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US4865805A Expired / Lapsed US ⏱️ 0.0 years remaining

Low-sulfur, lead-free alloy

Assignee: Frema Inc
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Filing: 1988-11-15
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Granted: 1989-09-12
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Expires: 2008-11-15
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Abstract

Abstract Composition and method for producing a low-sulphur, free-machining steel, substantially free of lead and including in weight percent about 0.05-0.40 copper, 0.005-0.040 tellurium, 0.002-0.35 bismuth, 0.002-0.05 tin, up to 0.55 carbon, and less than 0.25 sulphur, traces (up to about 0.005 weight percent) of barium, and the balance being iron. The elements bismuth, tellurium and tin are added as a molten alloy to the molten steel and uniformly distributed therethrough. The elements copper and barium can be added separately into the steel stream ahead of the molten addition inflow. The mass is then cooled to provide a solid metal casting substantially free of blemishes and free of surface checking and tearing. The casting is characterized by enhanced machining properties.

Inventors

  • 👤 Michael O. Holowaty

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 20:46
CPC Classifications
C; C22; C22C; C22C38/00; C22C38/60

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 97 words
The method of casting steel into billets, blooms, or ingots or lead-free, low-sulfur, free-machining steel, said method comprising the steps of: preparing a heat of low-sulfur, lead-free, copper-bearing, liquid steel, pre-melting, in combination, pre-measured quantities of alloying elements including bismuth, tin and tellurium in specific concentrational ratios, to provide a liquid bismuth alloy, gravitationally adding and intimately blending the liquid alloy into the liquid steel under ambient conditions and at a metered rate to provide a liquid homogeneous melt, and promptly cooling the melt in a continuous process to form a solid steel ingot, billet or bloom.
Claim 2
Independent Claim 97 words
The method of casting steel into billets, blooms, or ingots or lead-free, low-sulfur, free-machining steel, said method comprising the steps of: preparing a heat of low-sulfur, lead-free, copper-bearing, liquid steel, pre-melting, in combination, pre-measured quantities of alloying elements including bismuth, tin and tellurium in specific concentrational ratios, to provide a liquid bismuth alloy, gravitationally adding and intimately blending the liquid alloy into the liquid steel under ambient conditions and at a metered rate to provide a liquid homogeneous melt, and promptly cooling the melt in a continuous process to form a solid steel ingot, billet or bloom.
Claim 3
Dependent Claim 50 words
A process as set forth in claim 1 and further comprising the method of increasing copper concentration in the steel, said method including the step of rateably feeding solid copper in wire or rod form into the liquid stream prior to blending the liquid bismuth alloy into the liquid steel.
Claim 4
Dependent Claim 132 words
In a continuous process wherein alloying ingredients are added to molten steel to provide a lead-free, low-sulfur, free-machining steel, a method for enhancing machining property characteristics of said steel, said method including the steps of: preparing a melt consisting essentially of a molten alloy containing elements selected from the group consisting of bismuth, tellurium, and tin and mixtures thereof in a selectable concentrational ratio, gravitationally adding said molten alloy to a flowing stream of molten steel under ambient conditions and at a controlled and metered rate, and thus uniformly distributing said molten alloy through the flowing stream of the molten steel to form an essentially homogeneous blend while teaming said blend into a mold, and promptly chilling said blend in said mold to provide a solid metal cast having enhanced machining properties.
Claim 5
Dependent Claim 132 words
In a continuous process wherein alloying ingredients are added to molten steel to provide a lead-free, low-sulfur, free-machining steel, a method for enhancing machining property characteristics of said steel, said method including the steps of: preparing a melt consisting essentially of a molten alloy containing elements selected from the group consisting of bismuth, tellurium, and tin and mixtures thereof in a selectable concentrational ratio, gravitationally adding said molten alloy to a flowing stream of molten steel under ambient conditions and at a controlled and metered rate, and thus uniformly distributing said molten alloy through the flowing stream of the molten steel to form an essentially homogeneous blend while teaming said blend into a mold, and promptly chilling said blend in said mold to provide a solid metal cast having enhanced machining properties.
Claim 6
Dependent Claim 45 words
The method as set forth in claim 1 and further comprising the steps of preparing successive heats of liquid steel in an uninterrupted sequence and adding the desired ratios of alloying elements to each successive, uninterrupted heat in turn to achieve continuous casting of steel.
Claim 7
Dependent Claim 41 words
The method as set forth in claim 3 and further comprising the steps of preparing successive heats of liquid steel in an uninterrupted sequence and adding alloying elements to each successive, uninterrupted heat in turn to achieve continuous casting of steel.

References Cited (Backward Citations)

US4147533A Cited
US4751047A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-09-11 1993-03-13 1993-09-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-09-11 1997-03-13 1997-09-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-09-11 2001-03-13 2001-09-12 $7700.00 Window Closed / Lapsed

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