US4863813A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Primary source of electrical energy using a mixture of fuel and oxidizer
Assignee: Iconectiv LLC
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Filing: 1988-09-15
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Granted: 1989-09-05
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Expires: 2008-09-15
Abstract
Abstract A solid electrolyte fuel cell capable of operating with a mixture of an oxidizer and a fuel includes a permeable catalytic electrode and an impermeable catalytic electrode separated by an electron insulating, ion conducting, gas permeable solid electrolyte. The device produces charge flow in an external circuit when the permeable electrode is exposed to a mixture including an oxidizer and a fuel such as hydrogen, methane or methanol. The solid electrolyte can be a hydrated aluminum oxide, primarily of the pseudoboehmite structure and either electrode can be Pt or Pd. The solid electrolyte can be produced by exposing a bulk aluminum surface or a deposited layer of aluminum to water or water vapor or by exposing an anodically oxidized layer of aluminum oxide to water vapor. The device is produced in thin film form and can be produced by techniques compatible with thin film device fabrication. The magnitude and direction of the charge flow is dependent on the particular fuel, so that the device can serve as a species selective, gas sensor which does not require the external application of sensing power in order to produce a measurable voltage.
Inventors
- 👤 Christopher K. Dyer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 10:08
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/406; G01N27/407; G01N27/4071; H; H01; H01M; H01M8/00; H01M8/10; H01M8/1016; H01M8/1018; H01M8/102; H01M8/1023; H01M8/1004; H01M8/1007; H01M8/1009; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
98 words
A device which is a source of electrical current comprising a first electrode and a second electrode separated by and in contact with a solid electrolyte body characterized in that the first electrode is permeable to an oxidizer and a fuel, the second electrode is impermeable to the oxidizer and the fuel and the solid electrolyte body consists essentially of an electron insulating material which is also ionically conducting to at least a first ionic species and which material is permeable to the oxidizer, the fuel and products of the electrochemical reactions of the oxidizer and the fuel.
Claim 2
Independent Claim
98 words
A device which is a source of electrical current comprising a first electrode and a second electrode separated by and in contact with a solid electrolyte body characterized in that the first electrode is permeable to an oxidizer and a fuel, the second electrode is impermeable to the oxidizer and the fuel and the solid electrolyte body consists essentially of an electron insulating material which is also ionically conducting to at least a first ionic species and which material is permeable to the oxidizer, the fuel and products of the electrochemical reactions of the oxidizer and the fuel.
Claim 3
Dependent Claim
13 words
A device of claim 1 in which the said species is ionic hydrogen.
Claim 4
Dependent Claim
21 words
A device of claim 1 including means for exposing the first electrode to a mixture comprising the oxidizer and the fuel.
Claim 5
Dependent Claim
13 words
A device of claim 1 in which the oxidizer and fuel are gaseous.
Claim 6
Dependent Claim
24 words
A device of claim 1 in which the said material consists essentially of a hydrated oxide of aluminum consisting primarily of the pseudoboehmite structure.
Claim 7
Dependent Claim
18 words
A device of claim 5 in which the said material is at least 50% of the pseudoboehmite structure.
Claim 8
Dependent Claim
20 words
A device of claim 5 in which the solid electrolyte body is from 30 Angstroms to 10 microns in thickness.
Claim 9
Dependent Claim
17 words
A device of claim 1 in which the said material consists essentially of a crabon based polymer.
Claim 10
Dependent Claim
14 words
A device of claim 8 in which the carbon based polymer is polyacrylic acid.
Claim 11
Dependent Claim
29 words
A device of claim 1 in which the oxidizing gas is oxygen and the fuel is at least one member of the group consisting of hydrogen, methane and methanol.
Claim 12
Dependent Claim
21 words
A device of claim 1 including means for electrically connecting the first electrode and the second electrode to a utilizing device.
Claim 13
Dependent Claim
20 words
A device of claim 10 in which the solid electrolyte body is from 30 Angstroms to 1 millimeter in thickness.
Claim 14
Dependent Claim
32 words
A device of claim 12 in which the utilizing device includes means for differentiating between the presence or absence of a flow of electrons and the direction of the flow of electrons.
Claim 15
Dependent Claim
25 words
A device of claim 1 in which the said material is produced by a method including exposing a metallic aluminum body to H 2 O.
Claim 16
Dependent Claim
20 words
A device of claim 14 in which the temperature of the aluminum during the exposure is at least 20° C.
Claim 17
Dependent Claim
26 words
A device of claim 2 in which the first electrode and the second electrode consist essentially of Pt or Pd or alloys of Pt and Pd.
Claim 18
Dependent Claim
41 words
A device of claim 1 in which the said material is produced by a method including the steps of anodizing a metallic aluminum body to produce an aluminum oxide film and subsequently exposing the aluminum oxide film to H 2 O.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-09-04 | 1993-03-06 | 1993-09-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-09-04 | 1997-03-06 | 1997-09-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-09-04 | 2001-03-06 | 2001-09-05 | $7700.00 | Window Closed / Lapsed |