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US4834847A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrochemical cell for the electrolysis of an alkali metal halide and the production of a halogenated hydrocarbon

Assignee: Dow Chemical Co
•
Filing: 1987-04-03
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Granted: 1989-05-30
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Expires: 2007-04-03
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Abstract

Abstract An electrochemical cell and process for the electrolysis of an aqueous solution of an alkali metal halide and the production of a halogenated hydrocarbon comprising an electrolytic cell having a gas depolarized anode and a cathode which can be a dimensionally stable or a gas depolarized cathode wherein the production of an aqueous solution of an alkali metal hydroxide and a halogenated hydrocarbon are accompanied by significantly reduced voltage requirements in the cell.

Inventors

  • 👤 John M. McIntyre

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 17:23
CPC Classifications
C; C25; C25B; C25B1/00; C25B1/01; C25B1/14; C25B1/16; C25B3/00; C25B3/01; C25B3/07; C25B3/11; C25B3/20; C25B3/27

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 149 words
A process for the production of a dihalogenated olefin and an alkali metal hydroxide wherein the free energy of the electrolysis reaction of an alkali metal halide is reduced, so as to reduce energy consumption in the production of an alkali metal hydroxide, by depolarizing a gas diffusion anode with a gaseous olefin; said process comprising providing an electrochemical cell having a porous anode comprising a gas and electrolyte diffusion layer and a cathode, separated by a permselective membrane or an electrolyte permeable diaphragm, and said anode and cathode are contained respectively in an anolyte compartment and a catholyte compartment of said electrochemical cell; said process comprising; (A) flowing a gaseous olefin to said anolyte compartment; (B) flowing an aqueous alkali metal halide electrolyte to said catholyte compartment; (C) forming at least one dihalogenated olefin by reacting said gaseous olefin with a halogen; and (D) separating said dihalogenated olefin.
Claim 2
Dependent Claim 149 words
A process for the production of a dihalogenated olefin and an alkali metal hydroxide wherein the free energy of the electrolysis reaction of an alkali metal halide is reduced, so as to reduce energy consumption in the production of an alkali metal hydroxide, by depolarizing a gas diffusion anode with a gaseous olefin; said process comprising providing an electrochemical cell having a porous anode comprising a gas and electrolyte diffusion layer and a cathode, separated by a permselective membrane or an electrolyte permeable diaphragm, and said anode and cathode are contained respectively in an anolyte compartment and a catholyte compartment of said electrochemical cell; said process comprising; (A) flowing a gaseous olefin to said anolyte compartment; (B) flowing an aqueous alkali metal halide electrolyte to said catholyte compartment; (C) forming at least one dihalogenated olefin by reacting said gaseous olefin with a halogen; and (D) separating said dihalogenated olefin.
Claim 3
Dependent Claim 45 words
The process of claim 1 wherein said electrolyte permeable diaphragm consists of at least one layer of asbestos or at least one layer of a microporous polyolefin film and said olefin is selected from the group consisting of at least one of ethylene and propylene.
Claim 4
Dependent Claim 66 words
The process of claim 1 wherein said porous anode is an assembly which comprises a heterogeneous or homogeneous, gas diffusion anode and an electrically conductive current collector in contact therewith; said anode is a mixture comprising an electrically conductive, particulate material and a hydrophobic polymer; said cathode is a porous gas diffusion cathode; and said anode and cathode are separated by an anion permeable permselective membrane.
Claim 5
Dependent Claim 38 words
The process of claim 3 wherein said anode comprises a gas diffusion, hollow anode having an electrically conductive, porous, hydrophilic, electrochemically active layer comprising an electrically conductive carbon and a porous, homogeneous, hydrophobic layer comprising a hydrophobic polymer.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-05-29 1992-11-28 1993-05-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-05-29 1996-11-28 1997-05-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-05-29 2000-11-28 2001-05-30 $7700.00 Window Closed / Lapsed

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