US4822850A
Expired / Lapsed
US
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Modified polyorganosiloxane containing isocyanate group and process for preparing the same
Assignee: JNC Corp
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Filing: 1987-12-21
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Granted: 1989-04-18
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Expires: 2007-12-21
Abstract
Abstract There is here provided a modifier for a resin containing an active hydrogen capable of reacting with an isocyanate group. The modifier of the present invention can give characteristics such as low frictional properties, water repellency, oil repellency and antithrombotic properties to the resin, and when the modifier of the present invention is used, neither bleeding phenomenon nor deterioration in mechanical strength takes place. The present modifier comprises a modified polyorganosiloxane containing an isocyanate group which is represented by the general formula (A) ##STR1## wherein Me is a methyl group, Ph is a phenyl group, R is a methyl or phenyl group, R 1 is H or a methyl group, each of m and n is 0 or more and a value of m+n is within the range of 0 to 600, a is 1, 2 or 3, b is 1, 2 or 3, c is a value of 1 to 300, and Q is a residue obtained by subtracting one isocyanate group from a compound having at least two isocyanate groups. A process for preparing the compound having the general formula (A) comprises reacting a compound in which the moiety of --O--CO--NH--Q in the general formula (A) is not introduced yet thereinto, i.e., the moiety is --OH, with another compound having at least 2 isocyanate groups.
Inventors
- 👤 Hirofumi Yashuda
- 👤 Takahiro Saho
- 👤 Nobumasa Ohtake
- 👤 Takaharu Nakano
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 15:48
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/04; C08G77/38; C08G77/382; C08G77/388; C08G18/00; C08G18/06; C08G18/28; C08G18/2805; C08G18/288; C08G18/289
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
105 words
A modified polyorganosiloxane containing an isocyanate group which is represented by the general formula (A) ##STR15## wherein Me is a methyl group, Ph is a phenyl group, R is a methyl or phenyl group, R 1 is H or a methyl group, each of m and n is 0 or more and a value of m+n is within the range of 0 to 600, a is 1, 2 or 3, b is 1, 2 or 3, c is a value of 1 to 300, and Q is a residue having at least one isocyanate group derived from a compound having at least two isocyanate groups.
Claim 2
Dependent Claim
105 words
A modified polyorganosiloxane containing an isocyanate group which is represented by the general formula (A) ##STR15## wherein Me is a methyl group, Ph is a phenyl group, R is a methyl or phenyl group, R 1 is H or a methyl group, each of m and n is 0 or more and a value of m+n is within the range of 0 to 600, a is 1, 2 or 3, b is 1, 2 or 3, c is a value of 1 to 300, and Q is a residue having at least one isocyanate group derived from a compound having at least two isocyanate groups.
Claim 3
Dependent Claim
29 words
A modified polyorganosiloxane containing an isocyanate group according to claim 1 wherein said value of m+n in said general formula (A) is within the range of 10 to 120.
Claim 4
Dependent Claim
23 words
A modified polyorganosiloxane containing an isocyanate group according to claim 1 wherein said value of a in said general formula (A) is 1.
Claim 5
Dependent Claim
36 words
A modified polyorganosiloxane containing an isocyanate group according to claim 1 wherein in said general formula (A), said value of m+n is within the range of 10 to 120, and said value of a is 1.
Claim 6
Dependent Claim
22 words
A modified polyorganosiloxane containing an isocyanate group according to claim 1 wherein the isocyanate group in said general formula (A) is blocked.
Claim 7
Dependent Claim
35 words
A modified polyorganosiloxane containing an isocyanate group according to claim 1 wherein in said general formula (A), said value of m+n is within the range of 10 to 120, and said isocyanate group is blocked.
Claim 8
Dependent Claim
29 words
A modified polyorganosiloxane containing an isocyanate group according to claim 1 wherein in said general formula (A), said value of a is 1, and said isocyanate group is blocked.
Claim 9
Dependent Claim
41 words
A modified polyorganosiloxane containing an isocyanate group according to claim 1 wherein in said general formula (A), said value of m+n is within the range of 10 to 120, said value of a is 1, and said isocyanate group is blocked.
Claim 10
Dependent Claim
164 words
A process for preparing a modified polyorganosiloxane containing an isocyanate group represented by the general formula (A) ##STR16## comprising reacting a polyorganosiloxane having one modified terminal group representing by the general formula (B) ##STR17## with at least one compound having at least two isocyanate groups in a molar ratio of the isocyanate group-containing compound to the polyorganosiloxane of at least 1:1, at a temperature of 50° C. or more in the presence of a solvent, wherein Me is a methyl group, Ph is a phenyl group, R is a methyl or phenyl group, R 1 is H or a methyl group, each of m and n is 0 or more and a value of m+n is within the range of 0 to 600, a is 1, 2 or 3, b is 1, 2 or 3, c is a value of 1 to 300, and Q is a residue having at least one isocyanate group derived from a compound having at least two isocyanate groups.
Claim 11
Dependent Claim
164 words
A process for preparing a modified polyorganosiloxane containing an isocyanate group represented by the general formula (A) ##STR16## comprising reacting a polyorganosiloxane having one modified terminal group representing by the general formula (B) ##STR17## with at least one compound having at least two isocyanate groups in a molar ratio of the isocyanate group-containing compound to the polyorganosiloxane of at least 1:1, at a temperature of 50° C. or more in the presence of a solvent, wherein Me is a methyl group, Ph is a phenyl group, R is a methyl or phenyl group, R 1 is H or a methyl group, each of m and n is 0 or more and a value of m+n is within the range of 0 to 600, a is 1, 2 or 3, b is 1, 2 or 3, c is a value of 1 to 300, and Q is a residue having at least one isocyanate group derived from a compound having at least two isocyanate groups.
Claim 12
Dependent Claim
140 words
A process for preparing a modified polyorganosiloxane containing an isocyanate group according to claim 9 wherein said at least one compound having at least two isocyanate groups is one or more selected from the group consisting of tolylene diisocyanate, diphenylmethane diisocyanate, dianisidine diisocyanate, diphenyl ether diisocyanate, ditolylene diisocyanate, naphthalene diisocyanate, hexamethylene diisocyanate, isophorone diisocyanate, lysine diisocyanate methyl ester, meta-xylene diisocyanate, 2,2,4-trimethylhexamethylene diisocyanate, dimer acid diisocyanate, isopropylidene bis(4-cyclohexyl isocyanate), cyclohexylmethane diisocyanate dimer, triphenylmethane triisocyanate, triisocyanate phenyl thiophosphate, a biuret of a diisocyanate, a cyanurate of a diisocyanate, an adduct of a diisocyanate and trimethylolpropane, an adduct of a diisocyanate and trimethylolethane, a prepolymer having two or more isocyanate residues of said isocyanate group-containing compound and a polyvalent alcohol, and a prepolymer having two or more isocyanate residues of said isocyanate group-containing compound and a compound having two or more amino groups.
Claim 13
Dependent Claim
164 words
A process for preparing a modified polyorganosiloxane containing an isocyanate group according to claim 9 wherein said modified polyorganosiloxane having the general formula (B) is prepared by reacting a compound having the general formula (E) ##STR18## with a lower alcohol or aqueous hydrochloric acid solution in order to eliminate the trimethylsilyl group from the formula (E), said compound having the general formula (E) being prepared by the addition reaction of an H-modified polyorganosiloxane represented by the general formula (C) ##STR19## with a compound represented by the general formula (D) CH.sub.2 =CHCH.sub.2 -[O(CHR.sup.1)(CH).sub.b ].sub.c -OSiMe.sub.3 (D) wherein Me is a methyl group, Ph is a phenyl group, R is a methyl or phenyl group, R 1 is H or a methyl group, each of m and n is 0 or more and a value of m+n is within the range of 0 to 600, a is 1, 2 or 3, b is 1, 2 or 3, and c is a value of 1 to 300.
Claim 14
Dependent Claim
33 words
A process for preparing a modified polyorganosiloxane containing an isocyanate group according to claim 9 wherein said value of m+n in said general formula (A) is within the range of 10 to 120.
Claim 15
Dependent Claim
27 words
A process for preparing a modified polyorganosiloxane containing an isocyanate group according to claim 9 wherein said value of a in said general formula (A) is 1.
Claim 16
Dependent Claim
40 words
A process for preparing a modified polyorganosiloxane containing an isocyanate group according to claim 9 wherein in said general formula (A), said value of m+n is within the range of 10 to 120, and said value of a is 1.
Claim 17
Dependent Claim
26 words
A process for preparing a modified polyorganosiloxane containing an isocyanate group according to claim 9 wherein the isocyanate group in said general formula (A) is blocked.
Claim 18
Dependent Claim
39 words
A process for preparing a modified polyorganosiloxane containing an isocyanate group according to claim 9 wherein in said general formula (A), said value of m+n is within the range of 10 to 120, and said isocyanate group is blocked.
Claim 19
Dependent Claim
33 words
A process for preparing a modified polyorganosiloxane containing an isocyanate group according to claim 9 wherein in said general formula (A), said value of a is 1, and said isocyanate group is blocked.
Claim 20
Dependent Claim
45 words
A process for preparing a modified polyorganosiloxane containing an isocyanate group according to claim 9 wherein in said general formula (A), said value of m+n is within the range of 10 to 120, said value of a is 1, and said isocyanate group is blocked.
References Cited (Backward Citations)
US4387206A
Cited
US4644046A
Cited
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1992-04-17 | 1992-10-17 | 1993-04-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-04-17 | 1996-10-17 | 1997-04-18 | $3760.00 | Window Closed / Lapsed |
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