An LB film according to claim 4, wherein A is: ##STR22##
Claim 7
Dependent Claim
11 words
An LB film according to claim 2, wherein A is: ##STR23##
Claim 8
Dependent Claim
54 words
An LB film according to claim 1, wherein A is a long chain alkyl amine of the structure C n H.sub.(1=2n+1) --NH 2 where n is 16-26, and B is a long chain fatty acid of structure R 5 and is selected from CH 3 and CH 2 ═CH and where m is 16-26.
Claim 9
Dependent Claim
52 words
An LB film according to claim 7, wherein n is 18, and R 5 (CH 2 ) m is selected from the group consisting of C 17 H 35 , C 19 H 39 , C 21 H 43 , C 23 H 47 and CH 2 ═CH(CH 2 ) 20 .
Claim 10
Dependent Claim
57 words
An LB film according to claim 1, wherein A is a long chain alkyl amine of the structure C 2 H.sub.(2n+1) --NH 2 where n is 16-26, and B is of a compound of the structure: ##STR24## in which K is 2-20, l is 0 to 10, and Y and Z are as defined in claim 1.
Claim 11
Dependent Claim
15 words
An LB film according to claim 9 wherein n is 18 and B is: ##STR25##
Claim 12
Dependent Claim
65 words
An LB film according to claim 1, wherein A is a long chain carboxylic acid of the formula R 5 (CH 2 ) m COOH where R 5 and m are as defined in claim 1 and B is a compound of the formula: ##STR26## where k is 2-20, l is 0 to 10 and X, Y and Z are as defined in claim 1.
Claim 13
Dependent Claim
27 words
An LB film according to claim 1 wherein R 5 (CH 2 ) m is CH 3 (CH 2 ) 18 and B is selected from ##STR27##
Claim 14
Dependent Claim
24 words
An electro optical device incorporating an LB film according to claim 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 or 12.
References Cited (Backward Citations)
US4536450A
Cited
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