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US4865685A Expired / Lapsed US ⏱️ 0.0 years remaining

Dry etching of silicon carbide

Assignee: North Carolina State University
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Filing: 1987-11-03
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Granted: 1989-09-12
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Expires: 2007-11-03
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Abstract

Abstract The invention comprises a method of etching silicon carbide targets. In one embodiment, a reactive ion plasma is formed from a gas which is easily dissociated into its elemental species in the plasma, for which all of the dissociated elemental species are volatile in the plasma, and for which at least one of the elemental species is reactive with silicon carbide. The silicon carbide target to be etched is positioned on one of the electrodes which is formed from a material with a low sputter yield and which material reacts with a dissociated species to thereby prevent contamination of the target with either sputtered materials from the electrode or polymerized species from the plasma.

Inventors

  • 👤 John W. Palmour

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 20:24
CPC Classifications
H; H10; H10P; H10P50/00; H10P50/20; H10P50/24; H10P50/242; Y; Y10; Y10S; Y10S438/00; Y10S438/931

Claims Analysis

Total Claims: 36
Claim 1
Independent Claim 167 words
A method of etching a silicon carbide target, the method comprising: applying a plasma generating potential across two electrodes; generating a plasma between the two electrodes by introducing a gas between the electrodes, and wherein the gas is easily dissociated substantially into its elemental species in the plasma and wherein substantially all of the dissociated species from the gas are volatile in the plasma and wherein at least one of the dissociated species is reactive with silicon carbide; and positioning a silicon carbide target to be etched on one of the electrodes, and wherein the electrode is formed from a material with a low sputter yield and wherein the electrode material is reactive with the dissociated species; and reacting the plasma with the silicon carbide to thereby etch the silicon carbide while the reaction of the dissociated species with the electrode, and the electrode's low sputter yield prevents contamination of the target with either sputtered materials from the supporting electrode or unreacted dissociated species from the plasma.
Claim 2
Independent Claim 167 words
A method of etching a silicon carbide target, the method comprising: applying a plasma generating potential across two electrodes; generating a plasma between the two electrodes by introducing a gas between the electrodes, and wherein the gas is easily dissociated substantially into its elemental species in the plasma and wherein substantially all of the dissociated species from the gas are volatile in the plasma and wherein at least one of the dissociated species is reactive with silicon carbide; and positioning a silicon carbide target to be etched on one of the electrodes, and wherein the electrode is formed from a material with a low sputter yield and wherein the electrode material is reactive with the dissociated species; and reacting the plasma with the silicon carbide to thereby etch the silicon carbide while the reaction of the dissociated species with the electrode, and the electrode's low sputter yield prevents contamination of the target with either sputtered materials from the supporting electrode or unreacted dissociated species from the plasma.
Claim 3
Dependent Claim 22 words
A method according to claim 1 wherein the step of generating a plasma comprises forming a reactive ion plasma from nitrogen trifluoride.
Claim 4
Dependent Claim 24 words
A method according to claim 2 wherein the step of generating a reactive ion plasma comprises applying a direct current bias to the plasma.
Claim 5
Dependent Claim 29 words
A method according to claim 1 wherein the step of positioning a silicon carbide target on one of the electrodes comprises positioning the silicon carbide target on the cathode.
Claim 6
Dependent Claim 28 words
A method according to claim 4 wherein the step of positioning the silicon carbide target on the cathode comprises positioning the silicon carbide target on a carbon cathode.
Claim 7
Dependent Claim 22 words
A method according to claim 1 wherein the step of positioning a silicon carbide target comprises positioning a silicon carbide thin film.
Claim 8
Dependent Claim 25 words
A method according to claim 6 wherein the step of positioning a silicon carbide thin film comprises positioning a thin film of beta silicon carbide.
Claim 9
Dependent Claim 25 words
A method according to claim 6 wherein the step of positioning a silicon carbide thin film comprises positioning a thin film of alpha silicon carbide.
Claim 10
Dependent Claim 29 words
A method according to claim 1 wherein the step of applying a plasma generating potential comprises applying between about 10 and about 400 watts of power to the electrodes.
Claim 11
Dependent Claim 35 words
A method according to claim 1 wherein the step of applying a plasma generating potential comprises applying a power density of between about 0.04 and about 2 watts per square centimeter to the powered electrode.
Claim 12
Dependent Claim 35 words
A method according to claim 1 wherein the step of applying a plasma generating potential comprises applying a power density of between about 0.4 and about 0.9 watts per square centimeter to the powered electrode.
Claim 13
Dependent Claim 32 words
A method according to claim 1 wherein the step of introducing a gas between the electrodes comprises introducing the gas at a pressure of between about 5 milliTorr and about 10 Torr.
Claim 14
Dependent Claim 27 words
A method according to claim 1 wherein the step of introducing a gas between the electrodes comprises introducing the gas at a pressure of about 40 milliTorr.
Claim 15
Dependent Claim 33 words
A method according to claim 1 wherein the step of introducing a gas comprises introducing a gas at a flow rate of between about 1 and about 500 standard cubic centimeters per minute.
Claim 16
Dependent Claim 33 words
A method according to claim 1 wherein the step of introducing a gas comprises introducing a gas at a flow rate of between about 20 and about 60 standard cubic centimeters per minute.
Claim 17
Dependent Claim 29 words
A method according to claim 1 wherein the step of introducing a gas comprises introducing a gas at a flow rate of about 25 standard cubic centimeters per minute.
Claim 18
Dependent Claim 22 words
A method according to claim 1 wherein the step of introducing a gas comprises introducing a mixture of nitrogen trifluoride and oxygen.
Claim 19
Dependent Claim 22 words
A method according to claim 1 wherein the step of introducing a gas comprises introducing a mixture of nitrogen trifluoride and argon.
Claim 20
Dependent Claim 23 words
A method according to claim 1 wherein the step of introducing a gas comprises introducing a mixture of nitrogen trifluoride, oxygen and argon.
Claim 21
Independent Claim 118 words
A method of etching of a silicon carbide target comprising: applying a plasma generating potential across an anode and a carbon cathode; generating a plasma between the anode and the carbon cathode by introducing nitrogen trifluoride therebetween; positioning a silicon carbide target to be etched on the carbon cathode whereby the carbon cathode exhibits a low sputter yield and is reactive with dissociated fluorine from the nitrogen trifluoride; and reacting the plasma with the silicon carbide to thereby etch the silicon carbide while the reaction of dissociated fluorine with the carbon cathode, and the cathode's low sputter yield prevents contamination of the target with either sputtered carbon materials from the cathode or polymerized fluorine species from the plasma.
Claim 22
Independent Claim 118 words
A method of etching of a silicon carbide target comprising: applying a plasma generating potential across an anode and a carbon cathode; generating a plasma between the anode and the carbon cathode by introducing nitrogen trifluoride therebetween; positioning a silicon carbide target to be etched on the carbon cathode whereby the carbon cathode exhibits a low sputter yield and is reactive with dissociated fluorine from the nitrogen trifluoride; and reacting the plasma with the silicon carbide to thereby etch the silicon carbide while the reaction of dissociated fluorine with the carbon cathode, and the cathode's low sputter yield prevents contamination of the target with either sputtered carbon materials from the cathode or polymerized fluorine species from the plasma.
Claim 23
Dependent Claim 22 words
A method according to claim 20 wherein the step of positioning a silicon carbide target comprises positioning a doped silcon carbide target.
Claim 24
Dependent Claim 24 words
A method according to claim 21 wherein the step of positioning a doped silicon carbide target comprises positioning a doped beta silicon carbide target.
Claim 25
Dependent Claim 24 words
A method according to claim 21 wherein the step of positioning a doped silicon carbide target comprises positioning a doped alpha silicon carbide target.
Claim 26
Dependent Claim 23 words
A method according to claim 20 wherein the step of generating a plasma further comprises applying a direct current bias to the plasma.
Claim 27
Independent Claim 182 words
A method of reactive ion beam etching of a silicon carbide target comprising: applying a plasma generating potential and a direct current bias across two electrodes positioned in a source chamber; generating a reactive ion plasma between the two electrodes in the source chamber by introducing a gas which is easily dissociated into its elemental species in the plasma and wherein substantially all of the dissociated species are volatile in the plasma and wherein at least one of the species is reactive with silicon carbide; positioning a silicon carbide target in a target chamber on a support formed from a material with a low sputter yield and wherein the material reacts with the elemental species in the plasma to thereby prevent contamination of the target with either sputtered materials from the support or polymerized species from the plasma, and wherein the target chamber is in communication with the source chamber; and applying a negative bias to the target so that a reactive ion plasma beam is directed from the source chamber to the target chamber to thereby etch the silicon carbide target.
Claim 28
Independent Claim 182 words
A method of reactive ion beam etching of a silicon carbide target comprising: applying a plasma generating potential and a direct current bias across two electrodes positioned in a source chamber; generating a reactive ion plasma between the two electrodes in the source chamber by introducing a gas which is easily dissociated into its elemental species in the plasma and wherein substantially all of the dissociated species are volatile in the plasma and wherein at least one of the species is reactive with silicon carbide; positioning a silicon carbide target in a target chamber on a support formed from a material with a low sputter yield and wherein the material reacts with the elemental species in the plasma to thereby prevent contamination of the target with either sputtered materials from the support or polymerized species from the plasma, and wherein the target chamber is in communication with the source chamber; and applying a negative bias to the target so that a reactive ion plasma beam is directed from the source chamber to the target chamber to thereby etch the silicon carbide target.
Claim 29
Dependent Claim 17 words
A method according to claim 25 wherein the step of introducing a gas comprises introducing nitrogen trifluoride.
Claim 30
Dependent Claim 25 words
A method according to claim 25 wherein the step of positioning a silicon carbide target comprises positioning the silicon carbide target on a carbon support.
Claim 31
Dependent Claim 20 words
A method according to claim 25 further comprising maintaining the target chamber at a lesser pressure than the source chamber.
Claim 32
Independent Claim 176 words
A method of patterning silicon carbide in the formation of electronic devices using reactive ion etching, the method comprising forming a masked pattern on a silicon carbide substrate; positioning the masked silicon carbide substrate as a target on a cathode in a reactive ion plasma system having an anode opposite the cathode; and applying a plasma generating potential and a direct current bias across the anode and cathode in the reactive ion system; generating plasma in the system by introducing a gas which is easily dissociated in the plasma and wherein substantially all of the dissociated species are volatile in the plasma and wherein at least one of the dissociated species is reactive with silicon carbide; wherein the cathode is formed from a material with a low sputter yield and wherein the material reacts with the dissociated species in the plasma to thereby prevent contamination of the target with either sputtered materials from the cathode or polymerized species from the plasma; and reacting the plasma with the silicon carbide substrate to thereby etch the silicon carbide.
Claim 33
Independent Claim 176 words
A method of patterning silicon carbide in the formation of electronic devices using reactive ion etching, the method comprising forming a masked pattern on a silicon carbide substrate; positioning the masked silicon carbide substrate as a target on a cathode in a reactive ion plasma system having an anode opposite the cathode; and applying a plasma generating potential and a direct current bias across the anode and cathode in the reactive ion system; generating plasma in the system by introducing a gas which is easily dissociated in the plasma and wherein substantially all of the dissociated species are volatile in the plasma and wherein at least one of the dissociated species is reactive with silicon carbide; wherein the cathode is formed from a material with a low sputter yield and wherein the material reacts with the dissociated species in the plasma to thereby prevent contamination of the target with either sputtered materials from the cathode or polymerized species from the plasma; and reacting the plasma with the silicon carbide substrate to thereby etch the silicon carbide.
Claim 34
Dependent Claim 30 words
A method according to claim 29 further comprising the step of removing the mask from the silicon carbide substrate following the step of reacting the plasma with the silicon carbide.
Claim 35
Dependent Claim 17 words
A method according to claim 29 wherein the step of introducing a gas comprises introducing nitrogen trifluoride.
Claim 36
Dependent Claim 30 words
A method according to claim 29 wherein the step of positioning the silicon carbide masked substrate on the cathode comprises positioning the masked silicon carbide substrate on a carbon cathode.

References Cited (Backward Citations)

US3398033A Cited
US4351894A Cited
US4560642A Cited
US4595453A Cited
US4735920A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-09-11 1993-03-13 1993-09-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-09-11 1997-03-13 1997-09-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-09-11 2001-03-13 2001-09-12 $7700.00 Window Closed / Lapsed

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