Modified thermosetting resin, a method for its production and its use

Claim 2

Modified theromosetting resin, comprising: (a) 50-98% by weight of a thermosetting resin or a mixture of thermosetting resins being crosslinkable by polyaddition or polycondensaion polymerization and processible into thermosetting plastics, said thermosetting resin or mixture of thermosetting resins being liquid at temperatures in the range of from 18 to 120° C. and having an average molecular weight of form 200to 500,000; and (b) 2-50% by weight of one or more three-dimensional crosslinked polyorganosiloxane rubbers, which are present in the reaction thermosetting resin or mixture of t.hermosetting resins in finely divided form as polyorganosiloxsane rubber particles having a diameter of from 0.01 to 50 micrometers, the rubber particles selected from the group consisting of those having the following generally formula of silioxane units: --(R.sub.2 SiO)-- (1 )

Claim 3

in which both monovalent R radicals, which are identical or different, are linear or branched alkyl groups with 1 to 18 C atoms, cycloaliphatic groups with 4 to 8 C atoms, linear or branched alkenyl groups with 2 to 4 C atoms, phenyl or alkylphenyl groups with 1 to 12 C atoms in the aliphatic radical, and the hydrocarbon radicals can be substituted by hydrogen, halogen, hydroxyl-, carboxyl, carboxylic acid anhydride-, amino-, epoxy-, alkoxy-, alkenyl oxy-, polyether- or polyolefine groups, said groups being connected directly or through an oxygen or nitrogen atom with a silicon atom of the polysilixane chain.

Claim 4

in which both monovalent R radicals, which are identical or different, are linear or branched alkyl groups with 1 to 18 C atoms, cycloaliphatic groups with 4 to 8 C atoms, linear or branched alkenyl groups with 2 to 4 C atoms, phenyl or alkylphenyl groups with 1 to 12 C atoms in the aliphatic radical, and the hydrocarbon radicals can be substituted by hydrogen, halogen, hydroxyl-, carboxyl, carboxylic acid anhydride-, amino-, epoxy-, alkoxy-, alkenyl oxy-, polyether- or polyolefine groups, said groups being connected directly or through an oxygen or nitrogen atom with a silicon atom of the polysilixane chain.

Claim 5

Modifed theremosetting resin as defined in claim 1, wherein the thermosetting resin to be modified consists of epoxy-, urethane-, or air-drying alkyd resins or a mixture theroef.

Claim 6

Modified thermosetting resin as defined in claim 1, wherein the theromosetting resin to be modified consists of phenol-, resorcinol- or cresol resins, urea-formaldehyde- or melamine-formaldehyde-precondensates, furan resins, saturated polyester resins or silicone resins or a mixture thereof.

Claim 7

Modified thermosetting resin as defined in claim 1, wherein the th®romosetting resin to be modified consists of one or more homo- or copolymers of acrylic acid and/or methacrylic acid or their esters.

Claim 8

Modified thermosetting resin as defined in claim 1, where in the thermosetting resin to be modified consists of one or more unsaturated polyester resins or bismaleimide resins or a mixture thereof.

Claim 9

Modified thermosetting resin as defined in claim 1, where in the thermosetting resin or mixture of thermosetting resins to be modified has an average molecular weight of from 300 to 20,000.

Claim 10

Modified thermosetting resin as defined in claim 1, wherein each R is a polyether radical selected from the group consisting of polyethylene glycol, polypropylene glycol, polybutylene glycol, polyhexamethylene glycol, polytetrahydrofuran and copolymers of these ethers, and polyolefine radicals selected from the group consisting of polybutadiene, polyisoprene, polybutene and polyisobutene.

Claim 11

Modified thermosetting resin as defined in claim 1, wherein the polyorganosiloxane rubber particles dispersed in the theromosetting resin have a diameter in the range of from 0.05 to 20 micrometers.

Claim 12

Modified thermosetting resin as defined in claim 1, wherein the polyorganosiloxane rubber particles dispersed in the thermosetting resin have a diameter in the range of from 0.1 to 5 micrometers.

Claim 13

A fracture and impact resistant molded object comprising the modified thermosetting resin defined by claim 1.

Claim 14

A modified thermosetting resin as defined by claim 1, additionally containing a dispersant with an average molecular weight of from 300-50,000 being able to stablize the polyorgasnosiloxane rubber particles dispersed in the thermosetting resin or mixture of thermosetting resins and being compatible with the polyorganosiloxanes and thermosetting resins or mixture of thermosetting resins.

Claim 15

Modifed thermosetting resin as defined in claim 11, wherein the dispersants are present in an amount of 1 to 30% by weight based on the polyorganosiloxane proportion.

Claim 16

Process for the production of modified thermosetting resins as defined in claim 11, which comprises dispersing 2 to 50% by weight of one or more three-dimensional crosslinkable, liquid polorganosiloxanes with an average molecular weight of from 800 to 500,000 in the presence of a crosslinking catalyst and/or a crosslinking agent in 50 to 98% by weight of a thermosetting resin or mixture of theromosetting resins being liquid at temperatures in the range of from 18 to 120? C. and having an average molecular weight of from 200 to 500,000 and, optionally, dispersants having an average molecular weight of from 300 to 50,000 being able to stablize the oplyorganosiloxane rubber particles to be dispersed in the thermosetting resin or mixture of thermosetting resins and being compatible with the polyorganosiloxanes and thermosetting resin or mixture of thermosetting resins, by using mechanical equipment effecting high ®h®ar fcrces in the medium to be dispersed or ultrasonic homogenizers which result in a fine distribution of the liquid polyorganosilonxanes in the liquid thermosetting resin or mixture of theromosetting resins, forming polyorganosiloxane droplets with a diameter in the range of from 0.01 to 50 micrometers.

Claim 17

Process as defined in claim 13, wherein 5 to 30% by weight of one or more three-dimensional crosslinkable, liquid polyorganosiloxanes are used in stage (a).

Claim 18

Process as defined in claim 13, wherein the crosslinkable polyorganosiloxane or polyoragnosiloxane mixture in stage (a) has an average molecular weight of 1000 to 100,000.

Claim 19

Process as defined in claim 13, wherein the crosslinkable polyorganosiloxane or polyorganosiloxane mixture in stage (a) has an average molecular weight: of 1200 to 30,000.

Claim 20

Process as defined in claim 13, wherein the one or more three-dimensional crosslinkable liquid polyorganosiloxanes are dispersed in a dispersion medium, the resulting dispersion is mixed thoroughly with the thermosetting resin or mixture of thermosetting resins, whereby the dispersion medium remains in the resulting dispersion or is removed from the resulting dispersion in a suitable manner.

Claim 21

Process as defined in claim 17, wherein water is used as dispersion medium.

Claim 22

Process as defined in claim 13 wherein the one or more liquid plyorganosiloxnaes to be dispersed are of such a tube in which more than 50% of all of the organic groups of the siloxane main chain are methyl groups.

Claim 23

Modified reaction resin as defined in claim 7, wherein the polyorganosiloxane rubber is a copolymer block, in which monovalent R, and R" radicals are arranged along the siloxane main chain in blocks, whioh derive from polymers of the following general formula: --(R'.sub.2 SiO).sub.x--(R".sub.2 SiO).sub.y × (2) in which the R' and R" radicals, which have the same meaning as R, are different from each other, while the R' and R" radicals can be identical or different from each other, and x and y are equal to 1 or whole number multiples thereof.

Claim 24

Modified reaction, resin as defined in claim 20 where at least 50% of the R, R' and R" radicals are methyl and/or phenyl groups.