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US4832467A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrochromic variable color tone nonglaring mirror

Assignee: Nissan Motor Co Ltd
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Filing: 1987-08-10
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Granted: 1989-05-23
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Expires: 2007-08-10
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Abstract

Abstract The invention relates to a nonglaring mirror which is an electrochromic (EC) device in principle. The mirror comprises a transparent front substrate provided with a transparent first electrode layer, a back substrate provided with a second electrode layer opposite to the first electrode layer, first and second EC layers formed on the first and second electrode layers, respectively, an electrolyte liquid which fills up the space between the two substrates and reflecting means for providing a reflective surface to the second substrate. The material of the first EC layer is an organic polymer which is colorless or very pale in color in its electrochemically reduced state and undergoes electrochemical oxidation in two stages to assume a characteristic color in the first-stage oxidized state and another color in the second-stage oxidized state, and intermediate colors in intermediately oxidized states. It is very favorable to use a polymer made up of repeating structural units of N,N,N',N'-tetraphenyl-p-phenylenediamine. The second EC layer is usually formed of a transition metal oxide, e.g. WO 3 , which takes on color in its electrochemically reduced state.

Inventors

  • 👤 Harutoshi Miyagi
  • 👤 Masazumi Ishikawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 02:06
CPC Classifications
B; B60; B60R; B60R1/00; B60R1/02; B60R1/08; B60R1/083; B60R1/088; G; G02; G02F; G02F1/00; G02F1/01; G02F1/15; G02F1/1514; G02F1/1516; G02F1/15165; G02F1/1523; G02F1/1524

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 187 words
An electrochromic nonglaring mirror, comprising: a transparent first substrate of which the inside surface is laid with a transparent first electrode layer; a first electrochromic layer laid on said first electrode layer and formed of an organic polymer which undergoes electrochemical oxidation and reduction in at least two states and assumes different colors at its respective stages of electrochemical oxidation and becomes pale or colorless in its electrochemically fully reduced state wherein said organic polymer is made up of repeating units represented by the following general formula: ##STR2## wherein X and X' each represent a hydrogen atom, a halogen atom, an alkyl group having not more than 4 carbon atoms or an alkoxyl group having not more than 4 carbon atoms; a second substrate comprising a second electrode layer arranged opposite to said first electrode layer; a second electrochromic layer laid on said second electrode layer; means for holding said first and second substrates spaced from each other and defining a closed space between the two substrates; an electrolyte liquid which occupies said closed space; and reflecting means for providing a reflective surface to said second substrate.
Claim 2
Dependent Claim 187 words
An electrochromic nonglaring mirror, comprising: a transparent first substrate of which the inside surface is laid with a transparent first electrode layer; a first electrochromic layer laid on said first electrode layer and formed of an organic polymer which undergoes electrochemical oxidation and reduction in at least two states and assumes different colors at its respective stages of electrochemical oxidation and becomes pale or colorless in its electrochemically fully reduced state wherein said organic polymer is made up of repeating units represented by the following general formula: ##STR2## wherein X and X' each represent a hydrogen atom, a halogen atom, an alkyl group having not more than 4 carbon atoms or an alkoxyl group having not more than 4 carbon atoms; a second substrate comprising a second electrode layer arranged opposite to said first electrode layer; a second electrochromic layer laid on said second electrode layer; means for holding said first and second substrates spaced from each other and defining a closed space between the two substrates; an electrolyte liquid which occupies said closed space; and reflecting means for providing a reflective surface to said second substrate.
Claim 3
Dependent Claim 27 words
A mirror according to claim 1, wherein said second electrochromic layer is formed of a transition metal oxide which takes on color in its electrochemically reduced state.
Claim 4
Dependent Claim 48 words
A mirror according to claim 2, wherein said transition metal oxide is selected from the group consisting of WO 3 , MoO 3 , Nb 2 O 5 , Cr 2 O 3 , Ta 2 O 5 , TiO 2 , Fe 2 O 3 and AgO.
Claim 5
Dependent Claim 21 words
A mirror according to claim 1, wherein aid electrolyte liquid is a solution of a supporting electrolyte in an organic solvent.
Claim 6
Dependent Claim 27 words
A mirror according to claim 4, further comprising drive means for applying a DC voltage not higher than 0.8 V across said first and second electrode layers.
Claim 7
Dependent Claim 35 words
A mirror according to claim 1, wherein both said second substrate and said second electrode layer are transparent, said reflecting means comprising a reflective metal film coated on the rear surface of said second substrate.
Claim 8
Dependent Claim 27 words
A mirror according to claim 1, wherein said second electrode layer is a reflecting metal layer, whereby said reflecting means is incorporated in said second electrode layer.

References Cited (Backward Citations)

US3844636A Cited
US4205988A Cited
US3990984A Cited
US4285575A Cited
US4465339A Cited
US4613211A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-05-22 1992-11-21 1993-05-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-05-22 1996-11-21 1997-05-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-05-22 2000-11-21 2001-05-23 $7700.00 Window Closed / Lapsed

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