US4867896A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Cleaning compositions containing cross-linked polymeric thickeners and hypochlorite bleach
Assignee: Lever Brothers Co
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Filing: 1988-02-17
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Granted: 1989-09-19
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Expires: 2008-02-17
Abstract
Abstract Liquid or gel-type cleaning compositions are reported containing a water-soluble polymer formed from monomers comprising at least one α, β-unsaturated carboxylic acid or salt thereof and one or more cross-linking monomers each having at least two unsaturated groups and which after cross-linking consists of a saturated hydrocarbon or aromatic structure. The polymer must be stable to oxidation by 1% hypochlorite at 25° C. for greater than two weeks without exhibiting any phase separation or greater than 50% viscosity loss from the composition. Besides polymer, the compositions will contain a chlorine bleach agent.
Inventors
- 👤 David L. Elliott
- 👤 Laura A. Kiefer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 23:42
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/395; C11D3/3956; C11D3/16; C11D3/37; C11D3/3746; C11D3/3757; C11D3/3765
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
189 words
A liquid or gel cleaning composition comprising: (i) a water-soluble polymer formed from 25 to 99.9 wt. % of monomers comprising at least one α, β-unsaturated carboxylic acid or salt thereof selected from the group consisting of acrylic acid, methacrylic acid, maleic anhydride, their salts and mixtures thereof, and from 0.1 to 15 wt. % of at least one cross-linking monomer each having at least two unsaturated groups selected from the group consisting of trivinylcyclohexane, 1,5-hexadiene, trivinylbenzene, divinylbenzene and polybutadiene and which after crosslinking consists of a saturated hydrocarbon or aromatic structure, said polymer being stable to oxidation by 1% hypochlorite at 25° C. for greater than two weeks without exhibiting any phase separation or greater than 50% loss in viscosity from said composition; and (ii) a chlorine containing bleach compound present in an amount to provide about 0.1 to 5% of available chlorine by weight of the composition; said cleaning composition having a viscosity on a Haake Rotovisco RV-100 Viscometer at 25° C. under 5 sec -1 shear of from about 500 to 20,000 cps and under 21 sec -1 shear of from about 200 to 5,000 cps.
Claim 2
Dependent Claim
189 words
A liquid or gel cleaning composition comprising: (i) a water-soluble polymer formed from 25 to 99.9 wt. % of monomers comprising at least one α, β-unsaturated carboxylic acid or salt thereof selected from the group consisting of acrylic acid, methacrylic acid, maleic anhydride, their salts and mixtures thereof, and from 0.1 to 15 wt. % of at least one cross-linking monomer each having at least two unsaturated groups selected from the group consisting of trivinylcyclohexane, 1,5-hexadiene, trivinylbenzene, divinylbenzene and polybutadiene and which after crosslinking consists of a saturated hydrocarbon or aromatic structure, said polymer being stable to oxidation by 1% hypochlorite at 25° C. for greater than two weeks without exhibiting any phase separation or greater than 50% loss in viscosity from said composition; and (ii) a chlorine containing bleach compound present in an amount to provide about 0.1 to 5% of available chlorine by weight of the composition; said cleaning composition having a viscosity on a Haake Rotovisco RV-100 Viscometer at 25° C. under 5 sec -1 shear of from about 500 to 20,000 cps and under 21 sec -1 shear of from about 200 to 5,000 cps.
Claim 3
Dependent Claim
16 words
A composition according to claim 1 wherein said polymer contains three or more different monomer units.
Claim 4
Dependent Claim
23 words
A composition according to claim 2 wherein said polymer also comprises a C 1 -C 22 alkyl ester of acrylic or methacrylic acid.
Claim 5
Dependent Claim
22 words
A composition according to claim 1 wherein said polymer is formed from polyacrylic or polymethacrylic acid and salts thereof cross-linked with trivinylcyclohexane.
Claim 6
Dependent Claim
22 words
A composition according to claim 1 wherein said polymer is formed from acrylic or methacrylic acid and salts thereof cross-linked with 1,5-hexadiene.
Claim 7
Dependent Claim
25 words
A composition according to claim 1 wherein said polymer is formed from acrylic or methacrylic acid and salts thereof, methyl acrylate, together cross-linked with 1,5-hexadiene.
Claim 8
Dependent Claim
29 words
A composition according to claim 1 wherein said polymer is formed from acrylic or methacrylic acid and salts thereof, and maleic anhydride or salts thereof, together cross-linked with trivinylcyclohexane.
Claim 9
Dependent Claim
18 words
A composition according to claim 1 having a J e o value greater than 0.01 meters 2 /Newton.
Claim 10
Dependent Claim
20 words
A composition according to claim 8 wherein the J e o ranges from about 0.02 to 0.1 meters 2 /Newton.
Claim 11
Dependent Claim
19 words
A composition according to claim 1 wherein said chlorine bleach is selected from sodium hypochlorite and alkali metal dichloroisocyanurate.
Claim 12
Dependent Claim
40 words
A composition according to claim 1 wherein said composition viscosity at 25° C. under 5 sec -1 shear ranges from about 3,000 to about 7,000 cps and under 21 sec -1 shear ranges from about 400 to about 2,500 cps.
Claim 13
Dependent Claim
33 words
A composition according to claim 1 wherein said monomers comprising at least one α, β-unsaturated carboxylic acid or salt are present from 40 to 99.9 wt. % based upon the final polymer weight.
Claim 14
Dependent Claim
25 words
A composition according to claim 1 wherein the cross-linking monomer is present from between 0.2 and 4 wt. % based upon the final polymer weight.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1992-09-18 | 1993-03-20 | 1993-09-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-09-18 | 1997-03-20 | 1997-09-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-09-18 | 2001-03-20 | 2001-09-19 | $7700.00 | Window Closed / Lapsed |