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US4839329A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for manufacturing a titania supported palladium catalyst

Assignee: Korea Advanced Institute of Science and Technology
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Filing: 1987-10-23
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Granted: 1989-06-13
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Expires: 2007-10-23
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Abstract

Abstract A process for manufacturing palladium catalyst on titania for converting acetylene to ethylene selectively, wherein the catalyst is composed of palladium in amount of 0.01-0.2% by weight and a titania carrier of 99.9-99.8% by weight.

Inventors

  • 👤 Sun K. Ihm
  • 👤 Dong K. Lee

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 19:39
CPC Classifications
C; C07; C07C; C07C11/00; C07C11/02; C07C11/04; B; B01; B01J; B01J23/00; B01J23/38; B01J23/40; B01J23/44

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 181 words
A process for manufacturing a titanium oxide supported palladium catalyst to convert acetylene to ethylene consisting essentially of: (a) removing moisture in an amount of titanium oxide in a vacuum at a temperature of 450° C. for 12 hours to produce dried titanium oxide, (b) dissolving an amount of palladium chloride in hydrochloric acid to produce a palladium solution and mixing sodium acetate with said palladium solution to produce an initial mixture, (c) diluting said initial mixture with distilled water, (d) pouring said diluted mixture into said dried titanium oxide to produce a second mixture, (e) mixing said second mixture at a pressure of 10 torr and a temperature of 80° C. to produce a third mixture, and (f) calcining said third mixture at a temperature of 500° C. for 3 hours and cooling to produce the catalyst composed of palladium in an amount of 0.01% to 0.2% by weight and titanium oxide carrier in an amount of 99.99% to 99.8% by weight, wherein said catalyst is selective in converting acetylene to ethylene but prevents the conversion of ethylene to ethane.
Claim 2
Dependent Claim 181 words
A process for manufacturing a titanium oxide supported palladium catalyst to convert acetylene to ethylene consisting essentially of: (a) removing moisture in an amount of titanium oxide in a vacuum at a temperature of 450° C. for 12 hours to produce dried titanium oxide, (b) dissolving an amount of palladium chloride in hydrochloric acid to produce a palladium solution and mixing sodium acetate with said palladium solution to produce an initial mixture, (c) diluting said initial mixture with distilled water, (d) pouring said diluted mixture into said dried titanium oxide to produce a second mixture, (e) mixing said second mixture at a pressure of 10 torr and a temperature of 80° C. to produce a third mixture, and (f) calcining said third mixture at a temperature of 500° C. for 3 hours and cooling to produce the catalyst composed of palladium in an amount of 0.01% to 0.2% by weight and titanium oxide carrier in an amount of 99.99% to 99.8% by weight, wherein said catalyst is selective in converting acetylene to ethylene but prevents the conversion of ethylene to ethane.
Claim 3
Dependent Claim 23 words
The process of claim 1, wherein the titanium oxide of the step (a) is poured into a flask of a rotary vacuum evaporator.
Claim 4
Dependent Claim 17 words
The process of claim 1, wherein the cooling of the step (f) is conducted at room temperature.

References Cited (Backward Citations)

US2030283A Cited
GB922022A Cited
US3271327A Cited
US4374047A Cited
JPS59112835A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-06-12 1992-12-12 1993-06-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-06-12 1996-12-12 1997-06-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-06-12 2000-12-12 2001-06-13 $7700.00 Window Closed / Lapsed

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