US4853361A
Expired / Lapsed
US
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Heat- and light-sensitive recording material
Assignee: Nippon Paper Industries Co Ltd
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Filing: 1988-04-14
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Granted: 1989-08-01
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Expires: 2008-04-14
Abstract
Abstract A heat- and light-sensitive recording material has a substrate and a color-forming layer which comprises a particular fluoran-type leuco dye. This heat- and light-sensitive recording material provides a clear image a superior contamination-resistance and an excellent readability in visible and near infrared range.
Inventors
- 👤 Toshimi Satake
- 👤 Toshiaki Minami
- 👤 Tomoaki Nagai
- 👤 Fumio Fujimura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 08:25
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/72; G03C1/73; B; B41; B41M; B41M5/00; B41M5/26; B41M5/30; B41M5/323; B41M5/327; B41M5/3275; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10S428/914; Y10S430/00; Y10S430/146
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
272 words
A heat- and light-sensitive recording material comprising a substrate having thereon a color-forming layer which contains a electron-donating compound and does not contain electron-accepting compound, said color-forming layer comprising as said electron-donating compound a fluoran-type leuco dye represented by the following general formula (I). ##STR9## wherein at least one of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 represents ##STR10## the remainders of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 , which may be the same or different, represent a hydrogen atom, an alkyl group, an alkoxy group, a cycloalkyl group, a halogen atom, a nitro group, a hydroxy group, an amino group, a substituted amino group, an aralkyl group, a substituted aralkyl group, an aryl group or a substituted aryl group; T 1 , T 2 and T 3 , which may be the same or different, represent a hydrogen atom, a C 3 -C 9 alkyl group, a C 3 -C 9 alkenyl group, or a C 3 -C 9 alkinyl T 4 represents a hydrogen atom, a C 1 -C 8 alkyl group, a C 3 -C 9 alkenyl group, a C 3 -C 9 alkinyl group or a phenyl group; in addition T 3 and T 4 taken together with the nitrogen to which they are attached, may represent, a morpholino group, a pyrrolidino group, a piperidino group or a hexamethylenimino group; and n represents an integer from 0 to 4
Claim 2
Dependent Claim
272 words
A heat- and light-sensitive recording material comprising a substrate having thereon a color-forming layer which contains a electron-donating compound and does not contain electron-accepting compound, said color-forming layer comprising as said electron-donating compound a fluoran-type leuco dye represented by the following general formula (I). ##STR9## wherein at least one of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 represents ##STR10## the remainders of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 , which may be the same or different, represent a hydrogen atom, an alkyl group, an alkoxy group, a cycloalkyl group, a halogen atom, a nitro group, a hydroxy group, an amino group, a substituted amino group, an aralkyl group, a substituted aralkyl group, an aryl group or a substituted aryl group; T 1 , T 2 and T 3 , which may be the same or different, represent a hydrogen atom, a C 3 -C 9 alkyl group, a C 3 -C 9 alkenyl group, or a C 3 -C 9 alkinyl T 4 represents a hydrogen atom, a C 1 -C 8 alkyl group, a C 3 -C 9 alkenyl group, a C 3 -C 9 alkinyl group or a phenyl group; in addition T 3 and T 4 taken together with the nitrogen to which they are attached, may represent, a morpholino group, a pyrrolidino group, a piperidino group or a hexamethylenimino group; and n represents an integer from 0 to 4
Claim 3
Dependent Claim
26 words
The recording material according to claim 1, wherein said fluoran-type leuco dye is at least one dye selected from a group consisting of 2-chloro-3-methyl-6-p-(p-phenylaminophenyl)aminoanilinofluoran and 2-methyl-6-p-(p-dimethylaminophenyl)aminoanilinofluoran.
Claim 4
Dependent Claim
44 words
The recording material according to claim 1 or 2, wherein said color-forming layer comprises 1-8 parts by weight of heat-meltable material, 1-20 parts by weight of filler and 10-25 parts by weight of binder, based on 1 part by weight of basic colorless dye.
Claim 5
Dependent Claim
12 words
The recording material according to claim 1, wherein said substrate is film.
Claim 6
Dependent Claim
309 words
A heat- and light-sensitive recording method, wherein a thermal pattern is applied to a heat- and light-sensitive material for the formation of a latent image, and then a light is irradiated thereon for the formation of a visible image, said heat- and light-sensitive material comprising a substrate having thereon a color-forming layer which contains electron-donating compound and does not contain electron-accepting compound, said color-forming layer comprising as said electron-donating a fluoran-type leuco dye represented by the following general formula (I). ##STR11## wherein at least one of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 represents ##STR12## the remainders of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 , which may be the same or different, represent a hydrogen atom, an alkyl group, an alkoxy group, a cycloalkyl group, a halogen atom, a nitro group, a hydroxy group, an amino group, a substituted amino group, an aralkyl group, a substituted aralkyl group, an aryl group or a substituted aryl group; T 1 , T 2 and T 3 , which may be the same or different, represent a hydrogen atom, a C 3 -C 9 alkyl group, a C 3 -C 9 alkenyl group, or a C 3 -C 9 alkinyl group; T 4 represents a hydrogen atom, a C 1 -C 8 alkyl group, a C 3 -C 9 alkenyl group, a C 3 -C 9 alkinyl group or a phenyl group; in addition, T 3 and T 4 taken together with the nitrogen to which they are attached, may represent, a morpholino group, a pyrrolidino group, a piperidino group or a hexamethylenimino group; and n represent an integer from 0 to 4.
Claim 7
Dependent Claim
309 words
A heat- and light-sensitive recording method, wherein a thermal pattern is applied to a heat- and light-sensitive material for the formation of a latent image, and then a light is irradiated thereon for the formation of a visible image, said heat- and light-sensitive material comprising a substrate having thereon a color-forming layer which contains electron-donating compound and does not contain electron-accepting compound, said color-forming layer comprising as said electron-donating a fluoran-type leuco dye represented by the following general formula (I). ##STR11## wherein at least one of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 represents ##STR12## the remainders of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 , which may be the same or different, represent a hydrogen atom, an alkyl group, an alkoxy group, a cycloalkyl group, a halogen atom, a nitro group, a hydroxy group, an amino group, a substituted amino group, an aralkyl group, a substituted aralkyl group, an aryl group or a substituted aryl group; T 1 , T 2 and T 3 , which may be the same or different, represent a hydrogen atom, a C 3 -C 9 alkyl group, a C 3 -C 9 alkenyl group, or a C 3 -C 9 alkinyl group; T 4 represents a hydrogen atom, a C 1 -C 8 alkyl group, a C 3 -C 9 alkenyl group, a C 3 -C 9 alkinyl group or a phenyl group; in addition, T 3 and T 4 taken together with the nitrogen to which they are attached, may represent, a morpholino group, a pyrrolidino group, a piperidino group or a hexamethylenimino group; and n represent an integer from 0 to 4.
Claim 8
Dependent Claim
20 words
The recording method according to claim 5, wherein said thermal pattern is applied by a thermal pen or laser beam.
Claim 9
Dependent Claim
14 words
The recording method according to claim 5, wherein UV-light is used as said light.
Claim 10
Dependent Claim
14 words
The recording material according to claim 5, wherein said film is comprised of paper.
References Cited (Backward Citations)
JPH0274687A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-07-31 | 1993-01-30 | 1993-08-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-07-31 | 1997-01-30 | 1997-08-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-07-31 | 2001-01-30 | 2001-08-01 | $7700.00 | Window Closed / Lapsed |