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US4842380A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid crystal optical elements

Assignee: Fujifilm Holdings Corp
•
Filing: 1987-08-19
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Granted: 1989-06-27
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Expires: 2007-08-19
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Abstract

Abstract Disclosed is a liquid crystal optical element for use in information recording media and displays, which is composed of a polymeric liquid crystal and from 0.01% to 10% by weight, on the basis of the polymeric liquid crystal, of a biphenyl or biphenyl derivative of formula (I) ##STR1## wherein X and Y each represents a hydrogen atom, an alkyl group, an oxyalkyl group, a halogen atom, a nitrile group, or a nitro group. By the addition of the biphenyl or biphenyl derivative, the orientation of the polymeric liquid crystal is improved.

Inventors

  • 👤 Takashi Takayanagi
  • 👤 Hideo Kawaguchi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 13:49
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/04; C09K19/38; C09K19/3833; C09K19/3842; C09K19/3852; C09K19/3866; C09K19/52; C09K19/54; C09K19/56; G; G02; G02F; G02F1/00; G02F1/01; G02F1/13; G02F1/133; G02F1/1333; G02F1/133365; G11; G11B; G11B7/00; G11B7/24; G11B7/241; G11B7/242; G11B7/244; G11B7/25; C09K2323/00

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 115 words
A liquid crystal optical element comprising a cell comprising two or more supports each having a transparent electroconductive layer, said cells containing a polymeric liquid crystal with positive dielectric anisotropy having a mesogenic biphenyl side chain, said polymeric liquid crystals being capable of being placed in the form of a vertically oriented state and being optically transparent in the vertically oriented state, and from 0.01% to 10% by weight, on the basis of said polymeric liquid crystal, of a non-liquid crystal biphenyl or biphenyl derivative represented by formula (I) ##STR8## wherein X and Y each represents a hydrogen atom, an alkyl group, an oxyalkyl group, a halogen atom, a nitrile group, or a nitro group.
Claim 2
Dependent Claim 115 words
A liquid crystal optical element comprising a cell comprising two or more supports each having a transparent electroconductive layer, said cells containing a polymeric liquid crystal with positive dielectric anisotropy having a mesogenic biphenyl side chain, said polymeric liquid crystals being capable of being placed in the form of a vertically oriented state and being optically transparent in the vertically oriented state, and from 0.01% to 10% by weight, on the basis of said polymeric liquid crystal, of a non-liquid crystal biphenyl or biphenyl derivative represented by formula (I) ##STR8## wherein X and Y each represents a hydrogen atom, an alkyl group, an oxyalkyl group, a halogen atom, a nitrile group, or a nitro group.
Claim 3
Dependent Claim 21 words
A liquid crystal optical element as in claim 1, wherein the biphenyl or biphenyl derivative is selected from the compounds ##STR9##
Claim 4
Dependent Claim 30 words
A liquid crystal optical element as in claim 1, wherein the polymeric liquid crystal is a polymeric compound having said mesogenic group via an alkyl chain in the side chain.
Claim 5
Dependent Claim 31 words
A liquid crystal optical element as in claim 1, wherein the polymeric liquid crystal is composed of three parts, consisting essentially of a main chain, a spacer, and a mesogenic group.
Claim 6
Dependent Claim 56 words
A liquid crystal optical element as in claim 4, wherein the main chain in the polymeric liquid crystal is a polyacrylate, polysiloxane, or polymethacrylate, the spacer therein is a methylene chain or an oxymethylene chain having from 2 to 18 carbon atoms, and the mesogenic group therein is selected from those represented by the formulae ##STR10##
Claim 7
Dependent Claim 31 words
A liquid crystal optical element as in claim 2, wherein the polymeric liquid crystal is composed of three parts consisting essentially of a main chain, a spacer, and a mesogenic group.
Claim 8
Dependent Claim 31 words
A liquid crystal optical element as in claim 3, wherein the polymeric liquid crystal is composed of three parts consisting essentially of a main chain, a spacer, and a mesogenic group.
Claim 9
Dependent Claim 166 words
A liquid crystal optical element as in claim 4, wherein the main chain in the polymeric liquid crystal is a polyacrylate, polysiloxane or polymethacrylate, the spacer therein is a methylene chain or an oxymethylene chain having from 2 to 18 carbon atoms, and the mesogenic group therein is selected from those represented by formulae ##STR11## wherein R represents --OCH 3 , --OC 2 H 5 , --OC 3 H 7 , --OC 4 H 9 , --OC 5 H 11 , --OC 6 H 13 , --CH 3 , --C 2 H 5 , --C 3 H 7 , --C 4 H 9 , --C 5 H 11 , --C 6 H 13 , --C 7 H 15 , --C 8 H 17 , H, Cl, Br, --C 9 H 19 , --C 10 H 21 --C 11 H 23 , --C 12 H 25 , --C 14 H 29 , --C 16 H 33 , and Chol represents a compound represented by the formula ##STR12##
Claim 10
Dependent Claim 167 words
A liquid crystal optical element as in claim 6, wherein the main chain in the polymeric liquid crystal is a polyacrylate, polysiloxane or polymethacrylate, the spacer therein is a methylene chain or an oxymethylene chain having from 2 to 18 carbon atoms, and the mesogenic group therein is selected from those represented by formulae ##STR13## wherein R represents --OCH 3 , --OC 2 H 5 , --OC 3 H 7 , --OC 4 H 9 , --OC 5 H 11 , --OC 6 H 13 , --CH 3 , --C 2 H 5 , --C 3 H 7 , --C 4 H 9 , --C 5 H 11 , --C 6 H 13 , --C 7 H 15 , --C 8 H 17 , H, Cl, Br, --C 9 H 19 , --C 10 H 21 , --C 11 H 23 , --C 12 H 25 , --C 14 H 29 , --C 16 H 33 , and Chol represents a compound represented by the formula ##STR14##

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-06-26 1992-12-26 1993-06-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-06-26 1996-12-26 1997-06-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-06-26 2000-12-26 2001-06-27 $7700.00 Window Closed / Lapsed

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