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US4855412A Expired / Lapsed US ⏱️ 0.0 years remaining

Diaminopyridine azo dyes having acyloxy radicals substituted on the diaminopyridine

Assignee: BASF SE
•
Filing: 1987-04-24
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Granted: 1989-08-08
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Expires: 2007-04-24
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Abstract

Abstract Compounds of the general formula ##STR1## where D is a radical of the formula ##STR2## and one of the two radicals L 1 and L 2 is unsubstituted amino and the other the radical ##STR3## where R 1 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy-C 2 -C 4 -alkyl or C 1 -C 8 -acyloxy-C 2 -C 4 -alkyl, R 2 is C 2 -C 10 -alkylene or C 2 -C 10 -alkylene is interrupted by oxygen, T is C 1 -C 8 -alkanoyl which is unsubstituted or is substituted by chlorine or methoxy, B 1 is C 1 -C 4 -alkyl or benzyl or phenyl, which are each unsubstituted or are each substituted by methyl, methoxy or chlorine, B 2 is B 1 , hydrogen, halogen, cyano or C 1 -C 5 -alkoxycarbonyl, X 1 is hydrogen, nitro, cyano, C 1 -C 9 -alkoxycarbonyl, C 1 -C 9 -mono- or -dialkylaminocarbonyl, trifluoromethyl, methylsulfonyl or ethylsulfonyl, X 2 is nitro or C 1 -C 5 -alkoxycarbonyl, X 3 is X 2 , cyano or formyl, Y is hydrogen, chlorine, bromine, methyl, methoxy or ethoxy and Z is hydrogen, chlorine, bromine, cyano or C 1 -C 9 -alkoxycarbonyl which is unsubstituted or is substituted by C 1 -C 4 -alkoxy, and one or more of the substituents X 1 , Y and Z is different from hydrogen, are disclosed. The dyes of the present invention may be used in dyeing synthetic polyester.

Inventors

  • 👤 Johannes Dehnert
  • 👤 Gunther Lamm
  • 👤 Hermann Loeffler

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 20:27
CPC Classifications
C; C09; C09B; C09B29/00; C09B29/0025; C09B29/0074; C09B29/0077; C09B29/0085; C09B29/0059; C09B29/0081; C09B29/34; C09B29/36; C09B29/3604; C09B29/3617; C09B29/3621; C09B29/3639; Y; Y10; Y10S; Y10S534/00; Y10S534/02

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 231 words
A compound of the formula: ##STR46## where D is a radical of the formula ##STR47## one of the two radicals L 1 and L 2 is unsubstituted amino and the other radical is ##STR48## where R 1 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy-C 2 -C 4 -alkyl or C 1 -C 8 -alkanoyloxy-C 2 -C 4 -alkyl, R 2 is C 2 -C 10 -alkylene or C 2 -C 10 -alkylene which is interrupted by oxygen, T is C 1 -C 8 -alkanoyl which is unsubstituted or is substituted by chlorine or methoxy, B 1 is C 1 -C 4 -alkyl or benzyl or phenyl, which are each unsubstituted or are each substituted by methyl, methoxy or chlorine, B 2 is B 1 , hydrogen, halogen, cyano or C 1 -C 5 -alkoxycarbonyl, X 1 is hydrogen, nitro, cyano, C 1 -C 9 -alkoxycarbonyl, C 1 -C 9 -mono- or -dialkylaminocarbonyl, trifluoromethyl, methylsulfonyl or ethylsulfonyl, X 2 is nitro or C 1 -C 5 -alkoxycarbonyl, X 3 is X 2 , cyano or formyl, Y is hydrogen, chlorine, bromine, methyl, methoxy or ethoxy and Z is hydrogen, chlorine, bromine, cyano or C 1 -C 9 -alkoxycarbonyl which is unsubstituted or is substituted by C 1 -C 4 -alkoxy, and one or more of the substituents X 1 , Y and Z is different from hydrogen.
Claim 2
Dependent Claim 231 words
A compound of the formula: ##STR46## where D is a radical of the formula ##STR47## one of the two radicals L 1 and L 2 is unsubstituted amino and the other radical is ##STR48## where R 1 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy-C 2 -C 4 -alkyl or C 1 -C 8 -alkanoyloxy-C 2 -C 4 -alkyl, R 2 is C 2 -C 10 -alkylene or C 2 -C 10 -alkylene which is interrupted by oxygen, T is C 1 -C 8 -alkanoyl which is unsubstituted or is substituted by chlorine or methoxy, B 1 is C 1 -C 4 -alkyl or benzyl or phenyl, which are each unsubstituted or are each substituted by methyl, methoxy or chlorine, B 2 is B 1 , hydrogen, halogen, cyano or C 1 -C 5 -alkoxycarbonyl, X 1 is hydrogen, nitro, cyano, C 1 -C 9 -alkoxycarbonyl, C 1 -C 9 -mono- or -dialkylaminocarbonyl, trifluoromethyl, methylsulfonyl or ethylsulfonyl, X 2 is nitro or C 1 -C 5 -alkoxycarbonyl, X 3 is X 2 , cyano or formyl, Y is hydrogen, chlorine, bromine, methyl, methoxy or ethoxy and Z is hydrogen, chlorine, bromine, cyano or C 1 -C 9 -alkoxycarbonyl which is unsubstituted or is substituted by C 1 -C 4 -alkoxy, and one or more of the substituents X 1 , Y and Z is different from hydrogen.
Claim 3
Dependent Claim 119 words
A compound as claimed in claim 1, wherein D is a radical of the formula ##STR49## one of the two radicals L 1 and L 2 is unsubstituted amino and the other is --NH--R 3 --O--T 1 , where R 3 is (CH 2 )--O--(CH 2 ) 2 , (CH 2 ) 3 O(CH 2 ) 3 or (CH 2 ) 3 O(CH 2 ) 4 , T 1 is C 1 -C 4 -alkanoyl, X 4 is nitro, cyano, methylsulfonyl or ethylsulfonyl, Y 2 is hydrogen, chlorine or bromine, Z 2 is hydrogen, cyano or C 1 -C 5 -alkoxycarbonyl, B 3 is C 1 -C 3 -alkyl, benzyl or phenyl and R 4 is methyl or ethyl.

References Cited (Backward Citations)

US29640A Cited
USRE29640E Cited
US4042578A Cited
US3980659A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-08-07 1993-02-06 1993-08-08 $2000.00 Window Closed / Lapsed
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