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US4845150A Expired / Lapsed US ⏱️ 0.0 years remaining

Interpenetrated polymer films

Assignee: Vencore Services and Solutions Inc
•
Filing: 1987-06-22
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Granted: 1989-07-04
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Expires: 2007-06-22
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Abstract

Abstract This invention relates in general to the formation of films having a controlled molecular orientation prepared from rod-like extended chain aromatic-heterocyclic ordered polymers, and containing a binder in the micro-infrastructure. Such films have high tensile strength, modulus, and environmental resistance characteristics.

Inventors

  • 👤 Robert Kovak
  • 👤 Roland R. Wallis, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 12:40
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/18; B; B29; B29C; B29C48/00; B29C48/03; B29C48/07; B29C48/08; B29C48/25; B29C48/30; B29C48/305; B29C48/88; B29C48/919; B29C55/00; B29C55/005; B29C55/02; B29C55/10; B29C55/12; C08L; C08L79/00; C08L79/04; C08L79/06; B29C48/06; B29C48/09; B29C48/10; B29K; B29K2079/00; B29K2105/00; B29K2105/0079; C08J2379/00; C08J2379/04; C08J2379/06; Y; Y10; Y10S; Y10S525/00; Y10S525/903; Y10T; Y10T428/00; Y10T428/25; Y10T428/254

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 60 words
A polymer film comprising an ordered rod-like extended chain aromatic heterocyclic polymer selected from the group consisting of poly(p-phenylenebenzo bisthiazole) and poly(p-phenylenebenzo bisoxazole) having a binder selected from the group consisting of glass, ceramic, polysulfone, epoxy and polyimide interpenetrated in the microinfrastructure, and wherein the polymer is infiltrated with the binder to form a microcomposite of the polymer and binder.
Claim 2
Dependent Claim 60 words
A polymer film comprising an ordered rod-like extended chain aromatic heterocyclic polymer selected from the group consisting of poly(p-phenylenebenzo bisthiazole) and poly(p-phenylenebenzo bisoxazole) having a binder selected from the group consisting of glass, ceramic, polysulfone, epoxy and polyimide interpenetrated in the microinfrastructure, and wherein the polymer is infiltrated with the binder to form a microcomposite of the polymer and binder.
Claim 3
Dependent Claim 13 words
The film of claim 1, wherein said binder is a thermoset acetylene-terminated polyimide.
Claim 4
Dependent Claim 62 words
A polymer film comprising an ordered rod-like extended chain aromatic heterocyclic polymer selected from the group consisting of poly(p-phenylenebenzo bisthiazole) and poly(p-phenylenebenzo bisoxazole having a binder precursor selected from the group consisting of glass, ceramic, polysulfone, epoxy and polyimide interpenetrated in the microinfrastructure, and wherein the polymer is infiltrated with the binder precursor to form a microcomposite of the polymer and binder.
Claim 5
Dependent Claim 62 words
A polymer film comprising an ordered rod-like extended chain aromatic heterocyclic polymer selected from the group consisting of poly(p-phenylenebenzo bisthiazole) and poly(p-phenylenebenzo bisoxazole having a binder precursor selected from the group consisting of glass, ceramic, polysulfone, epoxy and polyimide interpenetrated in the microinfrastructure, and wherein the polymer is infiltrated with the binder precursor to form a microcomposite of the polymer and binder.
Claim 6
Dependent Claim 13 words
The film of claim 3, wherein said binder is a thermosetting acetylene-terminated polyisoimide.
Claim 7
Dependent Claim 41 words
A polymer film comprising an ordered rod-like extended chain aromatic heterocyclic polymer selected from the group consisting of poly(para-phenylenebenzo bisthiazole) and poly(para-phenylenebenzo bisoxazole), and a glass binder infiltrated within the polymer to form a microcomposite of the polymer and the binder.
Claim 8
Dependent Claim 41 words
A polymer film comprising an ordered rod-like extended chain aromatic heterocyclic polymer selected from the group consisting of poly(para-phenylenebenzo bisthiazole) and poly(para-phenylenebenzo bisoxazole), and a glass binder infiltrated within the polymer to form a microcomposite of the polymer and the binder.
Claim 9
Dependent Claim 42 words
A polymer film comprising an ordered rod-like extended chain aromatic heterocyclic polymer selected from the group consisting of poly(para-phenylenebenzo bisthiazole) and poly(para-phenylenebenzo bisoxazole), and a glass binder precursor infiltrated within the polymer to form a microcomposite of the polymer and the binder.
Claim 10
Dependent Claim 42 words
A polymer film comprising an ordered rod-like extended chain aromatic heterocyclic polymer selected from the group consisting of poly(para-phenylenebenzo bisthiazole) and poly(para-phenylenebenzo bisoxazole), and a glass binder precursor infiltrated within the polymer to form a microcomposite of the polymer and the binder.
Claim 11
Dependent Claim 77 words
A polymer film comprising an ordered rod-like extended chain aromatic heterocyclic polymer having a binder selected from the group consisting of glass, ceramic, polysulfone, epoxy and polyimide interpenetrated in the microinfrastructure prepared by treating by shear a dope containing an ordered polymer to produce a microscale structure orientation therein, solidifying said microscale structure by coagulation in an aqueous medium, penetrating a binder precursor into the microstructure of said solidified polymer, and converting said precursor to said binder.
Claim 12
Dependent Claim 77 words
A polymer film comprising an ordered rod-like extended chain aromatic heterocyclic polymer having a binder selected from the group consisting of glass, ceramic, polysulfone, epoxy and polyimide interpenetrated in the microinfrastructure prepared by treating by shear a dope containing an ordered polymer to produce a microscale structure orientation therein, solidifying said microscale structure by coagulation in an aqueous medium, penetrating a binder precursor into the microstructure of said solidified polymer, and converting said precursor to said binder.

References Cited (Backward Citations)

US4631318A Cited
US4578432A Cited
US4695610A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-07-03 1993-01-02 1993-07-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-07-03 1997-01-02 1997-07-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-07-03 2001-01-02 2001-07-04 $7700.00 Window Closed / Lapsed

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