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US4851492A Expired / Lapsed US ⏱️ 0.0 years remaining

Organopolysiloxanes containing acyl thiourea groups, methods of their preparation and use

Assignee: Evonik Operations GmbH
•
Filing: 1988-02-24
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Granted: 1989-07-25
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Expires: 2008-02-24
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Abstract

Abstract Organopolysiloxane products containing acyl thiourea groups and from the units: ##STR1## are disclosed. R 1 stands for an optionally substituted phenyl group or an alky group and R 2 and R 3 for R.sup.4 --SiO.sub.3/2 (2) units. R 4 is alkylene. The free valences of the oxygen atoms are saturated by Si atoms of further R 4 --SiO 3/2 groups and/or by Si atoms of: ##STR2## amine units, wherein R 5 =H; R 2 or R 3 and/or by cross-linking compounds of Si, Ti or Al. The ratio between the Si atoms in (1) and (3) to the Si, Ti, Al cross-linking atoms is 1:0 to 1:10. Various methods of preparing the products are described. These polymers to separate metals from solutions.

Inventors

  • 👤 Peter Panster
  • 👤 Karl-Heinz Koenig
  • 👤 Elske Schopenhauer-Gehrmann
  • 👤 Peter Kleinschmit

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 17:49
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/04; C08G77/38; C08G77/382; C08G77/392; B; B01; B01J; B01J20/00; B01J20/22; C02; C02F; C02F1/00; C02F1/28; C02F1/285; C22; C22B; C22B3/00; C22B3/20; C22B3/22; C22B3/24; Y; Y02; Y02P; Y02P10/00; Y02P10/20

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 228 words
An organopolysiloxane containing acyl thiourea groups and composed of recurring units of the formula: ##STR24## whereby R 1 represents a phenyl group, or a phenyl group substituted with an NO 2 group, or an alkyl group with 1 to 3 C atoms, R 2 and R 3 represent units of formula (2): R.sup.4 --SiO.sub.3/2 (2) in which R 4 represents an alkylene group with 1 to 10 C atoms or a cycloalkylene group with 5 to 8 C atoms or represents a unit of the formulae: ##STR25## wherein n is from 1 to 6 and the free valences of the oxygen atoms in formula (2) are saturated by (a) silicon atoms of further groups of formula (2) or by (b) silicon atoms of amine units according to formula (3), or mixtures of (a) and (b): ##STR26## in which R 2 and R 3 have the same meaning as in formula (2) and can be the same or different, R 5 represents H or has the same meaning as R 2 or R 3 , or by (c) cross-linking binding links SiO.sub.4/2, R'SiO.sub.3/2, R.sub.2 'SiO.sub.2/2 TiO.sub.4/2, R'TiO.sub.3/2, R.sub.2 'TiO.sub.2/2 AlO.sub.3/2, R'AlO.sub.2/2, or mixtures of (a), (b) and (c) wherein R' represents a methyl or ethyl group and the ratio of the silicon atoms in formulae (1) and (3) to the binding links silicon, titanium, aluminum is 1:0 to 1:10.
Claim 2
Dependent Claim 228 words
An organopolysiloxane containing acyl thiourea groups and composed of recurring units of the formula: ##STR24## whereby R 1 represents a phenyl group, or a phenyl group substituted with an NO 2 group, or an alkyl group with 1 to 3 C atoms, R 2 and R 3 represent units of formula (2): R.sup.4 --SiO.sub.3/2 (2) in which R 4 represents an alkylene group with 1 to 10 C atoms or a cycloalkylene group with 5 to 8 C atoms or represents a unit of the formulae: ##STR25## wherein n is from 1 to 6 and the free valences of the oxygen atoms in formula (2) are saturated by (a) silicon atoms of further groups of formula (2) or by (b) silicon atoms of amine units according to formula (3), or mixtures of (a) and (b): ##STR26## in which R 2 and R 3 have the same meaning as in formula (2) and can be the same or different, R 5 represents H or has the same meaning as R 2 or R 3 , or by (c) cross-linking binding links SiO.sub.4/2, R'SiO.sub.3/2, R.sub.2 'SiO.sub.2/2 TiO.sub.4/2, R'TiO.sub.3/2, R.sub.2 'TiO.sub.2/2 AlO.sub.3/2, R'AlO.sub.2/2, or mixtures of (a), (b) and (c) wherein R' represents a methyl or ethyl group and the ratio of the silicon atoms in formulae (1) and (3) to the binding links silicon, titanium, aluminum is 1:0 to 1:10.
Claim 3
Dependent Claim 21 words
The organopolysiloxane containing acyl thiourea groups according to claim 1, wherein R 4 is a linear or branched chain alkylene group.
Claim 4
Dependent Claim 20 words
The organopolysiloxane containing acyl thiourea groups according to claim 1, wherein R 2 is the same as R 3 .
Claim 5
Dependent Claim 16 words
The organopolysiloxane containing acyl thiourea groups according to claim 1, wherein formula (1) represents: ##STR27## units.
Claim 6
Dependent Claim 29 words
The organopolysiloxane containing acyl thiourea groups according to claim 1, wherein the molar ratio between units of formula (1) to units of formula (3) is from 1:0 to 1:9.
Claim 7
Dependent Claim 18 words
The organopolysiloxane containing acyl thiourea groups according to claim 1, in the form of a finely divided solid.
Claim 8
Dependent Claim 28 words
The organopolysiloxane containing acyl thiourea groups according to claim 1 which has a specific surface area of less than 1 m 2 /g to 100 m 2 /g.
Claim 9
Dependent Claim 22 words
The organopolysiloxane containing acyl thiourea groups according to claim 1 having a particle size for about 0.1 μm to about 1 cm.

References Cited (Backward Citations)

US3269982A Cited
US3642855A Cited
EP0018102A1 Cited
US4455415A Cited
US4424332A Cited
US4448694A Cited
US4645848A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-07-24 1993-01-23 1993-07-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-07-24 1997-01-23 1997-07-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-07-24 2001-01-23 2001-07-25 $7700.00 Window Closed / Lapsed

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