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US4873203A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for formation of insulation film on silicon buried in trench

Assignee: Micron Memory Japan Ltd
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Filing: 1988-07-19
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Granted: 1989-10-10
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Expires: 2008-07-19
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Abstract

Abstract An insulation film on silicon buried in a trench is prepared by forming a field oxide film by using a first Si 3 N 4 mask formed on a silicon substrate, forming a second Si 3 N 4 mask for formation of a trench, forming a trench in the silicon substrate by using the second Si 3 N 4 mask, burying polycrystalline silicon in the trench, removing the second Si 3 N 4 mask while leaving the first Si 3 N 4 mask and oxidizing the surface of the polycrystalline silicon buried in the trench by thermal oxidation. The so-formed insulation film on silicon buried in the trench has a uniform thickness and a high dielectric strength. The surface of the substrate at a part where an active element will be formed in the future is not oxidized.

Inventors

  • 👤 Toru Kaga
  • 👤 Shinichiro Kimura
  • 👤 Tokuo Kure
  • 👤 Yoshifumi Kawamoto
  • 👤 Hideo Sunami

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 18:48
CPC Classifications
H; H10; H10B; H10B12/00; H10B12/01; H10B12/02; H10B12/03; H10B12/038; H10D; H10D1/00; H10D1/01; H10D1/045; H10D1/047; H10P; H10P14/00; H10P14/60; H10P14/61; H10W; H10W10/00; H10W10/01; H10W10/011; H10W10/012; H10W10/014; H10W10/041; H10W10/40

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 111 words
A method for forming an insulation film on silicon buried in a trench, which comprises the steps of (i) forming a first mask composed of a first Si 3 N 4 layer on a silicon substrate, (ii) forming a field oxide film by using the first mask composed of the first Si 3 N 4 layer, (iii)forming a trench in the silicon substrate, (iv) burying polycrystalline silicon in the trench, and (v) oxidizing the surface of the polycrystalline silicon in the state where no Si 3 N 4 , other than the first Si 3 N 4 layer of the first mask, is present on the silicon substrate adjacent the trench.
Claim 2
Independent Claim 111 words
A method for forming an insulation film on silicon buried in a trench, which comprises the steps of (i) forming a first mask composed of a first Si 3 N 4 layer on a silicon substrate, (ii) forming a field oxide film by using the first mask composed of the first Si 3 N 4 layer, (iii)forming a trench in the silicon substrate, (iv) burying polycrystalline silicon in the trench, and (v) oxidizing the surface of the polycrystalline silicon in the state where no Si 3 N 4 , other than the first Si 3 N 4 layer of the first mask, is present on the silicon substrate adjacent the trench.
Claim 3
Dependent Claim 41 words
A method for forming an insulation film on silicon buried in a trench according to claim 1, wherein the trench is formed using a second mask, the second mask being removed prior to said oxidizing the surface of the polycrystalline silicon.
Claim 4
Dependent Claim 26 words
A method for forming an insulation film on silicon buried in a trench according to claim 2, wherein said second mask is composed of photoresist material.
Claim 5
Dependent Claim 53 words
A method for forming an insulation film on silicon buried in a trench according to claim 2, wherein, said second mask is composed of a second Si 3 N 4 layer, the second Si 3 N 4 layer being removed, adjacent the trench, prior to said oxidizing the surface of the polycrystalline silicon.
Claim 6
Dependent Claim 38 words
A method for forming an insulation film on silicon buried in a trench according to claim 4, wherein the first Si 3 N 4 layer has a silicon oxide film formed thereon, prior to forming the second mask.
Claim 7
Dependent Claim 42 words
A method for forming an insulation film on silicon buried in a trench according to claim 1, wherein, after forming the trench and prior to burying polycrystalline silicon in the trench, an insulating film is provided on the surfaces in the trench.
Claim 8
Dependent Claim 46 words
A method for forming an insulation film on silicon buried in a trench according to claim 1, wherein the surface of the polycrystalline silicon is oxidized in the state where only regions for formation of active semiconductor elements are covered with Si 3 N 4 .
Claim 9
Dependent Claim 32 words
A method for forming an insulation film on silicon buried in a trench according to claim 1, wherein the first Si 3 N 4 layer has an Si0 2 film formed thereon.
Claim 10
Dependent Claim 40 words
A method for forming an insulation film on silicon buried in a trench according to claim 1, further comprising the step of forming a gate electrode on the oxide layer formed by said oxidizing the surface of the polycrystalline silicon.
Claim 11
Independent Claim 133 words
A method for forming an insulation film on silicon buried in a trench, which comprises the steps of (i) forming a first mask composed of a first Si 3 N 4 layer on a silicon substrate; (ii) forming a field oxide film by using the first mask composed of the first Si 3 N 4 layer; (iii,) forming a second mask composed of at least a second Si 3 N 4 layer on the silicon substrate , after step (ii); (iii) forming a trench in the silicon substrate by using the second mask; (iv) burying polycrystalline silicon in the trench; (iv') removing the second Si 3 N 4 layer on the silicon substrate, adjacent to the trench on the silicon substrate; and (v) after step (iv'), oxidizing the surface of the polycrystalline silicon.
Claim 12
Independent Claim 133 words
A method for forming an insulation film on silicon buried in a trench, which comprises the steps of (i) forming a first mask composed of a first Si 3 N 4 layer on a silicon substrate; (ii) forming a field oxide film by using the first mask composed of the first Si 3 N 4 layer; (iii,) forming a second mask composed of at least a second Si 3 N 4 layer on the silicon substrate , after step (ii); (iii) forming a trench in the silicon substrate by using the second mask; (iv) burying polycrystalline silicon in the trench; (iv') removing the second Si 3 N 4 layer on the silicon substrate, adjacent to the trench on the silicon substrate; and (v) after step (iv'), oxidizing the surface of the polycrystalline silicon.
Claim 13
Dependent Claim 38 words
A method for forming an insulation film on silicon buried in a trench according to claim 10, wherein, prior to forming the second mask, a silicon oxide film is formed on the first Si 3 N 4 layer.
Claim 14
Dependent Claim 34 words
A method for forming an insulation film on silicon buried in a trench according to claim 10, wherein the steps (ii'), (iii), (iv), (iv') and (v) are performed without removal of the first mask.
Claim 15
Dependent Claim 37 words
A method for forming an insulation film on silicon buried in a trench according to claim 10, wherein the first Si 3 N 4 layer composing the first mask has a thickness of 50 to 300 nm.
Claim 16
Dependent Claim 37 words
A method for forming an insulation film on silicon buried in a trench according to claim 13, wherein the second Si 3 N 4 layer composing the second mask has a thickness of at least 50 nm.
Claim 17
Independent Claim 148 words
A method for forming an insulation film on silicon buried in a trench, which comprises the steps of (I) forming a first mask composed of a first Si 3 N 4 layer on a silicon substrate, (II)forming a field oxide film by using the first mask composed of the first Si 3 N 4 layer, (III) forming a second mask, composed of at least a second Si 3 N 4 layer, on the silicon substrate, after step (II), (IV) forming a trench in the silicon substrate by using the second mask, (V) burying polycrystalline silicon in the trench, (VI) subjecting the surface of the polycrystalline silicon to a a first oxidation, (VII) removing the second Si 3 N 4 layer on the silicon substrate, adjacent to the trench on the silicon substrate, and (VIII) after step (VII), subjecting the surface of the polycrystalline silicon to a second oxidation.
Claim 18
Independent Claim 148 words
A method for forming an insulation film on silicon buried in a trench, which comprises the steps of (I) forming a first mask composed of a first Si 3 N 4 layer on a silicon substrate, (II)forming a field oxide film by using the first mask composed of the first Si 3 N 4 layer, (III) forming a second mask, composed of at least a second Si 3 N 4 layer, on the silicon substrate, after step (II), (IV) forming a trench in the silicon substrate by using the second mask, (V) burying polycrystalline silicon in the trench, (VI) subjecting the surface of the polycrystalline silicon to a a first oxidation, (VII) removing the second Si 3 N 4 layer on the silicon substrate, adjacent to the trench on the silicon substrate, and (VIII) after step (VII), subjecting the surface of the polycrystalline silicon to a second oxidation.
Claim 19
Independent Claim 146 words
A method for forming an insulation film on silicon buried in a trench, which comprises the steps of (i) forming a first mask composed of a first Si 3 N 4 layer on a silicon substrate; (ii) forming a field oxide film by using the first mask composed of the first Si 3 N 4 layer; (ii') forming a third mask composed of at least a double layer of a third Si 3 N 4 layer and an SiO 2 layer thereon, on the silicon substrate after the completion of the step (ii); (iii) forming a trench in the silicon substrate by using said third mask; (iv) burying polycrystalline silicon in the trench; (iv') removing said third Si 3 N 4 layer on the silicon substrate, adjacent to the trench on the silicon substrate; and (v) after step (iv'), oxidizing the surface of the polycrystalline silicon.
Claim 20
Independent Claim 146 words
A method for forming an insulation film on silicon buried in a trench, which comprises the steps of (i) forming a first mask composed of a first Si 3 N 4 layer on a silicon substrate; (ii) forming a field oxide film by using the first mask composed of the first Si 3 N 4 layer; (ii') forming a third mask composed of at least a double layer of a third Si 3 N 4 layer and an SiO 2 layer thereon, on the silicon substrate after the completion of the step (ii); (iii) forming a trench in the silicon substrate by using said third mask; (iv) burying polycrystalline silicon in the trench; (iv') removing said third Si 3 N 4 layer on the silicon substrate, adjacent to the trench on the silicon substrate; and (v) after step (iv'), oxidizing the surface of the polycrystalline silicon.
Claim 21
Dependent Claim 36 words
A method for forming an insulation film on silicon buried in a trench according to claim 16, wherein, prior to burying polycrystalline silicon in the trench, the SiO 2 layer of the third mask is removed.
Claim 22
Dependent Claim 56 words
A method for forming an insulation film on silicon buried in a trench according to claim 17, wherein removal of the SiO 2 layer of the third mask includes a step of depositing a fourth Si 3 N 4 layer on surfaces of the trench and then etching the SiO 2 layer of the third mask.
Claim 23
Dependent Claim 38 words
A method for forming an insulation film on silicon buried in a trench according to claim 18, wherein, after the SiO 2 layer of the third mask is removed, the fourth Si 3 N 4 layer is removed.
Claim 24
Independent Claim 177 words
A method for forming an insulation film on silicon buried in a trench, which comprises the sites of (I) forming a first mask composed of a first Si 3 N 4 layer on a silicon substrate; (II) forming a field oxide film by using the first mask composed of the first Si 3 N 4 layer; (III') forming a third mask composed of at least a double layer of a third Si 3 N 4 layer and an SiO 2 layer thereon, on the silicon substrate after the completion of the step (II); (IV) forming a trench in the silicon substrate by using the third mask; (IV') removing the SiO 2 layer on the third Si 3 N 4 layer; (V) burying polycrystalline silicon in the trench; (IV) subjecting the surface of the polycrystalline silicon to a first oxidation; (VII) removing the third Si 3 N 4 layer on the silicon substrate, adjacent to the trench on the silicon substrate; and (VIII) after step (VII), subjecting the surface of the polycrystalline silicon to a second oxidation burying.
Claim 25
Independent Claim 177 words
A method for forming an insulation film on silicon buried in a trench, which comprises the sites of (I) forming a first mask composed of a first Si 3 N 4 layer on a silicon substrate; (II) forming a field oxide film by using the first mask composed of the first Si 3 N 4 layer; (III') forming a third mask composed of at least a double layer of a third Si 3 N 4 layer and an SiO 2 layer thereon, on the silicon substrate after the completion of the step (II); (IV) forming a trench in the silicon substrate by using the third mask; (IV') removing the SiO 2 layer on the third Si 3 N 4 layer; (V) burying polycrystalline silicon in the trench; (IV) subjecting the surface of the polycrystalline silicon to a first oxidation; (VII) removing the third Si 3 N 4 layer on the silicon substrate, adjacent to the trench on the silicon substrate; and (VIII) after step (VII), subjecting the surface of the polycrystalline silicon to a second oxidation burying.

References Cited (Backward Citations)

JPS59108325A Cited
EP0116789A1 Cited
JPS60149149A Cited
JPS60149148A Cited
JPS61115336A Cited
JPS61201445A Cited
JPS61214446A Cited
GB2179788A Cited
JPH0638832A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-10-09 1993-04-10 1993-10-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-10-09 1997-04-10 1997-10-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-10-09 2001-04-10 2001-10-10 $7700.00 Window Closed / Lapsed

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