Cyclohexane derivatives

Abstract

Abstract Cyclohexane derivatives of the formula I R.sup.1 --A.sup.1 --Z.sup.1 --A.sup.2 --R.sup.2 I in which R 1 and R 2 are each an alkyl group having 1-10 C atoms, in which one or two non-adjacent CH 2 groups can also be replaced by O atoms and/or --CO-- groups and/or --CO--O-- groups and/or --CH═CH-- groups, one of the radicals R 1 and R 2 also being H, F, Cl, Br, CN or R 3 --A 3 --Z 2 --, A 1 is --A--, A 4 --A-- or --A--A 4 --, A is a trans-1,4-cyclohexylene group which can be substituted in the 2-, 3-, 5- and/or 6-position one or more times by F and/or Cl and/or Br and/or CN and/or an alkyl group or a fluorinated alkyl group which each have 1-10 C atoms and in which one or two non-adjacent CH 2 groups can also be replaced by 0 atoms and/or --CO-- groups and/or --CO--O-- groups, and which may also be substituted in the 1- and/or 4-position, A 2 , A 3 and A 4 are each 1,4-phenylene which is unsubstituted or substituted by one or two F and/or Cl atoms and/or CH 3 groups and/or CN groups and in which one or two CH groups can also be replaced by N atoms and/or NO; 1,4-cyclohexylene in which one or two non-adjacent CH 2 groups can also be replaced by 0 atoms; or 1,3-dithiane-2,5-diyl, piperidine-1,4-diyl, 1,4-bicyclo-(2,2,2)octylene, decahydronaphthalene-2,6-diyl or 1,2,3,4-tetrahydronaphthalene-2,6-diyl groups, Z 1 and Z 2 are each --CO--O--, --O--CO--, --CH 2 CH 2 --, --OCH 2 --, --CH 2 O or a single bond, and R 3 is H, an alkyl group having 1-10 (sic), in which one or two non-adjacent CH 2 groups can also be replaced by 0 atoms and/or --CO-- groups and/or --CO--O-- groups and/or CH═CH-- groups, or is F, Cl, Br or CN, with the proviso that in the case of Z 1 =--CO--O-- A 1 carries no equatorial substituent in the β-position relative to the --CO--O--bridge, are suitable for use as components of liquid-crystalline phases.

Inventors

• 👤 Ludwig Pohl
• 👤 Bernhard Scheuble
• 👤 Reinhard Hittich
• 👤 Rudolf Eidenschink
• 👤 Hans A. Kurmeier
• 👤 Andreas Wachtler

Bibliographic Details