US4828583A — Coated abrasive binder containing ternary photoin…

Claim 1

Independent Claim 90 words

A coated abrasive having abrasive granules which are supported on and adherently bonded to a carrier by a photocured binder made by photocuring an additionpolymerizable composition comprising: (a) free-radically-polymerizable monomer, and (b) photoinitiator system, soluble in said monomer, comprising photochemically effective amounts of (i) aryliodonium salt, (ii) sensitizing compound capable of absorbing light somewhere within the range of wavelengths between about 300 and about 1000 nanometers and capable of sensitizing 2-methyl-4,6-bis(trichloromethyl)-s-triazine, and (iii) electron donor compound, said donor being different from said sensitizing compound and zero<E ox (donor)≦E ox (p-dimethoxybenzene).

Claim 2

Dependent Claim 90 words

A coated abrasive having abrasive granules which are supported on and adherently bonded to a carrier by a photocured binder made by photocuring an additionpolymerizable composition comprising: (a) free-radically-polymerizable monomer, and (b) photoinitiator system, soluble in said monomer, comprising photochemically effective amounts of (i) aryliodonium salt, (ii) sensitizing compound capable of absorbing light somewhere within the range of wavelengths between about 300 and about 1000 nanometers and capable of sensitizing 2-methyl-4,6-bis(trichloromethyl)-s-triazine, and (iii) electron donor compound, said donor being different from said sensitizing compound and zero<E ox (donor)≦E ox (p-dimethoxybenzene).

Claim 3

Dependent Claim 29 words

A coated abrasive according to claim 1, wherein said abrasive granules are selected from the group consisting of flint, garnet, aluminum oxide, alumina:zirconia, synthetic ceramic, diamond and silicon carbide.

Claim 4

Dependent Claim 60 words

A coated abrasive according to claim 1, wherein said carrier comprises a backing sheet, and said granules are bonded to at least one major surface of said backing sheet by a make coating of a first resinous material and a size coating of a second resinous material, said first and/or said second resinous materials being made by photocuring said binder.

Claim 5

Dependent Claim 19 words

A coated abrasive according to claim 3, wherein said backing sheet comprises paper, resin-impregnated cloth, vulcanized fiber or film.

Claim 6

Dependent Claim 38 words

A coated abrasive according to claim 3, wherein said first resinous binder comprises said addition-polymerizable composition, and said second resinous binder is selected from the group consisting of said addition-polymerizable composition, varnish, epoxy resin, phenolic resin and polyurethane.

Claim 7

Dependent Claim 39 words

A coated abrasive according to claim 3, wherein said first resinous binder is selected from the group consisting of said addition-polymerizable composition, glue, varnish, epoxy resin, phenolic resin and polyurethane, and said second resinous material comprises said addition-polymerizable composition.

Claim 8

Dependent Claim 16 words

A coated abrasive according to claim 1, wherein said carrier comprises a low density open web.

Claim 9

Dependent Claim 14 words

A coated abrasive according to claim 7, wherein said web comprises a nonwoven web.

Claim 10

Dependent Claim 14 words

A coated abrasive according to claim 1, wherein said monomer comprises an acrylated oligomer.

Claim 11

Dependent Claim 20 words

A coated abrasive according to claim 1, wherein said monomer comprises the triacrylate of tris-hydroxyethylisocyanurate and/or the triacrylate of trimethylolpropane.

Claim 12

Dependent Claim 21 words

A coated abrasive according to claim 1, wherein said aryliodonium salt comprises a diphenyliodonium simple salt or diphenyliodonium metal complex salt.

Claim 13

Dependent Claim 19 words

A coated abrasive according to claim 1, wherein said range of wavelengths is about 400 to about 700 nanometers.

Claim 14

Dependent Claim 19 words

A coated abrasive according to claim 1, wherein said range of wavelengths is about 400 to about 600 nanometers.

Claim 15

Dependent Claim 14 words

A coated abrasive according to claim 1, wherein said sensitizing compound comprises a ketone.

Claim 16

Dependent Claim 33 words

A coated abrasive according to claim 14, wherein said sensitizing compound comprises an α-diketone having an extinction coefficient below about 1000 at the wavelength at which said addition-polymerizable composition is irradiated when photopolymerized.

Claim 17

Dependent Claim 23 words

A coated abrasive according to claim 14, wherein said sensitizing compound is selected from the group consisting of camphorquinone, benzil, 2-chlorothioxanthone and fluorenone.

Claim 18

Dependent Claim 95 words

A coated abrasive according to claim 14, wherein said sensitizing compound has the formula: where X is CO or CR 1 R 2 , where R 1 and R 2 can be the same or different, and can be hydrogen, alkyl, alkaryl or aralkyl, b is zero or 1, and A and B can be the same or different and can be substituted or unsubstituted aryl, alkyl, alkaryl or aralkyl groups, or together A and B can form a cyclic structure which can be a substituted or unsubstituted cycloaliphatic, aromatic, heteroaromatic or fused aromatic ring.

Claim 19

Dependent Claim 24 words

A coated abrasive according to claim 1, wherein said E ox (donor) is between about 0.5 and 1 volts vs. a saturated calomel electrode.

Claim 20

Dependent Claim 54 words

A coated abrasive according to claim 1, wherein said donor is selected from the group consisting of amines, amides, ethers, ureas, ferrocene, sulfinic acids and their salts, salts of ferrocyanide, ascorbic acid and its salts, dithiocarbamic acid and its salts, salts of xanthates, salts or ethylene diamine tetraacetic acid and salts of tetraphenylboronic acid.

Claim 21

Dependent Claim 36 words

A coated abrasive according to claim 1, wherein said donor contains a nitrogen, oxygen, phosphorus or sulfur donor atom and an abstractable hydrogen atom bonded to a carbon or silicon atom alpha to said donor atom.

Claim 22

Dependent Claim 18 words

A coated abrasive according to claim 1, wherein said donor comprises a tertiary amine containing an aromatic ring.

Claim 23

Dependent Claim 19 words

A coated abrasive according to claim 21, wherein there is at least one electron-withdrawing group on said aromatic ring.

Claim 24

Dependent Claim 39 words

A coated abrasive according to claim 1, wherein said composition contained, for every 100 parts by weight of said monomer, about 0.005 to about 10 parts by weight each of said aryliodonium salt, said sensitizing compound and said donor.

Claim 25

Dependent Claim 39 words

A coated adhesive according to claim 23, wherein said composition contained, for every 100 parts by weight of said monomer, about 0.1 to about 4 parts by weight each of said aryliodonium salt, said sensitizing compound and said donor.

Claim 26

Dependent Claim 129 words

A coated abrasive having abrasive granules which are supported on and adherently bonded to a carrier by a photocured binder made by photocuring an addition-polymerizable composition comprising: (a) free-radially-polymerizable monomer, and (b) photoinitiator system, soluble in said monomer, comprising 0.1 to 4 parts each of (i) diphenyliodonium metal complex salt, (ii) ketone sensitizing compound capable of absorbing light somewhere within the range of wavelengths between about 400 and about 600 nanometers and capable of sensitizing 2-methyl-4,6-bis(trichloromethyl)-s- triazine, and (iii) electron donor compound containing a nitrogen donor atom and having an abstractable hydrogen atom bonded to a carbon or silicon atom alpha to said nitrogen atom. wherein said donor compound is different from said sensitizing compound and wherein about 0.5 <E ox (donor)≦about 1 volt vs. a saturated calomel electrode.

Claim 27

Dependent Claim 129 words

A coated abrasive having abrasive granules which are supported on and adherently bonded to a carrier by a photocured binder made by photocuring an addition-polymerizable composition comprising: (a) free-radially-polymerizable monomer, and (b) photoinitiator system, soluble in said monomer, comprising 0.1 to 4 parts each of (i) diphenyliodonium metal complex salt, (ii) ketone sensitizing compound capable of absorbing light somewhere within the range of wavelengths between about 400 and about 600 nanometers and capable of sensitizing 2-methyl-4,6-bis(trichloromethyl)-s- triazine, and (iii) electron donor compound containing a nitrogen donor atom and having an abstractable hydrogen atom bonded to a carbon or silicon atom alpha to said nitrogen atom. wherein said donor compound is different from said sensitizing compound and wherein about 0.5 <E ox (donor)≦about 1 volt vs. a saturated calomel electrode.

Claim 28

Independent Claim 104 words

A method for making coated abrasive products comprising the steps of (A) coating a carrier with abrasive granules and a photocurable binder comprising an addition-polymerizable composition comprising: (i) free-radially-polymerizable monomer, and (ii) photoinitiator system, soluble in said monomer, comprising photochemically effective amounts of (a) aryliodonium salt, (b) sensitizing compound capable of absorbing light somewhere within the range of wavelengths between about 300 and about 1000 nanometers and capable of sensitizing 2-methyl-4,6-bis(trichloromethyl)-s-triazine, and (c) electron donor compound, said donor being different from said sensitizing compound and zero <E ox (donor)≦E ox (p-dimethoxybenzene); and (B) photocuring said binder by irradiating it with ultraviolet or visible light.

Claim 29

Independent Claim 104 words

A method for making coated abrasive products comprising the steps of (A) coating a carrier with abrasive granules and a photocurable binder comprising an addition-polymerizable composition comprising: (i) free-radially-polymerizable monomer, and (ii) photoinitiator system, soluble in said monomer, comprising photochemically effective amounts of (a) aryliodonium salt, (b) sensitizing compound capable of absorbing light somewhere within the range of wavelengths between about 300 and about 1000 nanometers and capable of sensitizing 2-methyl-4,6-bis(trichloromethyl)-s-triazine, and (c) electron donor compound, said donor being different from said sensitizing compound and zero <E ox (donor)≦E ox (p-dimethoxybenzene); and (B) photocuring said binder by irradiating it with ultraviolet or visible light.

Claim 30

Dependent Claim 26 words

A method according to claim 26, wherein said sensitizing compound comprises a ketone having an extinction coefficient below about 1000 at the wavelength of said light.

Claim 31

Dependent Claim 128 words

A method according to claim 26, wherein said carrier comprises a backing sheet coated on at least one major surface with a make coat of a first resinous material in liquid form, and between said step (A) and said step (B) are carried out the steps of (A1) depositing a plurality of said abrasive granules uniformly over the surface of said make coat of first resinous material; (A2) curing said first resinous material to bond said granules adherently to said major surface; (S3) coating over said make coat and said granules with a size coat of a second resinous material; wherein at least one of said first or second resinous materials comprises said photocurable binder and is photocured in said step (B) by said ultraviolet or visible light.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1992-05-08	1992-11-07	1993-05-09	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1996-05-08	1996-11-07	1997-05-09	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	2000-05-08	2000-11-07	2001-05-09	$7700.00	Window Closed / Lapsed

Coated abrasive binder containing ternary photoinitiator system

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