← Back to Patent Explorer
US4854938A Expired / Lapsed US ⏱️ 0.0 years remaining

Removal of water haze from distillate fuel

Assignee: Dow Silicones UK Ltd
•
Filing: 1988-04-28
•
Granted: 1989-08-08
•
Expires: 2008-04-28
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A method of de-hazing distillate fuel is disclosed which comprises adding to the fuel a solution of a halide salt dissolved in an alcohol, and an alcohol soluble organosiloxane. The halide salt may be the chloride of magnesium, cadmium, copper, nickel or the tetra methyl ammonium group, for example the salt may have the formula MgCl 2 .6H 2 O or (CH 3 ) 4 NCl. The organosiloxane may be a cyclic, linear or branched material and may have e.g. a minor amount of siloxane units having the general formula ##EQU1## and a minor amount of siloxane units having the general formula ##EQU2## in which each R represents a substituted or unsubstituted hydrocarbon group of up to ten carbon atoms, a has the value 0, 1, 2, or 3, b has the value 0, 1 or 2, c has the value 1 or 2, and each Z represents a group linked to the silicon atom and comprising a functional organic group. Each group Z may be a group selected from the polyoxyalkylene group R'(OCH 2 CH 2 ) p (OCH 2 CH.CH 3 ) r OR", the amine group R'NHQ, the quaternary ammonium salt R'NR 3 2 X, the carboxylate group R'CO 2 M, the sulphonate group R'SO 3 M, or the hydroxyl group, in which R' represents a group which provides a link to the silicon atom through an oxygen or a carbon atom, p has a value in the range 1 to 100, r has a value in the range 0 to 50, the sum of p and q is in the range 2 to 100, R" represents a hydrogen atom, an alkyl group or an acyl group, Q represents a hydrogen atom or a group R'NHQ, each R 2 represents an alkyl group, X represents a halide ion and each group M represents a cation.

Inventors

  • 👤 Thomas Easton
  • 👤 Bryan Thomas

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 13:26
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/106; C10L1/14; C10L1/143; C10L1/12; C10L1/1225; C10L1/18; C10L1/182; C10L1/1822; C10L1/1824; C10L1/22; C10L1/222; C10L1/2222; C10L1/28; C10L1/285

Claims Analysis

Total Claims: 29
Claim 1
Independent Claim 33 words
A method of de-hazing distillate fuel which comprises adding to the fuel an effective amount for dehazing of a solution of a halide salt dissolved in an alcohol, and an alcohol soluble organosiloxane.
Claim 2
Independent Claim 33 words
A method of de-hazing distillate fuel which comprises adding to the fuel an effective amount for dehazing of a solution of a halide salt dissolved in an alcohol, and an alcohol soluble organosiloxane.
Claim 3
Dependent Claim 24 words
A method according to claim 1 wherein the halide salt is the chloride of magnesium, cadmium, copper, nickel or the tetra methyl ammonium group.
Claim 4
Dependent Claim 23 words
A method according to claim 2 wherein the salt has the formula MgCl 2 .6H 2 O or (CH 3 ) 4 NCl.
Claim 5
Dependent Claim 43 words
A method according to claim 1 wherein the organosiloxane comprises siloxane units having the general formula ##EQU5## in which each R represents a substituted or unsubstituted hydrocarbon group of up to ten carbon atoms, a has the value 0, 1, 2, or 3.
Claim 6
Dependent Claim 66 words
A method according to claim 1 wherein the organosiloxane comprises siloxane units having the general formula ##EQU6## in which each R represents a substituted or unsubstituted hydrocarbon group of up to ten carbon atoms, b has the value 0, 1 or 2, c has the value 1 or 2, and each Z represents a group linked to the silicon atom and comprising a functional organic group.
Claim 7
Dependent Claim 157 words
A method according to claim 5 wherein each Z is a group selected from the group consisting of the polyoxyalkylene group R' (OCH 2 CH 2 ) p (OCH 2 CH.CH 3 ) r OR", the amine group R'NHQ, the quaternary ammonium salt R'NR 2 3 X, the carboxylate group R'CO 2 M, the sulphonate group R'SO 3 M, or the hydroxyl group, in which R' represents a group which provides a link to the silicon atom through an oxygen or a carbon atom, p has a value in the range 1 to 100, r has a value in the range 0 to 50, the sum of p and q is in the range 2 to 100, R" represents a hydrogen atom, an alkyl group or an acyl group, Q represents a hydrogen atom or a group R'NHQ, each R 2 represents an alkyl group, X represents a halide ion and each group M represents a cation.
Claim 8
Dependent Claim 20 words
A method according to claim 4 wherein the group R is an unsubstituted alkyl, aryl, alkaryl, aralkyl or cycloaliphatic group.
Claim 9
Dependent Claim 20 words
A method according to claim 5 wherein the group R is an unsubstituted alkyl, aryl, alkaryl, aralkyl or cycloaliphatic group.
Claim 10
Dependent Claim 17 words
A method according to claim 7 wherein not less than 80% of the groups R are methyl.
Claim 11
Dependent Claim 17 words
A method according to claim 8 wherein not less than 80% of the groups R are methyl.
Claim 12
Dependent Claim 152 words
A method according to claim 1 wherein the organosiloxane is a cyclic, linear or branched material comprising a major amount of siloxane units having the general formula in which each R represents a substituted or unsubstituted hydrocarbon group of up to ten carbon atoms, a has the value 0, 1, 2, or 3. and; a minor amount of siloxane units having the general formula ##EQU7## in which each R represents a substituted or unsubstituted hydrocarbon group of up to ten carbon atoms, a has the value 0, 1, 2, or 3 and; a minor amount os siloxane units having the general formula ##EQU8## in which each R represents a substituted or unsubstituted hydrocarbon group of up to ten carbon atoms, b has the value 0, 1 or 2, c has the value 1 or 2, and each Z represents a group linked to the silicon atom and comprising a functional organic group.
Claim 13
Dependent Claim 29 words
A method according to claim 1 wherien the organosiloxane is a polydimethylsiloxane, a block copolymer of an organosiloxane and a polyoxyalkylene glycol or a polydiorganosiloxane having quaternary amine groups.
Claim 14
Dependent Claim 22 words
A method according to claim 1 wherein the organosiloxane is added to the fuel in the same solution as the halide salt.
Claim 15
Dependent Claim 13 words
A distillate fuel oil when treated by a method according to claim 1.
Claim 16
Dependent Claim 25 words
A composition suitable for de-hazing distillate fuel comprising a solution in an aliphatic alcohol of an alcohol soluble halide salt, and an alcohol soluble organosiloxane.
Claim 17
Dependent Claim 25 words
A composition suitable for de-hazing distillate fuel comprising a solution in an aliphatic alcohol of an alcohol soluble halide salt, and an alcohol soluble organosiloxane.
Claim 18
Dependent Claim 24 words
A composition according to claim 15 wherein the halide salt is the chloride of magnesium, cadmium, copper, nickel or the tetra methyl ammonium group.
Claim 19
Dependent Claim 23 words
A composition according to claim 16 wherein the salt has the formula MgCl 2 .6H 2 O or (CH 3 ) 4 NCl.
Claim 20
Dependent Claim 44 words
A composition according to claim 15 wherein the organosiloxane comprises siloxane units having the general formula ##EQU9## in which each R represents a substituted or unsubstituted hydrocarbon group of up to ten carbon atoms and a has the value 0, 1, 2, or 3.
Claim 21
Dependent Claim 66 words
A composition according to claim 15 wherein the organosiloxane comprises siloxane units having the general formula ##EQU10## in which each R represents a substituted or unsubstituted hydrocarbon group of up to ten carbon atoms, b has the value 0, 1 or 2, c has the value 1 or 2, and each Z represents a group linked to the silicon atom and comprising a functional organic group.
Claim 22
Dependent Claim 156 words
A composition according to claim 19 wherein each Z is a group selected from the group consisting of the polyoxyalkylene group R' (OCH 2 CH 2 ) p (OCH 2 CH.CH 3 ) r OR", the amine group R'NHQ, the quaternary ammonium salt R'NR 3 X, the carboxylate group R'CO 2 M, the sulphonate group R'SO 3 M, or the hydroxyl group, in which R' represents a group which provides a link to the silicon atom through an oxygen or a carbon atom, p has a value in the range 1 to 100, r has a value in the range 0 to 50, the sum of p and q is in the range 2 to 100, R" represents a hydrogen atom, an alkyl group or an acyl group, Q represents a hydrogen atom or a group R'NHQ each R 2 represents an alkyl group, X represents a halide ion and each group M represents a cation.
Claim 23
Dependent Claim 20 words
A composition according to claim 18 wherein the group R is an unsubstituted alkyl, aryl, alkaryl, aralkyl or cycloaliphatic group.
Claim 24
Dependent Claim 20 words
A composition according to claim 19 wherein the group R is an unsubstituted alkyl, aryl, alkaryl, aralkyl or cycloaliphatic group.
Claim 25
Dependent Claim 17 words
A composition according to claim 21 wherein not less than 80% of the groups R are methyl.
Claim 26
Dependent Claim 17 words
A composition according to claim 22 wherein not less than 80% of the groups R are methyl.
Claim 27
Dependent Claim 115 words
A composition according to claim 15 wherein the organosiloxane is a cyclic, linear or branched material comprising a major amount of siloxane units having the general formula ##EQU11## in which each R represents a substituted or unsubstituted hydrocarbon group of up to ten carbon atoms, a has the value 0, 1, 2, or 3 and; a minor amount of siloxane units having the general formula ##EQU12## in which each R represents a substituted or unsubstituted hydrocarbon group of up to ten carbon atoms, b has the value 0, 1 or 2, c has the value 1 or 2, and each Z represents a group linked to the silicon atom and comprising a functional organic group.
Claim 28
Dependent Claim 29 words
A composition according to claim 15 wherein the organosiloxane is a polydimethylsiloxane, a block copolymer of an organosiloxane and a polyoxyalkylene glycol or a polydiorganosiloxane having quaternary amine groups.
Claim 29
Dependent Claim 14 words
A composition according to claim 15 wherein the alcohol is methanol or ethylene glycol.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-08-07 1993-02-06 1993-08-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-08-07 1997-02-06 1997-08-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-08-07 2001-02-06 2001-08-08 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag