US4839400A
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Active energy ray-curable resin composition
Assignee: Canon Inc
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Filing: 1987-03-06
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Granted: 1989-06-13
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Expires: 2007-03-06
Abstract
Abstract An active energy ray-curable resin composition comprises (A) a graft copolymerized polymer comprising graft chains composed mainly of structural units derived from at least one monomer selected from the group consisting of (a) hydroxyl containing (meth)acrylic monomers, (b) amino or alkylamino containing (meth)acrylic monomers, (c) carboxyl containing (meth)acrylic or vinyl monomers, (d) N-vinylpyrrolidone, (e) vinylpyridine or its derivatives and (f) (meth)acrylic amide derivatives represented by the general formula (II) shown below: ##STR1## (wherein R 1 is hydrogen or methyl group and R 2 is hydrogen or an alkyl or acyl group having 1 to 4 carbon atoms which may have hydroxyl group added to trunk chains composed mainly of structural units compsiting at least one monomer selected from the group consisting of the monomer represented by the general formula (I) shown below: ##STR2## (wherein R 1 to R 8 each represent hydrogen or methyl group), alkyl (meth)acrylates, acrylonitrile and styrene, and (B) a monomer having an ethylenically unsaturated bond.
Inventors
- 👤 Yasufumi Sato
- 👤 Megumi Munakata
- 👤 Hiromichi Noguchi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 05:49
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/032; C; C08; C08F; C08F285/00; C08F290/00; C08F290/02; C08F290/04
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
167 words
An active energy ray-curable resin composition comprising: (A) a graft copolymerized polymer comprising graft chains composed mainly of structural units derived from at least one monomer selected from the group consisting of (a) hydroxyl containing (meth)acrylic monomers, (b) amino or alkylamino containing (meth)acrylic monomers, (c) carboxyl containing (meth)acrylic or vinyl monomers, (d) N-vinylpyrrolidone, (e) vinylpyridine or its derivatives and (f) (meth)acrylic amide derivatives represented by the general formula (II) shown below: ##STR7## wherein R 1 is hydrogen or methyl group and R 2 is hydrogen or an alkyl or acryl group having 1 to 4 carbon atoms which may have a hydroxyl group, added to trunk chains comprising both structural units formed from at least one monomer represented by the general formula (I) shown below: ##STR8## wherein R 1 to R 8 each represent hydrogen or methyl group, and structural units formed from at least one monomer selected from the group consisting of alkyl (meth)acrylates, acrylonitrile and styrene, and (B) a monomer having an ethylenically unsaturated bond.
Claim 2
Dependent Claim
167 words
An active energy ray-curable resin composition comprising: (A) a graft copolymerized polymer comprising graft chains composed mainly of structural units derived from at least one monomer selected from the group consisting of (a) hydroxyl containing (meth)acrylic monomers, (b) amino or alkylamino containing (meth)acrylic monomers, (c) carboxyl containing (meth)acrylic or vinyl monomers, (d) N-vinylpyrrolidone, (e) vinylpyridine or its derivatives and (f) (meth)acrylic amide derivatives represented by the general formula (II) shown below: ##STR7## wherein R 1 is hydrogen or methyl group and R 2 is hydrogen or an alkyl or acryl group having 1 to 4 carbon atoms which may have a hydroxyl group, added to trunk chains comprising both structural units formed from at least one monomer represented by the general formula (I) shown below: ##STR8## wherein R 1 to R 8 each represent hydrogen or methyl group, and structural units formed from at least one monomer selected from the group consisting of alkyl (meth)acrylates, acrylonitrile and styrene, and (B) a monomer having an ethylenically unsaturated bond.
Claim 3
Dependent Claim
39 words
An active energy ray-curable resin composition according to claim 1, containing 20 to 80 parts by weight of the graft copolymerized polymer (A) and 80 to 20 parts by weight of the monomer having an ethylenically unsaturated bond (B).
Claim 4
Dependent Claim
39 words
An active energy ray-curable resin composition according to claim 1, wherein the proportion of the monomer represented by the formula (I) formulated in the graft copolymerized polymer (A) is within the range of from 1 to 30% by weight.
Claim 5
Dependent Claim
38 words
An active energy ray-curable resin composition according to claim 1, wherein said monomer having an ethylenically unsaturated bond has a boiling point of 100° C. or higher under the atmospheric pressure and at least two ethylenically unsaturated bonds.
Claim 6
Dependent Claim
97 words
An active energy ray-curable resin composition according to claim 1, wherein said monomer having an ethylenically unsaturated bond is selected from the group consisting of (i) (meth)acrylic acid esters of polyfunctional epoxy resins having two or more epoxy groups in one molecule; (ii) (meth)acrylic acid esters of alkyleneoxide addition products of polyhydric alcohols; (iii) polyester (meth)acrylates having (meth)acrylic acid ester group at the terminal ends of the molecular chains of polyesters having molecular weights of 500 3000 comprising dibasic acid and dihydric alcohol; and (iv) the reaction products between polyisocyanates and (meth)acrylic acid monomers having hydroxyl groups.
Claim 7
Dependent Claim
20 words
An active energy ray-curable resin composition according to claim 4, further containing a monomer having only one ethylenically unsaturated bond.
Claim 8
Dependent Claim
25 words
An active energy ray-curable resin composition according to claim 1, further comprising a monomer which is subjected to ring opening by heat to be crosslinked.
Claim 9
Dependent Claim
16 words
An active energy ray-curable resin composition according to claim 7, wherein the monomer is glycidyl (meth)acrylate.
Claim 10
Dependent Claim
27 words
An active energy ray-curable resin composition according to claim 1, wherein a photopolymerizable monomer is added to some of the graft chains of said graft copolymerized polymer.
Claim 11
Dependent Claim
36 words
An active energy ray-curable resin composition according to claim 1, wherein a hydrophobic monomer is contained within the range of 0 to about 25% by weight as a component of comonomers in said graft copolymerized polymer.
Claim 12
Dependent Claim
15 words
An active energy ray-curable resin composition according to claim 1, further comprising a photopolymerization initiator.
Claim 13
Dependent Claim
47 words
An active energy ray-curable resin composition according to claim 1, further comprising 0.1 to 20 parts by weight of a photopolymerization initiator based on 100 parts by weight of the total amount of the graft copolymerized polymer (A) and the monomer having an ethylenically unsaturated bond (B).
Claim 14
Dependent Claim
32 words
An active energy ray-curable resin composition according to claim 11, wherein the photopolymerization initiator is a compound selected from the group consisting of dibenzoyl, benzoin alkyl ethers, benzophenones, anthraquinones, xanthones and acetophenones.
Claim 15
Dependent Claim
15 words
An active energy ray-curable resin composition according to claim 11, further comprising a photopolymerization accelerator.
Claim 16
Dependent Claim
18 words
An active energy ray-curable resin composition according to claim 14, wherein the photopolymerization accelerator is an amino compound.
Claim 17
Dependent Claim
35 words
An active energy ray-curable resin composition according to claim 1, further comprising an additive selected from the group consisting of catalysts for condensation cross-linking, heat polymerization inhibitors, colorants, fine particulate fillers, adhesion promotors, and plasticizers.
Claim 18
Dependent Claim
28 words
An active energy ray-curable resin composition according to claim 16, wherein the catalyst for condensation cross-linking is selected from the group consisting of sulfonic acids and carboxylic acids.
Claim 19
Dependent Claim
29 words
An active energy ray-curable resin composition according to claim 16, wherein the heat polymerization inhibitor is selected from the group consisting of hydroquinone and its derivatives, p-ethoxyphenol and phenothiazine.
Claim 20
Dependent Claim
24 words
An active energy ray-curable resin composition according to claim 16, wherein the colorant if selected from the group consisting of oil-soluble dyes and pigments.
Claim 21
Dependent Claim
28 words
An active energy ray-curable resin composition according to claim 16, wherein the fine particulate filler is selected from the group consisting of extender pigments and fine plastic particles.
Claim 22
Dependent Claim
28 words
An active energy ray-curable resin composition according to claim 16, wherein the adhesion promotor is selected from the group consisting of silane coupling agents and low molecular surfactants.
Claim 23
Dependent Claim
24 words
An active energy ray-curable resin composition according to claim 1, wherein said graft copolymer has a weight-average molecular weight of about 5000 to 300,000.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-06-12 | 1992-12-12 | 1993-06-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-06-12 | 1996-12-12 | 1997-06-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-06-12 | 2000-12-12 | 2001-06-13 | $7700.00 | Window Closed / Lapsed |