US4863679A
Expired / Lapsed
US
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Cladding tube for nuclear fuel and nuclear fuel element having this cladding tube
Assignee: Toshiba Corp
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Filing: 1987-06-12
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Granted: 1989-09-05
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Expires: 2007-06-12
Abstract
Abstract Disclosed are a cladding tube for a nuclear fuel and a nuclear fuel element incorporating the cladding tube. The cladding tube consists of an inner zirconium liner layer and an outer zirconium alloy layer. The cladding tube has at least one of the following features: (I) the ratio a/b of the oxygen content a to iron content b in the zirconium liner layer is greater than 1.0, (II) the zirconium liner layer is made of a zirconium into the matrix of which impurities are dissolved, and (III) the second phase particles having microscopic sizes and dispersed in the inner surface of the zirconium liner layer and/or the outer surface of the zirconium alloy layer have been removed substantially. Owing to these features, undesirable stress corrosion cracking and local corrosion are remarkably suppressed in the cladding tube and the nuclear fuel element of the invention.
Inventors
- 👤 Hiromichi Imahashi
- 👤 Toshio Kubo
- 👤 Kazumi Asahi
- 👤 Hideyuki Mukai
- 👤 Keizo Ogata
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 02:24
CPC Classifications
G; G21; G21C; G21C3/00; G21C3/02; G21C3/04; G21C3/16; G21C3/20; Y; Y02; Y02E; Y02E30/00; Y02E30/30
Claims Analysis
Total Claims: 29
Claim 1
Independent Claim
90 words
A cladding tube for nuclear fuel comprising an inner zirconium liner layer and an outer zirconium alloy layer, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, and that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layer of zirconium in which said ratio is not greater that 1.0.
Claim 2
Dependent Claim
90 words
A cladding tube for nuclear fuel comprising an inner zirconium liner layer and an outer zirconium alloy layer, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, and that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layer of zirconium in which said ratio is not greater that 1.0.
Claim 3
Dependent Claim
24 words
A cladding tube for nuclear fuel as claimed in claim 1, consisting of said inner zirconium liner layer and said outer zirconium alloy layer.
Claim 4
Dependent Claim
27 words
A cladding tube for nuclear fuel as claimed in claim 1, wherein said inner zirconium liner layer consists of zirconium with oxygen and iron, and other impurities.
Claim 5
Dependent Claim
26 words
A cladding tube for nuclear fuel as claimed in claim 1, wherein said inner zirconium liner layer is positioned directly on the outer zirconium alloy layer.
Claim 6
Dependent Claim
109 words
A cladding tube for nuclear fuel comprising an inner zirconium liner layer and an outer zirconium alloy layer, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layers of zirconium in which said ratio is not greater that 1.0; and that a material of said zirconium liner layer is a matrix of zirconium into which matrix impurities are dissolved.
Claim 7
Dependent Claim
109 words
A cladding tube for nuclear fuel comprising an inner zirconium liner layer and an outer zirconium alloy layer, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layers of zirconium in which said ratio is not greater that 1.0; and that a material of said zirconium liner layer is a matrix of zirconium into which matrix impurities are dissolved.
Claim 8
Dependent Claim
40 words
A cladding tube for nuclear fuel as claimed in claim 2, wherein said impurities are elements, selected from the group consisting of Fe, Cr, Ni, Si, W, C, O, Hf, H, N, and Al, which form intermetallic compounds with zirconium.
Claim 9
Dependent Claim
26 words
A cladding tube for nuclear fuel as claimed in claim 5, wherein said inner zirconium liner layer is positioned directly on the outer zirconium alloy layer.
Claim 10
Dependent Claim
172 words
A cladding tube for nuclear fuel comprising an inner zirconium liner layer and an outer zirconium alloy layer, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layers of zirconium in which said ratio is not greater that 1.0; that a mean distribution density of the second phase particles, which are containing Fe or Ni or Cr, in an inside portion of said zirconium liner layer is smaller than that of an outside portion of said zirconium liner layer; and that a mean distribution density of the second phase particles, which are containing Fe or Ni or Cr or Sn, in an outside portion of said zirconium alloy layer is smaller than that of an inside portion of said zirconium alloy layer.
Claim 11
Dependent Claim
172 words
A cladding tube for nuclear fuel comprising an inner zirconium liner layer and an outer zirconium alloy layer, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layers of zirconium in which said ratio is not greater that 1.0; that a mean distribution density of the second phase particles, which are containing Fe or Ni or Cr, in an inside portion of said zirconium liner layer is smaller than that of an outside portion of said zirconium liner layer; and that a mean distribution density of the second phase particles, which are containing Fe or Ni or Cr or Sn, in an outside portion of said zirconium alloy layer is smaller than that of an inside portion of said zirconium alloy layer.
Claim 12
Dependent Claim
26 words
A cladding tube for nuclear fuel as claimed in claim 8, wherein said inner zirconium liner layer is positioned directly on the outer zirconium alloy layer.
Claim 13
Dependent Claim
61 words
A cladding tube for nuclear fuel as claimed in claim 8, wherein Fe or Ni or Cr contained in second phase particles in the zirconium liner layer are impurities in the liner layer, and wherein Fe or Ni or Cr or Sn contained in the second phase particles in the zirconium alloy layer are impurities contained in the zirconium alloy layer.
Claim 14
Dependent Claim
41 words
A cladding tube for nuclear fuel as claimed in claim 8, wherein the number density of the second phase particles in an inside portion of said zirconium liner layer is 1/10 that of an outside portion of said zirconium liner layer.
Claim 15
Dependent Claim
41 words
A cladding tube for nuclear fuel as claimed in claim 11, wherein the number density of the second phase particles in an outside portion of said zirconium alloy layer is 1/10 that of an inside portion of said zirconium alloy layer.
Claim 16
Dependent Claim
111 words
A nuclear fuel element comprising a cladding tube including an inner zirconium liner layer and an outer zirconium alloy layer, a plurality of fuel pellets charged in said cladding tube and plugs sealing both ends of said cladding tube, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, and that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layers of zirconium in which said ratio is not greater than 1.0.
Claim 17
Dependent Claim
111 words
A nuclear fuel element comprising a cladding tube including an inner zirconium liner layer and an outer zirconium alloy layer, a plurality of fuel pellets charged in said cladding tube and plugs sealing both ends of said cladding tube, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, and that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layers of zirconium in which said ratio is not greater than 1.0.
Claim 18
Dependent Claim
24 words
A nuclear fuel element as claimed in claim 13, wherein said inner zirconium liner layer is positioned directly on said outer zirconium alloy layer.
Claim 19
Dependent Claim
130 words
A nuclear fuel element comprising a cladding tube including an inner zirconium liner layer and an outer zirconium alloy layer, a plurality of fuel pellets charged in said cladding tube and plugs sealing both ends of said cladding tube, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layers of zirconium in which said ratio is not greater that 1.0; and that a material of said zirconium liner layer is a matrix of zirconium into which matrix impurities are dissolved.
Claim 20
Dependent Claim
130 words
A nuclear fuel element comprising a cladding tube including an inner zirconium liner layer and an outer zirconium alloy layer, a plurality of fuel pellets charged in said cladding tube and plugs sealing both ends of said cladding tube, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layers of zirconium in which said ratio is not greater that 1.0; and that a material of said zirconium liner layer is a matrix of zirconium into which matrix impurities are dissolved.
Claim 21
Dependent Claim
24 words
A nuclear fuel element as claimed in claim 15, wherein said inner zirconium liner layer is positioned directly on said outer zirconium alloy layer.
Claim 22
Dependent Claim
193 words
A nuclear fuel element comprising a cladding tube including an inner zirconium liner layer and an outer zirconium alloy layer, a plurality of fuel pellets charged in said cladding tube and plugs sealing both ends of said cladding tube, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layers of zirconium in which said ratio is not greater that 1.0; that a mean distribution density of the second phase particles, which are containing Fe or Ni or Cr, in an inside portion of said zirconium liner layer is smaller than that of an outside portion of said zirconium liner layer; and that a mean distribution density of the second phase particles; which are containing Fe or Ni or Cr or Sn, in an outside portion of said zirconium alloy layer is smaller than that of an inside portion of said zirconium alloy layer.
Claim 23
Dependent Claim
193 words
A nuclear fuel element comprising a cladding tube including an inner zirconium liner layer and an outer zirconium alloy layer, a plurality of fuel pellets charged in said cladding tube and plugs sealing both ends of said cladding tube, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layers of zirconium in which said ratio is not greater that 1.0; that a mean distribution density of the second phase particles, which are containing Fe or Ni or Cr, in an inside portion of said zirconium liner layer is smaller than that of an outside portion of said zirconium liner layer; and that a mean distribution density of the second phase particles; which are containing Fe or Ni or Cr or Sn, in an outside portion of said zirconium alloy layer is smaller than that of an inside portion of said zirconium alloy layer.
Claim 24
Dependent Claim
24 words
A nuclear fuel element as claimed in claim 17, wherein said inner zirconium liner layer is positioned directly on said outer zirconium alloy layer.
Claim 25
Dependent Claim
59 words
A nuclear fuel element as claimed in claim 17, wherein Fe or Ni or Cr contained in second phase particles in the zirconium liner layer are impurities in the liner layer, and wherein Fe or Ni or Cr or Sn contained in the second phase particles in the zirconium alloy layer are impurities contained in the zirconium alloy layer.
Claim 26
Dependent Claim
172 words
A cladding tube for nuclear fuel comprising an inner zirconium liner layer and an outer zirconium alloy layer, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layers of zirconium in which said ratio is not greater that 1.0; that a mean distribution density of the second phase particles, which are containing Fe or Ni or Cr, in an inside portion of said zirconium liner layer is smaller than that of an outside portion of said zirconium liner layer; or that a mean distribution density of the second phase particles, which are containing Fe or Ni or Cr or Sn, in an outside portion of said zirconium alloy layer is smaller than that of an inside portion of said zirconium alloy layer.
Claim 27
Dependent Claim
172 words
A cladding tube for nuclear fuel comprising an inner zirconium liner layer and an outer zirconium alloy layer, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layers of zirconium in which said ratio is not greater that 1.0; that a mean distribution density of the second phase particles, which are containing Fe or Ni or Cr, in an inside portion of said zirconium liner layer is smaller than that of an outside portion of said zirconium liner layer; or that a mean distribution density of the second phase particles, which are containing Fe or Ni or Cr or Sn, in an outside portion of said zirconium alloy layer is smaller than that of an inside portion of said zirconium alloy layer.
Claim 28
Dependent Claim
195 words
A nuclear fuel element comprising a cladding tube including an inner zirconium liner layer and an outer zirconium alloy layer, a plurality of fuel pellets charged in said cladding tube and plugs sealing both ends of said cladding tube, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, and that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layers of zirconium in which said ratio is not greater that 1.0; and that a mean distribution density of the second phase particles, which are containing Fe or Ni or Cr, in an inside portion of said zirconium liner layer is smaller than that of an outside portion of said zirconium liner layer, or that a mean distribution density of the second phase particles, which are containing Fe or Ni or Cr or Sn, in an outside portion of said zirconium alloy layer is smaller than that of an inside portion of said zirconium alloy layer.
Claim 29
Dependent Claim
195 words
A nuclear fuel element comprising a cladding tube including an inner zirconium liner layer and an outer zirconium alloy layer, a plurality of fuel pellets charged in said cladding tube and plugs sealing both ends of said cladding tube, characterized in that said inner zirconium liner layer contains iron and oxygen as impurities, and that the ratio a/b of the oxygen content a to the iron content b in said zirconium liner layer is greater that 1.0 so as to provide a liner layer having both decreased stress corrosion cracking susceptibility and increased mechanical strength as compared to liner layers of zirconium in which said ratio is not greater that 1.0; and that a mean distribution density of the second phase particles, which are containing Fe or Ni or Cr, in an inside portion of said zirconium liner layer is smaller than that of an outside portion of said zirconium liner layer, or that a mean distribution density of the second phase particles, which are containing Fe or Ni or Cr or Sn, in an outside portion of said zirconium alloy layer is smaller than that of an inside portion of said zirconium alloy layer.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1992-09-04 | 1993-03-06 | 1993-09-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-09-04 | 1997-03-06 | 1997-09-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-09-04 | 2001-03-06 | 2001-09-05 | $7700.00 | Window Closed / Lapsed |