US4839425A
Expired / Lapsed
US
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Thermoplastic resin composition comprising a polyphenylene ether and a polyamide
Assignee: JSR Corp
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Filing: 1987-03-30
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Granted: 1989-06-13
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Expires: 2007-03-30
Abstract
Abstract A thermoplastic resin composition obtained by melt-mixing: (a) 4 to 95% by weight of a polyphenylene ether resin, (b) 4 to 95% by weight of a polyamide, (c) 1 to 50% by weight of a rubbery polymer, and (d) if necessary, 91% by weight or less of a styrene resin (d) [the sum of the (a), (b), (c) and (d) components is 100% by weight] in the presence of 0.001 to 10% by weight, based on the total weight of the (a), (b), (c) and (d) components, of at least one functional group-containing unsaturated compound having at least one group selected from the class consisting of carboxyl group, acid anhydride group, epoxy group, hydroxyl group, amino group and amido group and 0.001 to 5% by weight, based on the total weight of the (a), (b), (c) and (d) components, of a peroxide. This thermoplastic resin composition is excellent in balance of impact strength of thin molded product, moldability and heat resistance. Therefore, the composition can be used as molded products such as external and internal trim parts of automobiles, electric and electronic components, housings and the like, requiring a high quality, and accordingly is highly valuable in industrial utilization.
Inventors
- 👤 Masaaki Mawatari
- 👤 Tetsuo Itoh
- 👤 Syuji Tsuchikawa
- 👤 Shinichi Kimura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 17:57
CPC Classifications
C; C08; C08L; C08L77/00; C08L25/00; C08L25/02; C08L25/04; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/123; C08L21/00; C08L79/00; C08L79/04; C08L79/08; C08L81/00; C08L81/02; C08L81/06; Y; Y10; Y10S; Y10S525/00; Y10S525/905
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
238 words
A thermoplastic resin composition obtained by first melt-mixing the following (a), (c) and (d) components in the presence of the following (e) component and (f) a peroxide, and then melt-mixing the following (b) component therewith: (a) 4 to 95% by weight of a polyphenylene ether resin, (b) 4-95% by weight of a polyamide, (c) 1-50% by weight of a rubbery polymer selected from the group consisting of polybutadiene, styrene-butadiene random copolymers, styrene-isoprene copolymers, acrylonitrile-butadiene copolymers, ethylene-α-olefin copolymers, ethylene-α-olefin-polyene copolymers, acrylic rubbers, polyisoprene, styrene-butadiene butadiene block copolymers, styrene-isoprene block copolymers, hydrogenated styrene-butadiene block copolymers, styrene-grafted ethylene-propylene elastomers and ethylenic ionomer resins, and (d) 91% by weight or less of a styrene resin selected from the group consisting of polystyrene, styrene-unsaturated acid copolymers, styrene-epoxy group-containing unsaturated compound copolymers, styrene-acid anhydride group-containing unsaturated compound copolymers, styrene-alkali (meth)acrylate copolymers, styrene-alkenyl cyanide compound copolymers, styrene-maleimide compound copolymers, styrene-amino group-containing ethylenically unsaturated compound copolymers and styrene-hydroxyl group-containing unsaturated compound copolymers, wherein the sum of the (a), (b), (c) and (d) components is 100% by weight; (e) 0.001-10% by weight based on the total weight of the (a), (b), (c) and (d) components, of at least one monomeric functional group-containing unsaturated compound having at least one group selected from the group consisting of carboxyl, acid anhydride, epoxy, hydroxy, amino and amido groups; the amount of the (f) component being 0.001-5% by weight based on the total weight of the (a), (b), (c) and (d) comoonents.
Claim 2
Dependent Claim
238 words
A thermoplastic resin composition obtained by first melt-mixing the following (a), (c) and (d) components in the presence of the following (e) component and (f) a peroxide, and then melt-mixing the following (b) component therewith: (a) 4 to 95% by weight of a polyphenylene ether resin, (b) 4-95% by weight of a polyamide, (c) 1-50% by weight of a rubbery polymer selected from the group consisting of polybutadiene, styrene-butadiene random copolymers, styrene-isoprene copolymers, acrylonitrile-butadiene copolymers, ethylene-α-olefin copolymers, ethylene-α-olefin-polyene copolymers, acrylic rubbers, polyisoprene, styrene-butadiene butadiene block copolymers, styrene-isoprene block copolymers, hydrogenated styrene-butadiene block copolymers, styrene-grafted ethylene-propylene elastomers and ethylenic ionomer resins, and (d) 91% by weight or less of a styrene resin selected from the group consisting of polystyrene, styrene-unsaturated acid copolymers, styrene-epoxy group-containing unsaturated compound copolymers, styrene-acid anhydride group-containing unsaturated compound copolymers, styrene-alkali (meth)acrylate copolymers, styrene-alkenyl cyanide compound copolymers, styrene-maleimide compound copolymers, styrene-amino group-containing ethylenically unsaturated compound copolymers and styrene-hydroxyl group-containing unsaturated compound copolymers, wherein the sum of the (a), (b), (c) and (d) components is 100% by weight; (e) 0.001-10% by weight based on the total weight of the (a), (b), (c) and (d) components, of at least one monomeric functional group-containing unsaturated compound having at least one group selected from the group consisting of carboxyl, acid anhydride, epoxy, hydroxy, amino and amido groups; the amount of the (f) component being 0.001-5% by weight based on the total weight of the (a), (b), (c) and (d) comoonents.
Claim 3
Dependent Claim
38 words
A thermoplastic resin composition according to claim 1, wherein at least one of the (a), (b) and (c) components is dispersed in the composition and the dispersed particles have a weight-average particle diameter of 5 μm or less.
Claim 4
Dependent Claim
196 words
A thermoplastic resin composition according to claim 1, wherein the functional group-containing unsaturated compound is selected from the class consisting of unsaturated carboxylic acids; unsaturated carboxylic anhydrides; unsaturated glycidyl esters, unsaturated glycidyl esters, epoxyalkenes and p-glycidylstyrenes representedby the formulas: ##STR8## wherein R 5 is a C 2-18 hydrocarbon group having an ethylenic unsaturation; R 6 is a hydrogen atom or a methyl group; and X is --CH 2 --O--, ##STR9## or; ##STR10## alcohols having a double bond; alcohols having a triple bond; esters of an unsaturated mono- or dicarboxylic acid with an unsubstituted dihydric alcohol, an unsubstituted trihydric alcohol, an unsubstituted tetrahydric alcohol or an unsubstituted penta- or higher-hydric alcohol; and alkenyl compounds having at least one group selected from the amino, substituted amino, amido and substituted amido groups represented by the formula: ##STR11## wherein R 7 is a hydrogen atom, a methyl group or an ethyl group; and R 8 is a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, an alkanoyl group having 2 to 12 carbon atoms, an aryl group having 6 to 12 carbon atoms, a cycloalkyl group having 6 to 12 carbon atoms or a derivative group thereof.
Claim 5
Dependent Claim
32 words
A thermoplastic resin composition according to claim 1, wherein the functional group-containing unsaturated compound is at least one compound selected from the class consisting of unsaturated carboxylic acids and unsaturated carboxylic anhydrides.
Claim 6
Dependent Claim
19 words
A thermoplastic resin composition according to claim 1, wherein the functional group-containing unsaturated compound is an unsaturated carboxylic anhydride.
Claim 7
Dependent Claim
58 words
A thermoplastic resin composition according to claim 4, wherein the unsaturated carboxylic acid is selected from the class consisting of acrylic acid, methacrylic acid, crotonic acid, cinnamic acid, itaconic acid and maleic acid, and the unsaturated carboxylic anhydride is selected from the class consisting of maleic anhydride, itaconic anhydride, chloromaleic anhydride, citraconic anhydride, butenylsuccinic anhydride and tetrahydrophthalic anhydride.
Claim 8
Dependent Claim
22 words
A thermoplastic resin composition according to claim 1, wherein the functional group-containing unsaturated compound is acrylic acid, methacrylic acid or maleic anhydride.
Claim 9
Dependent Claim
16 words
A thermoplastic resin composition according to claim 5, wherein the unsaturated carboxylic anhydride is maleic anhydride.
Claim 10
Dependent Claim
23 words
A thermoplastic resin composition according to claim 1, wherein the amount of the functional group-containing unsaturated compound is 0.005 to 5% by weight.
Claim 11
Dependent Claim
39 words
A thermoplastic resin composition according to claim 1, wherein the peroxide is at least one organic peroxide selected from the class consisting of 2,5-dimethyl-2,5-di(tert-butylperoxy)hexyne-3, 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane, 2,2'-bis(tert-butylperoxy)p-diisopropylbenzenedicumyl peroxide, di-tert-butyl peroxide, tert-butyl peroxybenzoate, 1,1-bis(tertbutylperoxy)-3,3,5-trimethylcyclohexane, 2,4-dichlorobenzoyl peroxide, benzoyl peroxide, and p-chlorobenzoyl peroxide.
Claim 12
Dependent Claim
16 words
A thermoplastic resin composition according to claim 10, wherein the organic peroxide is 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane or 2,5-di(tert-butylperoxy)hexyne-3.
Claim 13
Dependent Claim
20 words
A thermoplastic resin composition according to claim 1, wherein the amount of the peroxide is 0.005 to 2% by weight.
Claim 14
Dependent Claim
34 words
A thermoplastic resin composition according to claim 1, wherein the amount of the (a) component is 5 to 50% by weight and the amount of the (b) component is 40 to 90% by weight.
Claim 15
Dependent Claim
21 words
A thermoplastic resin composition according to claim 1, wherein the amount of the (d) component is 1 to 50% by weight.
Claim 16
Dependent Claim
19 words
A thermoplastic resin composition according to claim 2, wherein the component dispersed in the composition is the (a) component.
Claim 17
Dependent Claim
22 words
A thermoplastic resin composition according to claim 1, wherein the melt-mixing is conducted by a twin-screw extruder at 200° to 350° C.
Claim 18
Dependent Claim
20 words
A thermoplastic resin composition according to claim 2, wherein the diameter of the dispersed particles is 3 μm or less.
Claim 19
Dependent Claim
58 words
A thermoplastic resin composition according to claim 1, wherein the polyphenylene ether resin (a) is a polymer represented by the formula: ##STR12## wherein R 1 , R 2 , R 3 and R 4 , which may be the same or different, represent alkyl groups, aryl groups, halogen atoms or hydrogen atoms; and n is degree of polymerization.
Claim 20
Dependent Claim
93 words
A thermoplastic resin composition according to claim 1, wherein the polyamide as the (b) component is at least one polyamide selected from the class consisting of condensation products of a linear diamine represented by the formula: H.sub.2 N--(CH.sub.2).sub.x --NH.sub.2 wherein x is an integer of 4 to 12 with a linear dicarboxylic acid represented by the formula: HO.sub.2 C--(CH.sub.2).sub.y --CO.sub.2 H wherein y is an integer of 2 to 12; polyamides formed by the ring opening polymerization of a lactam; semi-aromatic polyamides formed from m-xylenediamine and the above linear dicarboxylic acid; and polyesteramides.
Claim 21
Dependent Claim
41 words
A thermoplastic resin composition according to claim 1, wherein the rubbery polymer as the (c) component is at least one rubbery polymer selected from the class consisting of polybutadiene, ethylene-α-olefin copolymers, ethylene-α-olefin-polyene copolymers, styrene-butadiene block copolymers and hydrogenated styrene-butadiene block copolymers.
Claim 22
Dependent Claim
33 words
A thermoplastic resin composition according to claim 19, wherein the rubbery polymer as the (c) component is selected from the class consisting of polybutadienes, styrene-butadiene random copolymers, ethylene-alpha-olefin copolymers and styrene-butadiene block copolymers.
Claim 23
Dependent Claim
23 words
A thermoplastic resin composition according to claim 1, wherein the styrene resin (d) is a styrene-glycidyl methacrylate copolymer or a styrene-acrylic acid copolymer.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-06-12 | 1992-12-12 | 1993-06-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-06-12 | 1996-12-12 | 1997-06-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-06-12 | 2000-12-12 | 2001-06-13 | $7700.00 | Window Closed / Lapsed |