US4834847A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Electrochemical cell for the electrolysis of an alkali metal halide and the production of a halogenated hydrocarbon
Assignee: Dow Chemical Co
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Filing: 1987-04-03
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Granted: 1989-05-30
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Expires: 2007-04-03
Abstract
Abstract An electrochemical cell and process for the electrolysis of an aqueous solution of an alkali metal halide and the production of a halogenated hydrocarbon comprising an electrolytic cell having a gas depolarized anode and a cathode which can be a dimensionally stable or a gas depolarized cathode wherein the production of an aqueous solution of an alkali metal hydroxide and a halogenated hydrocarbon are accompanied by significantly reduced voltage requirements in the cell.
Inventors
- 👤 John M. McIntyre
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 17:23
CPC Classifications
C; C25; C25B; C25B1/00; C25B1/01; C25B1/14; C25B1/16; C25B3/00; C25B3/01; C25B3/07; C25B3/11; C25B3/20; C25B3/27
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
149 words
A process for the production of a dihalogenated olefin and an alkali metal hydroxide wherein the free energy of the electrolysis reaction of an alkali metal halide is reduced, so as to reduce energy consumption in the production of an alkali metal hydroxide, by depolarizing a gas diffusion anode with a gaseous olefin; said process comprising providing an electrochemical cell having a porous anode comprising a gas and electrolyte diffusion layer and a cathode, separated by a permselective membrane or an electrolyte permeable diaphragm, and said anode and cathode are contained respectively in an anolyte compartment and a catholyte compartment of said electrochemical cell; said process comprising; (A) flowing a gaseous olefin to said anolyte compartment; (B) flowing an aqueous alkali metal halide electrolyte to said catholyte compartment; (C) forming at least one dihalogenated olefin by reacting said gaseous olefin with a halogen; and (D) separating said dihalogenated olefin.
Claim 2
Dependent Claim
149 words
A process for the production of a dihalogenated olefin and an alkali metal hydroxide wherein the free energy of the electrolysis reaction of an alkali metal halide is reduced, so as to reduce energy consumption in the production of an alkali metal hydroxide, by depolarizing a gas diffusion anode with a gaseous olefin; said process comprising providing an electrochemical cell having a porous anode comprising a gas and electrolyte diffusion layer and a cathode, separated by a permselective membrane or an electrolyte permeable diaphragm, and said anode and cathode are contained respectively in an anolyte compartment and a catholyte compartment of said electrochemical cell; said process comprising; (A) flowing a gaseous olefin to said anolyte compartment; (B) flowing an aqueous alkali metal halide electrolyte to said catholyte compartment; (C) forming at least one dihalogenated olefin by reacting said gaseous olefin with a halogen; and (D) separating said dihalogenated olefin.
Claim 3
Dependent Claim
45 words
The process of claim 1 wherein said electrolyte permeable diaphragm consists of at least one layer of asbestos or at least one layer of a microporous polyolefin film and said olefin is selected from the group consisting of at least one of ethylene and propylene.
Claim 4
Dependent Claim
66 words
The process of claim 1 wherein said porous anode is an assembly which comprises a heterogeneous or homogeneous, gas diffusion anode and an electrically conductive current collector in contact therewith; said anode is a mixture comprising an electrically conductive, particulate material and a hydrophobic polymer; said cathode is a porous gas diffusion cathode; and said anode and cathode are separated by an anion permeable permselective membrane.
Claim 5
Dependent Claim
38 words
The process of claim 3 wherein said anode comprises a gas diffusion, hollow anode having an electrically conductive, porous, hydrophilic, electrochemically active layer comprising an electrically conductive carbon and a porous, homogeneous, hydrophobic layer comprising a hydrophobic polymer.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-05-29 | 1992-11-28 | 1993-05-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-05-29 | 1996-11-28 | 1997-05-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-05-29 | 2000-11-28 | 2001-05-30 | $7700.00 | Window Closed / Lapsed |