US4855276A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Solid filtration medium incorporating alumina and carbon
Assignee: Purafil Inc
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Filing: 1987-09-02
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Granted: 1989-08-08
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Expires: 2007-09-02
Abstract
Abstract An adsorbent composition, method of preparing same, and method of treating a fluid stream with the absorbent are disclosed. Alumina and carbon are combined with water in preferred proportions in one embodiment. Sodium bicarbonate and impregnates such as Group 1A metal hydroxides and Group 7A salts of Group 1A metals can be added. Improved efficiency of removal of compounds such as hydrogen sulfide is achieved, and ignition temperature is reduced.
Inventors
- 👤 Michael W. Osborne
- 👤 Cynthia A. Afforder
- 👤 William G. England
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 00:27
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/02; B01J; B01J20/00; B01J20/02; B01J20/20
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
94 words
A process for making an adsorbent composition, consisting essentially of the steps of: (a) forming a mixture in water of the following components in the following proportions: from about 5% to about 90% finely divided carbon, from about 5% to about 90% alumina, and from about 5% to about 80% sodium bicarbonate; (b) forming said mixture into at least one cohesive unit; and (c) curing said unit at a temperature of from about 100 to about 225 degrees F. until said water is from about 5% to about 30% by weight of the composition.
Claim 2
Dependent Claim
94 words
A process for making an adsorbent composition, consisting essentially of the steps of: (a) forming a mixture in water of the following components in the following proportions: from about 5% to about 90% finely divided carbon, from about 5% to about 90% alumina, and from about 5% to about 80% sodium bicarbonate; (b) forming said mixture into at least one cohesive unit; and (c) curing said unit at a temperature of from about 100 to about 225 degrees F. until said water is from about 5% to about 30% by weight of the composition.
Claim 3
Dependent Claim
39 words
The process of claim 1, wherein said step of forming said mixture into cohesive units comprises tumbling a preliminary mixture of said carbon, alumina and sodium bicarbonate while spraying water on said preliminary mixture so as to form nodules.
Claim 4
Dependent Claim
10 words
An adsorbent composition produced by the process of claim 1.
Claim 5
Dependent Claim
34 words
The composition of claim 3, wherein said activated alumina has an LOI less than 20; and wherein said activated carbon is powdered and has a surface area in excess of 1000 meters per gram.
Claim 6
Dependent Claim
47 words
The composition of claim 3, wherein said mixture in water further consists essentially of a hydroxide of a Group IA Group IIA metal; and wherein said curing step includes curing said unit until said hydroxide is from about 1% to about 15% by weight of the composition.
Claim 7
Dependent Claim
87 words
The composition of claim 5, wherein said mixture in water further consists essentially of a salt selected from the group consisting of calcium fluoride, calcium chloride, calcium iodide, magnesium fluoride, magnesium chloride, magnesium iodide, lithium iodide, sodium chloride, sodium fluoride, sodium iodide, potassium fluoride, potassium chloride, and potassium iodide; and wherein said curing step includes curing said until said hydroxide is from about 1% to about 10% by weight of the composition and said salt is from about 1% to about 10% by weight of the composition.
Claim 8
Dependent Claim
11 words
The composition of claim 5 wherein said hydroxide is potassium hydroxide.
Claim 9
Dependent Claim
11 words
The composition of claim 6 wherein said salt is potassium iodide.
Claim 10
Dependent Claim
181 words
A process for making an adsorbent composition, consisting essentially of the steps of: (a) forming a mixture of from about 5% to about 90% finely divided carbon, from about 5% to about 90% alumina, and from about 5% to about 80% sodium bicarbonate; and (b) combining said mixture with a mixture of from about 0.5% to 50% solutions in water of a hydroxide of a Group IA or Group IIA metal and a salt selected from the group consisting of calcium fluoride, calcium chloride, calcium iodide, calcium bromide, magnesium fluoride, magnesium chloride, magnesium iodide, magnesium bromide, sodium chloride, sodium fluoride, sodium iodide, potassium fluoride, sodium bromide, potassium chloride, potassium bromide and potassium iodide to form at least one cohesive unit; and (c) curing said unit at a temperature of from about 100 to about 225 degrees F. until said water is from about 5% to about 30% by weight of the composition, said hydroxide is from about 1% to about 10% by weight of the composition, and said salt is from about 1% to about 10% by weight of the composition.
Claim 11
Dependent Claim
181 words
A process for making an adsorbent composition, consisting essentially of the steps of: (a) forming a mixture of from about 5% to about 90% finely divided carbon, from about 5% to about 90% alumina, and from about 5% to about 80% sodium bicarbonate; and (b) combining said mixture with a mixture of from about 0.5% to 50% solutions in water of a hydroxide of a Group IA or Group IIA metal and a salt selected from the group consisting of calcium fluoride, calcium chloride, calcium iodide, calcium bromide, magnesium fluoride, magnesium chloride, magnesium iodide, magnesium bromide, sodium chloride, sodium fluoride, sodium iodide, potassium fluoride, sodium bromide, potassium chloride, potassium bromide and potassium iodide to form at least one cohesive unit; and (c) curing said unit at a temperature of from about 100 to about 225 degrees F. until said water is from about 5% to about 30% by weight of the composition, said hydroxide is from about 1% to about 10% by weight of the composition, and said salt is from about 1% to about 10% by weight of the composition.
Claim 12
Dependent Claim
10 words
An adsorbent composition produced by the process of claim 9.
Claim 13
Dependent Claim
173 words
A process for making an adsorbent composition, consisting essentially of the steps of: (a) forming a mixture of from about 5% to about 90% finely divided carbon, from about 5% to about 90% alumina, and (b) combining said mixture with a mixture of from about 0.5% to about 50% solutions in water of a hydroxide of a Group IA or Group IIA metal, and a salt selected from the group consisting of calcium fluoride, calcium chloride, calcium iodide, calcium bromide, magnesium fluoride, magnesium chloride, magnesium iodide, magnesium bromide, sodium chloride, sodium fluoride, sodium iodide, potassium fluoride, sodium bromide, potassium chloride, potassium bromide and potassium iodide to form at least one cohesive unit; and (c) curing said unit at a temperature of from about 100 to about 225 degrees F. until said water is from about 5% to about 30% by weight of the composition, said hydroxide is from about 1% to about 10% by weight of the composition, and said salt is from about 1% to about 10% by weight of the composition.
Claim 14
Dependent Claim
173 words
A process for making an adsorbent composition, consisting essentially of the steps of: (a) forming a mixture of from about 5% to about 90% finely divided carbon, from about 5% to about 90% alumina, and (b) combining said mixture with a mixture of from about 0.5% to about 50% solutions in water of a hydroxide of a Group IA or Group IIA metal, and a salt selected from the group consisting of calcium fluoride, calcium chloride, calcium iodide, calcium bromide, magnesium fluoride, magnesium chloride, magnesium iodide, magnesium bromide, sodium chloride, sodium fluoride, sodium iodide, potassium fluoride, sodium bromide, potassium chloride, potassium bromide and potassium iodide to form at least one cohesive unit; and (c) curing said unit at a temperature of from about 100 to about 225 degrees F. until said water is from about 5% to about 30% by weight of the composition, said hydroxide is from about 1% to about 10% by weight of the composition, and said salt is from about 1% to about 10% by weight of the composition.
Claim 15
Dependent Claim
10 words
An adsorbent composition produced by the process of claim 11.
Claim 16
Dependent Claim
32 words
The adsorbent composition of claim 12, wherein said mixture of carbon and alumina is from about 25% to about 50% high surface area carbon and from 50% to about 75% activated alumina.
Claim 17
Dependent Claim
81 words
An adsorbent composition produced by a process consisting essentially of the steps of: (a) forming a mixture in water of the following components in the following proportions: from about 5% to about 90% finely divided carbon, from about 5% to about 90% alumina, and from about 5% to about 80% sodium bicarbonate; (b) forming said mixture into at least one cohesive unit; and (c) curing said unit said water is from about 5% to about 30% by weight of the composition.
Claim 18
Dependent Claim
81 words
An adsorbent composition produced by a process consisting essentially of the steps of: (a) forming a mixture in water of the following components in the following proportions: from about 5% to about 90% finely divided carbon, from about 5% to about 90% alumina, and from about 5% to about 80% sodium bicarbonate; (b) forming said mixture into at least one cohesive unit; and (c) curing said unit said water is from about 5% to about 30% by weight of the composition.
Claim 19
Dependent Claim
51 words
An adsorbent composition, consisting essentially of: (a) about 27% by weight of activated alumina; (b) about 27% by weight high surface area carbon; (c) about 27% by weight sodium bicarbonate; (d) about 5% by weight potassium hydroxide; (e) about 5% by weight potassium iodide; and (f) about 10% by weight water.
Claim 20
Dependent Claim
51 words
An adsorbent composition, consisting essentially of: (a) about 27% by weight of activated alumina; (b) about 27% by weight high surface area carbon; (c) about 27% by weight sodium bicarbonate; (d) about 5% by weight potassium hydroxide; (e) about 5% by weight potassium iodide; and (f) about 10% by weight water.
References Cited (Backward Citations)
US1452739A
Cited
US1781664A
Cited
US1843355A
Cited
US2196246A
Cited
US2423702A
Cited
US2537448A
Cited
US3049399A
Cited
US3391988A
Cited
US3226332A
Cited
US3578390A
Cited
US3360134A
Cited
US3416293A
Cited
US3598521A
Cited
US3819532A
Cited
US3736726A
Cited
SU406552A1
Cited
US3696629A
Cited
US3842014A
Cited
US4072479A
Cited
US4113839A
Cited
US4072480A
Cited
US4215096A
Cited
US4273751A
Cited
US4263268A
Cited
JPS58153537A
Cited
JPS58183941A
Cited
US4499208A
Cited
SU1219122A1
Cited
JPS61178089A
Cited
JPH06154236A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-08-07 | 1993-02-06 | 1993-08-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-08-07 | 1997-02-06 | 1997-08-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-08-07 | 2001-02-06 | 2001-08-08 | $7700.00 | Window Closed / Lapsed |