US4851492A
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Organopolysiloxanes containing acyl thiourea groups, methods of their preparation and use
Assignee: Evonik Operations GmbH
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Filing: 1988-02-24
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Granted: 1989-07-25
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Expires: 2008-02-24
Abstract
Abstract Organopolysiloxane products containing acyl thiourea groups and from the units: ##STR1## are disclosed. R 1 stands for an optionally substituted phenyl group or an alky group and R 2 and R 3 for R.sup.4 --SiO.sub.3/2 (2) units. R 4 is alkylene. The free valences of the oxygen atoms are saturated by Si atoms of further R 4 --SiO 3/2 groups and/or by Si atoms of: ##STR2## amine units, wherein R 5 =H; R 2 or R 3 and/or by cross-linking compounds of Si, Ti or Al. The ratio between the Si atoms in (1) and (3) to the Si, Ti, Al cross-linking atoms is 1:0 to 1:10. Various methods of preparing the products are described. These polymers to separate metals from solutions.
Inventors
- 👤 Peter Panster
- 👤 Karl-Heinz Koenig
- 👤 Elske Schopenhauer-Gehrmann
- 👤 Peter Kleinschmit
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 17:49
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/04; C08G77/38; C08G77/382; C08G77/392; B; B01; B01J; B01J20/00; B01J20/22; C02; C02F; C02F1/00; C02F1/28; C02F1/285; C22; C22B; C22B3/00; C22B3/20; C22B3/22; C22B3/24; Y; Y02; Y02P; Y02P10/00; Y02P10/20
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
228 words
An organopolysiloxane containing acyl thiourea groups and composed of recurring units of the formula: ##STR24## whereby R 1 represents a phenyl group, or a phenyl group substituted with an NO 2 group, or an alkyl group with 1 to 3 C atoms, R 2 and R 3 represent units of formula (2): R.sup.4 --SiO.sub.3/2 (2) in which R 4 represents an alkylene group with 1 to 10 C atoms or a cycloalkylene group with 5 to 8 C atoms or represents a unit of the formulae: ##STR25## wherein n is from 1 to 6 and the free valences of the oxygen atoms in formula (2) are saturated by (a) silicon atoms of further groups of formula (2) or by (b) silicon atoms of amine units according to formula (3), or mixtures of (a) and (b): ##STR26## in which R 2 and R 3 have the same meaning as in formula (2) and can be the same or different, R 5 represents H or has the same meaning as R 2 or R 3 , or by (c) cross-linking binding links SiO.sub.4/2, R'SiO.sub.3/2, R.sub.2 'SiO.sub.2/2 TiO.sub.4/2, R'TiO.sub.3/2, R.sub.2 'TiO.sub.2/2 AlO.sub.3/2, R'AlO.sub.2/2, or mixtures of (a), (b) and (c) wherein R' represents a methyl or ethyl group and the ratio of the silicon atoms in formulae (1) and (3) to the binding links silicon, titanium, aluminum is 1:0 to 1:10.
Claim 2
Dependent Claim
228 words
An organopolysiloxane containing acyl thiourea groups and composed of recurring units of the formula: ##STR24## whereby R 1 represents a phenyl group, or a phenyl group substituted with an NO 2 group, or an alkyl group with 1 to 3 C atoms, R 2 and R 3 represent units of formula (2): R.sup.4 --SiO.sub.3/2 (2) in which R 4 represents an alkylene group with 1 to 10 C atoms or a cycloalkylene group with 5 to 8 C atoms or represents a unit of the formulae: ##STR25## wherein n is from 1 to 6 and the free valences of the oxygen atoms in formula (2) are saturated by (a) silicon atoms of further groups of formula (2) or by (b) silicon atoms of amine units according to formula (3), or mixtures of (a) and (b): ##STR26## in which R 2 and R 3 have the same meaning as in formula (2) and can be the same or different, R 5 represents H or has the same meaning as R 2 or R 3 , or by (c) cross-linking binding links SiO.sub.4/2, R'SiO.sub.3/2, R.sub.2 'SiO.sub.2/2 TiO.sub.4/2, R'TiO.sub.3/2, R.sub.2 'TiO.sub.2/2 AlO.sub.3/2, R'AlO.sub.2/2, or mixtures of (a), (b) and (c) wherein R' represents a methyl or ethyl group and the ratio of the silicon atoms in formulae (1) and (3) to the binding links silicon, titanium, aluminum is 1:0 to 1:10.
Claim 3
Dependent Claim
21 words
The organopolysiloxane containing acyl thiourea groups according to claim 1, wherein R 4 is a linear or branched chain alkylene group.
Claim 4
Dependent Claim
20 words
The organopolysiloxane containing acyl thiourea groups according to claim 1, wherein R 2 is the same as R 3 .
Claim 5
Dependent Claim
16 words
The organopolysiloxane containing acyl thiourea groups according to claim 1, wherein formula (1) represents: ##STR27## units.
Claim 6
Dependent Claim
29 words
The organopolysiloxane containing acyl thiourea groups according to claim 1, wherein the molar ratio between units of formula (1) to units of formula (3) is from 1:0 to 1:9.
Claim 7
Dependent Claim
18 words
The organopolysiloxane containing acyl thiourea groups according to claim 1, in the form of a finely divided solid.
Claim 8
Dependent Claim
28 words
The organopolysiloxane containing acyl thiourea groups according to claim 1 which has a specific surface area of less than 1 m 2 /g to 100 m 2 /g.
Claim 9
Dependent Claim
22 words
The organopolysiloxane containing acyl thiourea groups according to claim 1 having a particle size for about 0.1 μm to about 1 cm.
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