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US4865958A Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic recording material comprising leuco dye for cold silver image tone

Assignee: Eastman Kodak Co
•
Filing: 1988-08-18
•
Granted: 1989-09-12
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Expires: 2008-08-18
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Abstract

Abstract A photographic recording material is described which comprises a leuco dye which is capable of generating a blue tone in a developed silver image.

Inventors

  • 👤 Thomas I. Abbott
  • 👤 Robert E. Dickerson
  • 👤 Michael P. Youngblood

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 13:42
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/26; Y; Y10; Y10S; Y10S430/00; Y10S430/166

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 249 words
A photographic recording material comprising a silver halide emulsion layer and a leuco compounds which, upon photographic processing, is capable of generating in an imagewise manner a blue tone in developed silver images wherein the leuco dye has the structural formula: ##STR4## wherein: R 1 is an unsubstituted or a substituted aliphatic group having from 1 to about 20 carbon atoms; R 2 is hydrogen; an unsubstituted or a substituted, straight or branched chain alkyl group having from 1 to about 10 carbon atoms; an unsubstituted or a substituted cycloalkyl group having from 3 to about 8 carbon atoms in the ring; or an aryl group having from 6 to about 10 carbon atoms; R 3 is hydrogen; an unsubstituted or a substituted alky group having from 1 to about 10 carbon atoms; an unsubstituted or a substituted aryl group having from 6 to about 10 carbon atoms; an unsubstituted or a substituted cycloalkyl group having from 3 to about 8 carbon atoms in the ring; nitro; or cyano; R 4 is as defined for R 3 , or R 4 can be hydroxy, sulfo or carboxy; R 5 is hydroxylalkyl; alkylsulfonamidoalkyl; alkoxyalkyl; or alkylsulfonic acid wherein the akyl or alkoxy group has from 1 to about 12 carbon atoms or an aryl group having from 6 to about 10 carbon atoms; R 6 is as defined for R 5 ; R 7 is hydrogen, alkyl, alkoxy, sulfoalkoxy or sulfoaryl; and R 8 as defined for R 7 .
Claim 2
Dependent Claim 249 words
A photographic recording material comprising a silver halide emulsion layer and a leuco compounds which, upon photographic processing, is capable of generating in an imagewise manner a blue tone in developed silver images wherein the leuco dye has the structural formula: ##STR4## wherein: R 1 is an unsubstituted or a substituted aliphatic group having from 1 to about 20 carbon atoms; R 2 is hydrogen; an unsubstituted or a substituted, straight or branched chain alkyl group having from 1 to about 10 carbon atoms; an unsubstituted or a substituted cycloalkyl group having from 3 to about 8 carbon atoms in the ring; or an aryl group having from 6 to about 10 carbon atoms; R 3 is hydrogen; an unsubstituted or a substituted alky group having from 1 to about 10 carbon atoms; an unsubstituted or a substituted aryl group having from 6 to about 10 carbon atoms; an unsubstituted or a substituted cycloalkyl group having from 3 to about 8 carbon atoms in the ring; nitro; or cyano; R 4 is as defined for R 3 , or R 4 can be hydroxy, sulfo or carboxy; R 5 is hydroxylalkyl; alkylsulfonamidoalkyl; alkoxyalkyl; or alkylsulfonic acid wherein the akyl or alkoxy group has from 1 to about 12 carbon atoms or an aryl group having from 6 to about 10 carbon atoms; R 6 is as defined for R 5 ; R 7 is hydrogen, alkyl, alkoxy, sulfoalkoxy or sulfoaryl; and R 8 as defined for R 7 .
Claim 3
Dependent Claim 26 words
A recording material according to claim 1 wherein R 1 is a straight or branched chain alkyl group having from 1 to about 20 carbon atoms.
Claim 4
Dependent Claim 18 words
A recording material according to claim 2 wherein R 1 comprises from 1 to about 12 carbon atoms.
Claim 5
Dependent Claim 18 words
A recording material according to claim 3 wherein R 1 is substituted with at least one halogen atom.
Claim 6
Dependent Claim 13 words
A recording material according to claim 4 wherein the halogen atom is fluorine.
Claim 7
Dependent Claim 22 words
A recording material according to claim 1 wherein R 2 is an alkyl group comprising from 1 to about 10 carbon atoms.
Claim 8
Dependent Claim 24 words
A recording material according to claim 1 wherein R 3 and R 4 are alkyl groups comprising from 1 to about 10 carbon atoms.
Claim 9
Dependent Claim 16 words
A recording material according to claim 1 wherein the leuco dye has the structural formula: ##STR5##

References Cited (Backward Citations)

US3880658A Cited
US3938995A Cited
US4035184A Cited
US4022617A Cited
JPS56133733A Cited
US4374921A Cited
US4390606A Cited
US4423126A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-09-11 1993-03-13 1993-09-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-09-11 1997-03-13 1997-09-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-09-11 2001-03-13 2001-09-12 $7700.00 Window Closed / Lapsed

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