US4837128A
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Light-sensitive composition
Assignee: Fujifilm Holdings Corp
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Filing: 1987-07-29
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Granted: 1989-06-06
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Expires: 2007-07-29
Abstract
Abstract A light-sensitive composition is herein disclosed, which comprises at least one light-sensitive s-triazine compound represented by the following general formula (I) and at least one compound having at least one ethylenically unsaturated double bond and capable of causing addition polymerization: ##STR1## wherein R 1 and R 2 independently represent hdyrogen atom, a substituted or unsubstituted alkyl or aryl group, or a group represented by the general formula: R 5 --CO-- or N(R 6 ) (R 7 )--CO-- (wherein R 5 stands for a substituted or unsubstituted alkyl or aryl group; and R 6 and R 7 independently represent hydrogen atom or a substituted or unsubstituted alkyl or aryl group), provided that R 1 and R 2 may form a heterocyclic ring consisting of non-metallic atoms together with the nitrogen atom to which they are bonded; R 3 and R 4 represent hydrogen, a halogen, an alkyl or an alkoxyl; X and Y independently represent chlorine or bromine; and m and n are 0, 1 or 2. The light-sensitive composition has high sensitivity even after storing at a high temperature and effectively used for producing light-sensitive plates for making lithographic printing plates; proof plates for printing; films for overhead projector, intermediate print and photomasks; and photoresists.
Inventors
- 👤 Kouichi Kawamma
- 👤 Yukio Abe
- 👤 Tatsuji Higashi
- 👤 Yoshimasa Aotani
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 17:14
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/029; G03F7/0295; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/117; Y10S430/12; Y10S430/121
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
212 words
A light-sensitive composition comprises at least one light-sensitive s-triazine compound represented by the following general formula (I) and at leat one compound having at least one ethylenically unsaturated double bond and capable of causing addition polymerization: ##STR16## wherein R 1 and R 2 may or may not be identical with each other and represent hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a group represented by the following general formula (II) or (III): ##STR17## (in the general formulas (II) and (III), R 5 stands for a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; and R 6 and R 7 may or may not be identical with each other and represent hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group), provided that R 1 and R 2 may form a heterocyclic ring consisting of non-metallic atoms together with the nitrogen atom to which they are bonded; R 3 and R 4 represent hydrogen atom, a halogen atom, an alkyl group or an alkoxyl group; X and Y may or may not be identical with each other and represent chlorine atom or bromine atom; and m and n are an integer of 0, 1 or 2.
Claim 2
Dependent Claim
212 words
A light-sensitive composition comprises at least one light-sensitive s-triazine compound represented by the following general formula (I) and at leat one compound having at least one ethylenically unsaturated double bond and capable of causing addition polymerization: ##STR16## wherein R 1 and R 2 may or may not be identical with each other and represent hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a group represented by the following general formula (II) or (III): ##STR17## (in the general formulas (II) and (III), R 5 stands for a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; and R 6 and R 7 may or may not be identical with each other and represent hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group), provided that R 1 and R 2 may form a heterocyclic ring consisting of non-metallic atoms together with the nitrogen atom to which they are bonded; R 3 and R 4 represent hydrogen atom, a halogen atom, an alkyl group or an alkoxyl group; X and Y may or may not be identical with each other and represent chlorine atom or bromine atom; and m and n are an integer of 0, 1 or 2.
Claim 3
Dependent Claim
49 words
The light-sensitive composition as set forth in claim 1 wherein the substituted or unsubstituted alkyl group represented by R 1 to R 7 has 1 to 6 carbon atoms and the substituted or unsubstituted aryl group represented by R 1 to R 7 has 6 to 14 carbon atoms.
Claim 4
Dependent Claim
189 words
The light-sensitive composition as set forth in claim 2 wherein the substituent of the substituted alkyl or aryl group appearing in R 1 and R 2 is selected from the group consisting of aryl groups in the case of substituted alkyl groups, alkyl groups in the case of substituted aryl groups, halogen atoms, alkoxyl groups, carboxyl groups, carboalkoxy groups, carboaryloxy groups, cyano groups, acyl groups, nitro groups, dialkylamino groups, and groups derived from sulfonyl derivatives represented by the general formula: --SO 2 --Z, --SO 3 --Z or --SO 2 --NH--Z wherein Z represents a hydrogen atom, an alkyl group or an aryl group; and the substituent of the substituted alkyl or aryl group appearing in R 5 to R 7 is selected from the group consisting of aryl groups in the case of substituted alkyl groups, alkyl groups in the case of substituted aryl groups, halogen atoms, cyano groups, acyl groups, nitro groups, dialkylamino groups, and groups derived from sulfonyl derivatives represented by the general formula: --SO 2 --Z, --SO 3 --Z or --SO 2 --NH--Z wherein Z represents a hydrogen atom, an alkyl group or an aryl group.
Claim 5
Dependent Claim
75 words
The light-sensitive composition as set forth in claim 2 wherein the substituent of the substituted alkyl or aryl group represented by R 1 and R 2 is a member selected from the group consisting of halogen atoms, carboxyl groups, carboalkoxy groups, cyano groups, acyl groups and groups derived from sulfonyl derivatives and the substituent of the substituted alkyl or aryl group of R 5 is a member selected from the group consisting of dialkylamino groups.
Claim 6
Dependent Claim
30 words
The light-sensitive composition as set forth in claim 1 wherein R 1 and R 2 form a heterocyclic ring selected from the group consisting of groups (D) to (H): ##STR18##
Claim 7
Dependent Claim
92 words
The light-sensitive composition as set forth in claim 1 wherein the s-triazine compound is selected from the group consisting of those represented by the general formula (I) in which R 1 and R 2 represent hydrogen atom, a carboalkoxymethyl group, chloromethyl group, chloroethyl group or cyanoethyl group, provided that at least one of them represents a group other than hydrogen atom or R 1 and R 2 form a ring represented by the following formula: ##STR19## and R 3 and R 4 represent hydrogen atom, a halogen atom or an alkyl group.
Claim 8
Dependent Claim
52 words
The light-sensitive composition as set forth in claim 1 wherein the compound having at least one ethylenically unsaturated double bond is selected from the group consisting of unsaturated carboxylic acids and salts thereof; esters of unsaturated carboxylic acids and aliphatic polyol compounds; and amides of unsaturated carboxylic acids and aliphatic polyamine compounds.
Claim 9
Dependent Claim
49 words
The light-sensitive composition as set forth in claim 7 wherein the substituted or unsubstituted alkyl group represented by R 1 to R 7 has 1 to 6 carbon atoms and the substituted or unsubstituted aryl group represented by R 1 to R 7 has 6 to 14 carbon atoms.
Claim 10
Dependent Claim
18 words
The light-sensitive composition as set forth in claim 8 wherein the composition further comprises at least one binder.
Claim 11
Dependent Claim
26 words
The light-sensitive composition as set forth in claim 9 the binder is a linear organic high molecular polymer having a molecular weight of 5,000 to 2,000,000.
Claim 12
Dependent Claim
18 words
The light-sensitive composition as set forth in claim 9 wherein the composition further comprises at least one sensitizer.
Claim 13
Dependent Claim
71 words
The light-sensitive composition as set forth in claim 11 wherein the sensitizer is selected from the group consisting of Michler's ketone and compounds represented by the following general formula (VI): ##STR20## wherein R 1 represents a substituted or unsubstituted alkyl group, R 2 represents an alkyl group or an aryl group and Z represents non-metallic atoms required to form a heterocyclic group derived from benzothiazoles, naphthothiazoles, benzoselenazoles, naphthoselenazoles, benzoxazoles or naphthoxazoles.
Claim 14
Dependent Claim
19 words
The light-sensitive composition as set forth in claim 11 wherein the composition comprises at least one heat polymerization inhibitor.
Claim 15
Dependent Claim
36 words
The light-sensitive composition as set forth in claim 13 wherein the heat polymerization inhibitor is selected from the group consisting of hydroquinone, p-methoxyphenol, di-tert-butyl-p-cresol, pyrogallol, tert-butylcatechol, benzoquinone, cuprous chloride, phenothiazine, chloranil, naphthylamine, beta-naphthol, nitrobenzene and dinitrobenzene.
Claim 16
Dependent Claim
18 words
The light-sensitive composition as set forth in claim 13 wherein the composition comprises a dye or a pigment.
Claim 17
Dependent Claim
15 words
The light-sensitive composition as set forth in claim 15 wherein the composition comprises a plasticizer.
Claim 18
Dependent Claim
99 words
The light-sensitive composition as set forth in claim 1 wherein the light-sensitive composition comprises 0.01 to 100 parts by weight of the compound represented by the general formula (I), 0 to 1,000 parts by weight of the binder, 0 to 100 parts by weight of the sensitizer, 0 to 10 parts by weight of the heat polymerization inhibitor, 0 to 50 parts by weight of the dye or the pigment and 0 to 200 parts by weight of the plasticizer on the basis of 100 parts by weight of the compound having at least one ethylenically unsaturated double bond.
Claim 19
Dependent Claim
99 words
The light-sensitive composition as set forth in claim 17 wherein the light-sensitive composition comprises 0.1 to 30 parts by weight of the compound represented by the general formula (I), 0 to 500 parts by weight of the binder, 0 to 20 parts by weight of the sensitizer, 0 to 5 parts by weight of the heat polymerization inhibitor, 0 to 20 parts by weight of the dye or the pigment and 0 to 50 parts by weight of the plasticizer on the basis of 100 parts by weight of the compound having at least one ethylenically unsaturated double bond.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-06-05 | 1992-12-05 | 1993-06-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-06-05 | 1996-12-05 | 1997-06-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-06-05 | 2000-12-05 | 2001-06-06 | $7700.00 | Window Closed / Lapsed |