US4836833A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Production and recovery of hydrogen and carbon monoxide
Assignee: Air Products and Chemicals Inc
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Filing: 1988-02-17
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Granted: 1989-06-06
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Expires: 2008-02-17
Abstract
Abstract Separation and individual recovery of high purity hydrogen and carbon monoxide from a mixed gas stream containing these compounds in association with carbon dioxide and one or more minor components such as particularly methane, is achieved by pressure swing adsorption to remove contained carbon dioxide from the charged gas, and further treatment of the CO 2 -freed gas product by a sequence of steps utilizing (a) pressure swing adsorption and (b) selective permeation through a series of semi-permeable membranes, which steps (a) and (b) are carried out in either order of sequence.
Inventors
- 👤 David M. Nicholas
- 👤 Stephen P. Goff
- 👤 Thomas M. Roden
- 👤 Joseph P. Bushinsky
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 20:00
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/02; B01D53/04; B01D53/047; B01D53/0476; B01D53/22; B01D53/229; C; C01; C01B; C01B3/00; C01B3/50; C01B3/501; C01B3/56; C01B32/00; C01B32/40; B01D2253/00; B01D2253/10; B01D2253/102; B01D2253/106; B01D2253/108; B01D2253/116; B01D2256/00; B01D2256/16; B01D2256/20; B01D2257/00; B01D2257/50; B01D2257/504; B01D2257/70; B01D2257/702; B01D2257/7022; B01D2257/7025; B01D2259/00; B01D2259/40; B01D2259/40001; B01D2259/40011; B01D2259/40013; B01D2259/40015; B01D2259/40028; B01D2259/4003; B01D2259/40032; B01D2259/40043; B01D2259/4005; B01D2259/40052; B01D2259/40058; B01D2259/40064; B01D2259/40066; B01D2259/40067; B01D2259/403; B01D2259/404; B01D2259/406; B01D2259/4062; C01B2203/00; C01B2203/04; C01B2203/0405; C01B2203/042; C01B2203/043; C01B2203/0465; C01B2203/047; C01B2203/0475; C01B2203/048; Y; Y02; Y02C; Y02C20/00; Y02C20/20; Y02C20/40; Y02P; Y02P20/00; Y02P20/151; Y02P20/156
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
129 words
The method for individual recovery of hydrogen and carbon monoxide each at high purity, from a contaminated gas mixture containing these in association with carbon dioxide and methane, which comprises: passing the gas mixture at superatmospheric pressure through a bed of solid adsorbent selective in adsorptive retention of carbon dioxide while discharging from said bed the unadsorbed primary effluent; purifying said primary effluent by treatments, in either order of sequence, comprising: (a) pressure swing adsorption and (b) selective permeation through a system comprised of one or more semi-permeable membranes, thereby recovering hydrogen as a permeate stream separated from a non-permeate stream rich in carbon monoxide, said hydrogen stream having a purity of at least 99 mol% H 2 and said non-permeate stream comprising at least about 85 mol% CO.
Claim 2
Independent Claim
129 words
The method for individual recovery of hydrogen and carbon monoxide each at high purity, from a contaminated gas mixture containing these in association with carbon dioxide and methane, which comprises: passing the gas mixture at superatmospheric pressure through a bed of solid adsorbent selective in adsorptive retention of carbon dioxide while discharging from said bed the unadsorbed primary effluent; purifying said primary effluent by treatments, in either order of sequence, comprising: (a) pressure swing adsorption and (b) selective permeation through a system comprised of one or more semi-permeable membranes, thereby recovering hydrogen as a permeate stream separated from a non-permeate stream rich in carbon monoxide, said hydrogen stream having a purity of at least 99 mol% H 2 and said non-permeate stream comprising at least about 85 mol% CO.
Claim 3
Dependent Claim
25 words
The method as defined in claim 1 wherein said primary effluent is purified by being first subjected to pressure swing adsorption then to selective permeation.
Claim 4
Dependent Claim
25 words
The method as defined in claim 2 wherein said purification by pressure swing adsorption is carried out in an adsorbent bed comprised of molecular sieve.
Claim 5
Dependent Claim
60 words
The method as defined in claim 2 wherein the components of said primary effluent retained in an adsorbent bed during said purification by pressure swing adsorption are desorbed therefrom and the desorbed product stream is compressed to a pressure of at least about 6 atmospheres before passage of said product stream through said system of one or more semi-permeable membranes.
Claim 6
Dependent Claim
71 words
The method as defined in claim 4 wherein said system is composed of three semi-permeable membranes, and wherein the permeate from the first of said membranes is recycled to be combined with the gas mixture being passed through said bed of adsorbent selective in retention of carbon dioxide, and the permeates passing through the second and third membranes are returned to combine with said desorbed product stream being subjected to compression.
Claim 7
Dependent Claim
22 words
The method as defined in claim 5 wherein said contaminated gas mixture is one obtained by steam reforming of a methane-rich feed.
Claim 8
Dependent Claim
39 words
The method as defined in claim 5 wherein said contaminated gas mixture is one obtained by two-stage reforming of natural gas in a multistage operation comprising steam reforming followed by oxidative reforming in the presence of added free oxygen.
Claim 9
Dependent Claim
41 words
The method as defined in claim 1 wherein said primary effluent is purified by being first subjected to selective permeation and the obtained permeate further subjected to pressure swing adsorption for removal of contained contaminants and recovery of high purity hydrogen.
Claim 10
Dependent Claim
37 words
The method as defined in claim 8 wherein the removal of contained contaminants from the permeate by pressure swing adsorption is carried out by selective adsorption of these contaminants in an adsorbent bed comprised of molecular sieve.
Claim 11
Dependent Claim
42 words
The method as defined in claim 8 wherein said primary effluent freed of carbon dioxide is compressed to a pressure of at least about 6 atmospheres before being subject to selective permeation through a system comprised of one or more semi-permeable membranes.
Claim 12
Dependent Claim
51 words
The method as defined in claim 10 wherein said system is comprised of three semi-permeable membranes and wherein the permeate from the first of said membranes is subjected to further purification by pressure swing adsorption wherein accompanying contaminants are selectively adsorbed and an unadsorbed substantially pure hydrogen product stream is discharged.
Claim 13
Dependent Claim
22 words
The method as defined in claim 11 wherein said contaminated gas mixture is one obtained by steam reforming of a methane-rich feed.
Claim 14
Dependent Claim
28 words
The method as defined in claim 12 wherein a portion of said discharged hydrogen product stream is recycled and combined with said methane-rich feed subjected to steam reforming.
Claim 15
Dependent Claim
46 words
The method as defined in claim 11 wherein the contaminants selectively adsorbed during said further purification by pressure swing adsorption are desorbed and the desorbed contaminants are recycled to combine with said contaminated gas mixture being passed through said adsorbent selective in retention of carbon dioxide.
Claim 16
Dependent Claim
53 words
The method as defined in claim 11 wherein the respective permeate from the second and third membranes are compressed to about the pressure level of the permeate leaving the first membrane and are combined therewith, the combined permeates being subjected to further purification by pressure swing adsorption and recovery of substantially pure hydrogen.
Claim 17
Dependent Claim
40 words
The method as defined in claim 1 wherein said contaminated gas mixture is a product obtained by subjecting a methane-rich hydrocarbon stream to steam reforming followed by oxidative reforming of the obtained steam reformate in the presence of added oxygen.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-06-05 | 1992-12-05 | 1993-06-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-06-05 | 1996-12-05 | 1997-06-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-06-05 | 2000-12-05 | 2001-06-06 | $7700.00 | Window Closed / Lapsed |