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US4829094A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic microspheres

Assignee: Henkel Corp
•
Filing: 1987-11-25
•
Granted: 1989-05-09
•
Expires: 2007-11-25
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Abstract

Abstract Microsphere wet cake is mixed with a processing aid effective to prevent agglomeration and surface bonding of the microspheres, and thereafter removing water by drying with continuous mixing, optionally also under reduced pressure, i.e. vacuum drying. By the control of the application of heat and balancing temperature and the mixing, and optionally also the reduced pressure, it is possible to also control expansion of the microspheres from substantially none to substantially theoretical limits of expansion. The processing aid in the present invention is any one of a wide diversity of materials which meet the requirements of the intended function, i.e., to prevent the agglomeration of the microspheres during the process. Suitable materials include, by way of example, dry inorganic pigments or filler materials, and the like, and related organic materials.

Inventors

  • 👤 George E. Melber
  • 👤 William A. Oswald
  • 👤 Leon E. Wolinski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 18:06
CPC Classifications
B; B01; B01J; B01J13/00; B01J13/02; B82; B82Y; B82Y30/00; B01J13/20; B01J13/206; C; C08; C08J; C08J3/00; C08J3/12; C08J3/124; C08J9/00; C08J9/32; C01; C01P; C01P2004/00; C01P2004/30; C01P2004/32; C01P2004/34; C01P2004/60; C01P2004/61; C01P2004/62; C01P2004/64; C01P2004/80; C01P2006/00; C01P2006/10; C01P2006/20; C01P2006/32; C01P2006/33; C01P2006/34; C01P2006/60; C01P2006/80; C01P2006/82; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2982; Y10T428/2991; Y10T428/2998

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 39 words
Dry, free-flowing microspheres comprising from about 3 to about 80 weight percent hollow thermoplastic resin microspheres and from about 97 to about 20 weight percent of a processing aid embedded in and adhered to the surface of said microspheres.
Claim 2
Dependent Claim 39 words
Dry, free-flowing microspheres comprising from about 3 to about 80 weight percent hollow thermoplastic resin microspheres and from about 97 to about 20 weight percent of a processing aid embedded in and adhered to the surface of said microspheres.
Claim 3
Dependent Claim 12 words
The dry, free-flowing microspheres of claim 1 wherein said microspheres are unexpanded.
Claim 4
Dependent Claim 12 words
The dry, free-flowing microspheres of claim 1 wherein said microspheres are expanded.
Claim 5
Dependent Claim 19 words
The dry, free-flowing microspheres of claim 1 wherein said processing aid is embedded in the surface of said microspheres.
Claim 6
Dependent Claim 21 words
The dry, free-flowing microspheres of claim 1 wherein said processing aid forms a discontinuous coating on the surface of said microspheres.
Claim 7
Dependent Claim 21 words
The dry, free-flowing microspheres of claim 1 wherein said processing aid forms a continuous coating on the surface of said microspheres.
Claim 8
Dependent Claim 47 words
The dry, free-flowing microspheres of claim 1 wherein said processing aid is a free-flowing particulate or fibrous solid have a melting point above the temperature of the drying process, finely divided enough to be able to effectively blend with and adhere to the surfaces of the microspheres.
Claim 9
Dependent Claim 52 words
The dry, free-flowing microspheres of claim 1 wherein said processing aid is a member selected from the group consisting of talc, calcium carbonate, barium sulfate, alumina, silica, titanium dioxide, zinc oxide, spherical beads, or hollow beads, of ceramics, quartz, or glass, glass fibers, cotton flock, carbon and graphite fibers, and mixtures thereof.

References Cited (Backward Citations)

GB145012A Cited
EP0056219A1 Cited
US4397799A Cited
US4513106A Cited
US4722943A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-05-08 1992-11-07 1993-05-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-05-08 1996-11-07 1997-05-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-05-08 2000-11-07 2001-05-09 $7700.00 Window Closed / Lapsed

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