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US4867896A Expired / Lapsed US ⏱️ 0.0 years remaining

Cleaning compositions containing cross-linked polymeric thickeners and hypochlorite bleach

Assignee: Lever Brothers Co
•
Filing: 1988-02-17
•
Granted: 1989-09-19
•
Expires: 2008-02-17
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Abstract

Abstract Liquid or gel-type cleaning compositions are reported containing a water-soluble polymer formed from monomers comprising at least one α, β-unsaturated carboxylic acid or salt thereof and one or more cross-linking monomers each having at least two unsaturated groups and which after cross-linking consists of a saturated hydrocarbon or aromatic structure. The polymer must be stable to oxidation by 1% hypochlorite at 25° C. for greater than two weeks without exhibiting any phase separation or greater than 50% viscosity loss from the composition. Besides polymer, the compositions will contain a chlorine bleach agent.

Inventors

  • 👤 David L. Elliott
  • 👤 Laura A. Kiefer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 23:42
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/395; C11D3/3956; C11D3/16; C11D3/37; C11D3/3746; C11D3/3757; C11D3/3765

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 189 words
A liquid or gel cleaning composition comprising: (i) a water-soluble polymer formed from 25 to 99.9 wt. % of monomers comprising at least one α, β-unsaturated carboxylic acid or salt thereof selected from the group consisting of acrylic acid, methacrylic acid, maleic anhydride, their salts and mixtures thereof, and from 0.1 to 15 wt. % of at least one cross-linking monomer each having at least two unsaturated groups selected from the group consisting of trivinylcyclohexane, 1,5-hexadiene, trivinylbenzene, divinylbenzene and polybutadiene and which after crosslinking consists of a saturated hydrocarbon or aromatic structure, said polymer being stable to oxidation by 1% hypochlorite at 25° C. for greater than two weeks without exhibiting any phase separation or greater than 50% loss in viscosity from said composition; and (ii) a chlorine containing bleach compound present in an amount to provide about 0.1 to 5% of available chlorine by weight of the composition; said cleaning composition having a viscosity on a Haake Rotovisco RV-100 Viscometer at 25° C. under 5 sec -1 shear of from about 500 to 20,000 cps and under 21 sec -1 shear of from about 200 to 5,000 cps.
Claim 2
Dependent Claim 189 words
A liquid or gel cleaning composition comprising: (i) a water-soluble polymer formed from 25 to 99.9 wt. % of monomers comprising at least one α, β-unsaturated carboxylic acid or salt thereof selected from the group consisting of acrylic acid, methacrylic acid, maleic anhydride, their salts and mixtures thereof, and from 0.1 to 15 wt. % of at least one cross-linking monomer each having at least two unsaturated groups selected from the group consisting of trivinylcyclohexane, 1,5-hexadiene, trivinylbenzene, divinylbenzene and polybutadiene and which after crosslinking consists of a saturated hydrocarbon or aromatic structure, said polymer being stable to oxidation by 1% hypochlorite at 25° C. for greater than two weeks without exhibiting any phase separation or greater than 50% loss in viscosity from said composition; and (ii) a chlorine containing bleach compound present in an amount to provide about 0.1 to 5% of available chlorine by weight of the composition; said cleaning composition having a viscosity on a Haake Rotovisco RV-100 Viscometer at 25° C. under 5 sec -1 shear of from about 500 to 20,000 cps and under 21 sec -1 shear of from about 200 to 5,000 cps.
Claim 3
Dependent Claim 16 words
A composition according to claim 1 wherein said polymer contains three or more different monomer units.
Claim 4
Dependent Claim 23 words
A composition according to claim 2 wherein said polymer also comprises a C 1 -C 22 alkyl ester of acrylic or methacrylic acid.
Claim 5
Dependent Claim 22 words
A composition according to claim 1 wherein said polymer is formed from polyacrylic or polymethacrylic acid and salts thereof cross-linked with trivinylcyclohexane.
Claim 6
Dependent Claim 22 words
A composition according to claim 1 wherein said polymer is formed from acrylic or methacrylic acid and salts thereof cross-linked with 1,5-hexadiene.
Claim 7
Dependent Claim 25 words
A composition according to claim 1 wherein said polymer is formed from acrylic or methacrylic acid and salts thereof, methyl acrylate, together cross-linked with 1,5-hexadiene.
Claim 8
Dependent Claim 29 words
A composition according to claim 1 wherein said polymer is formed from acrylic or methacrylic acid and salts thereof, and maleic anhydride or salts thereof, together cross-linked with trivinylcyclohexane.
Claim 9
Dependent Claim 18 words
A composition according to claim 1 having a J e o value greater than 0.01 meters 2 /Newton.
Claim 10
Dependent Claim 20 words
A composition according to claim 8 wherein the J e o ranges from about 0.02 to 0.1 meters 2 /Newton.
Claim 11
Dependent Claim 19 words
A composition according to claim 1 wherein said chlorine bleach is selected from sodium hypochlorite and alkali metal dichloroisocyanurate.
Claim 12
Dependent Claim 40 words
A composition according to claim 1 wherein said composition viscosity at 25° C. under 5 sec -1 shear ranges from about 3,000 to about 7,000 cps and under 21 sec -1 shear ranges from about 400 to about 2,500 cps.
Claim 13
Dependent Claim 33 words
A composition according to claim 1 wherein said monomers comprising at least one α, β-unsaturated carboxylic acid or salt are present from 40 to 99.9 wt. % based upon the final polymer weight.
Claim 14
Dependent Claim 25 words
A composition according to claim 1 wherein the cross-linking monomer is present from between 0.2 and 4 wt. % based upon the final polymer weight.

References Cited (Backward Citations)

US2798053A Cited
US2985625A Cited
US2810716A Cited
US3544488A Cited
US3579455A Cited
US4147650A Cited
US4228048A Cited
GB2163447A Cited
GB2164350A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-09-18 1993-03-20 1993-09-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-09-18 1997-03-20 1997-09-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-09-18 2001-03-20 2001-09-19 $7700.00 Window Closed / Lapsed

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