US4840816A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of fabricating optical waveguides by ion implantation doping
Assignee: United States Department of Energy
•
Filing: 1987-03-24
•
Granted: 1989-06-20
•
Expires: 2007-03-24
Abstract
Abstract A method for fabricating high-quality optical waveguides in optical quality oxide crystals by ion implantation doping and controlled epitaxial recrystallization is provided. Masked LiNbO 3 crystals are implanted with high concentrations of Ti dopant at ion energies of about 350 keV while maintaining the crystal near liquid nitrogen temperature. Ion implantation doping produces an amorphous, Ti-rich nonequilibrium phase in the implanted region. Subsequent thermal annealing in a water-saturated oxygen atmosphere at up to 1000° C. produces solid-phase epitaxial regrowth onto the crystalline substrate. A high-quality single crystalline layer results which incorporates the Ti into the crystal structure at much higher concentrations than is possible by standard diffusion techniques, and this implanted region has excellent optical waveguides properties.
Inventors
- 👤 Bill R. Appleton
- 👤 Paul R. Ashley
- 👤 Christopher J. Buchal
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 16:20
CPC Classifications
G; G02; G02B; G02B6/00; G02B6/10; G02B6/12; G02B6/13; G02B6/134; G02B6/1347; C; C23; C23C; C23C14/00; C23C14/22; C23C14/48; C30; C30B; C30B1/00; C30B1/02; C30B1/023; C30B29/00; C30B29/10; C30B29/16; C30B29/22; C30B29/30; C30B31/00; C30B31/20; C30B31/22
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
178 words
A method for fabricating an optical waveguide in an oxide crystalline substrate, comprising the steps of: providing said crystalline substrate in the form of an optical quality crystalline oxide body; implanting a dopant into said crystalline oxide body over a selected waveguiding region by directing a beam of ions of a selected heavy metal dopant onto a patterned region defining said selected region of said crystalline oxide body at a selected concentration and energy for a period sufficient to alter the refractive index of said crystalline oxide body to provide optical waveguiding through said patterned region while maintaining said oxide body at a low temperature sufficient to substantially prevent thermal diffusion of said dopant and disloged crystal atoms within said crystalline oxide body; and annealing said crystalline oxide body in a water saturated oxygen atmosphere at a selected temperature and period of time sufficient to induce epitaxial regrowth of the ion implanted region of said crystalline structure of said crystalline oxide body to restore crystal structure and incorporate said dopant into the crystalline lattice of said oxide body.
Claim 2
Independent Claim
178 words
A method for fabricating an optical waveguide in an oxide crystalline substrate, comprising the steps of: providing said crystalline substrate in the form of an optical quality crystalline oxide body; implanting a dopant into said crystalline oxide body over a selected waveguiding region by directing a beam of ions of a selected heavy metal dopant onto a patterned region defining said selected region of said crystalline oxide body at a selected concentration and energy for a period sufficient to alter the refractive index of said crystalline oxide body to provide optical waveguiding through said patterned region while maintaining said oxide body at a low temperature sufficient to substantially prevent thermal diffusion of said dopant and disloged crystal atoms within said crystalline oxide body; and annealing said crystalline oxide body in a water saturated oxygen atmosphere at a selected temperature and period of time sufficient to induce epitaxial regrowth of the ion implanted region of said crystalline structure of said crystalline oxide body to restore crystal structure and incorporate said dopant into the crystalline lattice of said oxide body.
Claim 3
Dependent Claim
16 words
The method of claim 1 wherein said oxide crystalline sustrate is a LiNbO 3 crystalline body.
Claim 4
Dependent Claim
25 words
The method of claim 2 wherein said heavy metal dopant is selected from the group consisting of Ti, Cs, Pb, Cu, Ag, Cr, and Ni.
Claim 5
Dependent Claim
41 words
The method of claim 3 wherein said LiNbO 3 crystalline body is maintained at a temperature of about -190° C. in a high vacuum environment during said implanting step and subsequently maintained at said low temperature prior to said annealing step.
Claim 6
Dependent Claim
24 words
The method of claim 4 wherein said annealing step is carried out at a temperature in the range of from 800° to 1000° C.
Claim 7
Independent Claim
202 words
A method for fabricating optical waveguide channel regions in an optical quality LiNbO 3 single crystal, comprising the steps of: applying a coating of a suitable ion masking material onto a selected surface of said crystal to form a masked surface having openings aligned with said waveguide channels to be formed in said crystal; implanting a dopant metal into said channel regions of said crystal by directing a beam of ions of a metal dopant selected from the group consisting of Ti, Cs, Pb, Cu, Ag, Cr, and Ni onto said masked surface of said crystal at a selected density and energy for a period to implant sufficient ions of said metal dopant into said crystal to alter the refractive index thereof in said waveguide channel regions to a degree sufficient to produce the desired light waveguiding properties of said channel regions; removing said masking metal from said surface of said crystal; and annealing said crystal in a water saturated oxygen atmosphere at a temperature in the range of from 800° to 1000° C. for a period sufficient to produce epitaxial regrowth of said ion implanted regions of said crystal to essentially the original crystalline structure of said LiNbO 3 single crystal.
Claim 8
Independent Claim
202 words
A method for fabricating optical waveguide channel regions in an optical quality LiNbO 3 single crystal, comprising the steps of: applying a coating of a suitable ion masking material onto a selected surface of said crystal to form a masked surface having openings aligned with said waveguide channels to be formed in said crystal; implanting a dopant metal into said channel regions of said crystal by directing a beam of ions of a metal dopant selected from the group consisting of Ti, Cs, Pb, Cu, Ag, Cr, and Ni onto said masked surface of said crystal at a selected density and energy for a period to implant sufficient ions of said metal dopant into said crystal to alter the refractive index thereof in said waveguide channel regions to a degree sufficient to produce the desired light waveguiding properties of said channel regions; removing said masking metal from said surface of said crystal; and annealing said crystal in a water saturated oxygen atmosphere at a temperature in the range of from 800° to 1000° C. for a period sufficient to produce epitaxial regrowth of said ion implanted regions of said crystal to essentially the original crystalline structure of said LiNbO 3 single crystal.
Claim 9
Dependent Claim
69 words
The method of claim 6 wherein said dopant metal is Ti and wherein said implanting step is carried out in a vaccum environment at a pressure of at least 10- 7 Torr and at an ion beam energy of 360 keV for a period sufficient to provide a dopant density in the range of from 1.2×10 17 to 2.5×10 17 Ti/cm 2 in said channel regions of said crystal.
Claim 10
Dependent Claim
12 words
The method of claim 7 wherein said ion masking material is titanium.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-06-19 | 1992-12-19 | 1993-06-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-06-19 | 1996-12-19 | 1997-06-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-06-19 | 2000-12-19 | 2001-06-20 | $7700.00 | Window Closed / Lapsed |