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US4866114A Expired / Lapsed US ⏱️ 0.0 years remaining

Self-extinguishing, thermoplastic polyphenylene ether/polyamide molding materials and their use for the production of moldings

Assignee: BASF SE
•
Filing: 1988-09-28
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Granted: 1989-09-12
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Expires: 2008-09-28
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Abstract

Abstract Self-extinguishing, thermoplastic polyphenylene ether/polyamide molding materials contain, as essential components, (A) from 10 to 90% by weight of component (A), which consists of (A 1 ) from 70 to 99% by weight of a modified polyphenylene ether, (A 2 ) from 1 to 30% by weight of a compound containing bound phosphorus, the percentages by weight being based on the total weight of component (A), and (B) from 90 to 10% by weight of component (B), which consists of (B 1 ) from 80 to 99% by weight of one or more polyamides and (B 2 ) from 1 to 20% by weight of one or more compounds containing a bound triazine radical and from the group consisting of cyanuric acid and its derivatives.

Inventors

  • 👤 Christof Taubitz
  • 👤 Hermann Gausepohl
  • 👤 Klaus Boehlke

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 10:41
CPC Classifications
C; C08; C08L; C08L51/00; C08L51/08; C08G; C08G65/00; C08G65/34; C08G65/48; C08G65/485; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/126; C08L77/00

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 313 words
A self-extinguishing, thermoplastic polyphenylene ether/polyamide molding material containing, as essential components, (A) from 10 to 90% by weight of component (A), which consists of (A1) from 70 to 99% by weight of a modified polyphenylene ether prepared from (a 1 ) 4.95-99.95% by weight of polyphenylene ether, (a 2 ) 0-90% by weight of a vinylaromatic polymer, (a 3 ) 0.05-10% by weight of (a 31 ) fumaric acid and/or (a 32 ) a maleimide of the formula I ##STR12## where R 1 , R 2 and R 3 are each hydrogen or an alkyl, alkoxy, cycloalkyl, alkenyl, aryl, arylene or alkylene group of 1 to 12 carbon atoms, and/or (a 33 ) a monomer containing amide groups and a polymerizable double bond and/or (a 34 ) a monomer containing lactam groups and a polymerizable double bond and/or (a 35 ) a half ester or half amide of an α,β-unsaturated dicarboxylic acid, (a 4 ) 0-80% by weight of further monomers capable of grafting and (a 5 ) 0-20% by weight of a free radical initiator, and (A2) from 1 to 30% by weight of a compound containing bound phosphorus, the percentages by weight being based on the total weight of components (A1) and (A2), (B) from 90 to 10% by weight of component (B), which consists of (B1) from 80 to 99% by weight of one or more polyamides and (B2) from 1 to 20% by weight of one or more compounds containing a triazine radical and from the group consisting of cyanuric acid and its derivatives, the percentages by weight being based on the total weight of components (B1) and (B2), (C) from 0 to 30% by weight of one or more impact-modifying rubbers and (D) from 0 to 60% by weight of one or more additives, the percentages by weight of components (A) to (D) summing to 100% by weight.
Claim 2
Dependent Claim 313 words
A self-extinguishing, thermoplastic polyphenylene ether/polyamide molding material containing, as essential components, (A) from 10 to 90% by weight of component (A), which consists of (A1) from 70 to 99% by weight of a modified polyphenylene ether prepared from (a 1 ) 4.95-99.95% by weight of polyphenylene ether, (a 2 ) 0-90% by weight of a vinylaromatic polymer, (a 3 ) 0.05-10% by weight of (a 31 ) fumaric acid and/or (a 32 ) a maleimide of the formula I ##STR12## where R 1 , R 2 and R 3 are each hydrogen or an alkyl, alkoxy, cycloalkyl, alkenyl, aryl, arylene or alkylene group of 1 to 12 carbon atoms, and/or (a 33 ) a monomer containing amide groups and a polymerizable double bond and/or (a 34 ) a monomer containing lactam groups and a polymerizable double bond and/or (a 35 ) a half ester or half amide of an α,β-unsaturated dicarboxylic acid, (a 4 ) 0-80% by weight of further monomers capable of grafting and (a 5 ) 0-20% by weight of a free radical initiator, and (A2) from 1 to 30% by weight of a compound containing bound phosphorus, the percentages by weight being based on the total weight of components (A1) and (A2), (B) from 90 to 10% by weight of component (B), which consists of (B1) from 80 to 99% by weight of one or more polyamides and (B2) from 1 to 20% by weight of one or more compounds containing a triazine radical and from the group consisting of cyanuric acid and its derivatives, the percentages by weight being based on the total weight of components (B1) and (B2), (C) from 0 to 30% by weight of one or more impact-modifying rubbers and (D) from 0 to 60% by weight of one or more additives, the percentages by weight of components (A) to (D) summing to 100% by weight.
Claim 3
Dependent Claim 23 words
A self-extinguishing, thermoplastic polyphenylene ether/polyamide molding material as claimed in claim 1, wherein component A1 is a polyphenylene ether modified with fumaric acid.
Claim 4
Dependent Claim 22 words
A self-extinguishing, thermoplastic polyphenylene ether/polyamide molding material as claimed in claim 1, wherein component A2 consists of triphenylphosphine oxide and/or triphenyl phosphate.
Claim 5
Dependent Claim 29 words
A self-extinguishing, thermoplastic polyphenylene ether/polyamide molding material as claimed in claim 1, wherein component B1 consists of polycaprolactam having a weight average molecular weight of from 10,000 to 80,000.
Claim 6
Dependent Claim 20 words
A self-extinguishing, thermoplastic polyphenylene ether/polyamide molding material as claimed in claim 1, wherein component B2 consists of melamine and/or melamine/cyanurate.
Claim 7
Dependent Claim 201 words
A self-extinguishing, thermoplastic polyphenylene ether/polyamide molding material containing, as essential components, (A) from 10 to 90% by weight of component (A), which consists of (A1) from 70 to 99% by weight of a modified polyphenylene ether prepared from (a 1 ) 4.95-99.95% by weight of polyphenylene ether, (a 2 ) 0-90% by weight of a vinylaromatic polymer and (a 3 ) 0.05-10% by weight of fumaric acid and (A2) from 1 to 30% by weight of a compound from the group consisting of triphenylphosphine oxide and/or triphenyl phosphate, the percentages by weight being based on the total weight of component (A), (B) from 90 to 10% by weight of component (B), which consists of (B1) from 80 to 99% by weight of one or more polycaprolactams having a weight average molecular weight of 10,000 to 80,000 and (B2) from 1 to 20% by weight of melamine and/or melamine cyanurate, the percentages by weight being based on the weight of component (B), (C) from 0 to 30% by weight of one or more impact-modifying rubbers and (D) from 0 to 40% by weight of one or more additives, the percentages by weight of components (A) to (D) summing to 100% by weight.
Claim 8
Dependent Claim 201 words
A self-extinguishing, thermoplastic polyphenylene ether/polyamide molding material containing, as essential components, (A) from 10 to 90% by weight of component (A), which consists of (A1) from 70 to 99% by weight of a modified polyphenylene ether prepared from (a 1 ) 4.95-99.95% by weight of polyphenylene ether, (a 2 ) 0-90% by weight of a vinylaromatic polymer and (a 3 ) 0.05-10% by weight of fumaric acid and (A2) from 1 to 30% by weight of a compound from the group consisting of triphenylphosphine oxide and/or triphenyl phosphate, the percentages by weight being based on the total weight of component (A), (B) from 90 to 10% by weight of component (B), which consists of (B1) from 80 to 99% by weight of one or more polycaprolactams having a weight average molecular weight of 10,000 to 80,000 and (B2) from 1 to 20% by weight of melamine and/or melamine cyanurate, the percentages by weight being based on the weight of component (B), (C) from 0 to 30% by weight of one or more impact-modifying rubbers and (D) from 0 to 40% by weight of one or more additives, the percentages by weight of components (A) to (D) summing to 100% by weight.
Claim 9
Dependent Claim 16 words
A molding produced from a self-extinguishing, thermoplastic polyphenylene ether/polyamide molding material as claimed in claim 1.

References Cited (Backward Citations)

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EP0101207A1 Cited
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US4525505A Cited
EP0164767A2 Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-09-11 1993-03-13 1993-09-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-09-11 1997-03-13 1997-09-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-09-11 2001-03-13 2001-09-12 $7700.00 Window Closed / Lapsed

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