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US4820601A Expired / Lapsed US ⏱️ 0.0 years remaining

Photoresponsive imaging members with protective copolyurethane overcoatings

Assignee: Xerox Corp
•
Filing: 1988-02-01
•
Granted: 1989-04-11
•
Expires: 2008-02-01
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Abstract

Abstract An imaging member comprised of a photoconductive layer, and a protective copolyurethane overcoating of the formula: ##STR1## wherein A is a trivalent group; A' is a bivalent group; R is selected from the group consisting of alkylene, substituted alkylene, arylene, and substituted arylene; x and y are number mole fractions of from about 0.05 to about 0.95 subsequent to the provision that the sum of x+y is equal to 1.0. Also disclosed are processes for the preparation of the aforementioned copolyurethanes.

Inventors

  • 👤 Beng S. Ong
  • 👤 Dasarao K. Murti
  • 👤 John R. C. Fuller

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 17:45
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/675; C08G18/677; C08G18/678; G; G03; G03G; G03G5/00; G03G5/14; G03G5/147; G03G5/14708; G03G5/14713; G03G5/14747; G03G5/14769; Y; Y10; Y10S; Y10S430/00; Y10S430/001; Y10S430/10

Claims Analysis

Total Claims: 31
Claim 1
Independent Claim 70 words
An imaging member comprised of a photoconductive layer, and a protective copolyurethane coating of the formula: ##STR9## wherein A is a trivalent group; A' is a bivalent group; R is selected from the group consisting of alkylene, substituted alkylene, arylene, and substituted arylene; x and y are number mole fractions of from about 0.05 to about 0.95 subsequent to the provision that the sum of x+y is equal to 1.0.
Claim 2
Dependent Claim 70 words
An imaging member comprised of a photoconductive layer, and a protective copolyurethane coating of the formula: ##STR9## wherein A is a trivalent group; A' is a bivalent group; R is selected from the group consisting of alkylene, substituted alkylene, arylene, and substituted arylene; x and y are number mole fractions of from about 0.05 to about 0.95 subsequent to the provision that the sum of x+y is equal to 1.0.
Claim 3
Dependent Claim 16 words
An imaging member in accordance with claim 1 wherein the photoconductive layer is comprised of selenium.
Claim 4
Dependent Claim 18 words
An imaging member in accordance with claim 1 wherein the photoconductive layer is comprised of a selenium alloy.
Claim 5
Dependent Claim 17 words
An imaging member in accordance with claim 3 wherein the alloy is selenium arsenic, or selenium tellurium.
Claim 6
Dependent Claim 21 words
An imaging member in accordance with claim 1 wherein the trivalent group A contains from 4 to about 20 carbon atoms.
Claim 7
Dependent Claim 13 words
An imaging member in accordance with claim 1 wherein A is 2,2-dimethylene butyl.
Claim 8
Dependent Claim 13 words
An imaging member in accordance with claim 1 wherein A is 2,2-dimethylene propyl.
Claim 9
Dependent Claim 13 words
An imaging member in accordance with claim 1 wherein A is 2,2-dimethylene ethyl.
Claim 10
Dependent Claim 13 words
An imaging member in accordance with claim 1 wherein A is triethylene amine.
Claim 11
Dependent Claim 22 words
An imaging member in accordance with claim 1 wherein R is an arylene group of from 6 to about 24 carbon atoms.
Claim 12
Dependent Claim 22 words
An imaging member in accordance with claim 1 wherein R is a alkylene group of from 1 to about 20 carbon atoms.
Claim 13
Dependent Claim 12 words
An imaging member in accordance with claim 1 wherein R is hexamethylene.
Claim 14
Dependent Claim 12 words
An imaging member in accordance with claim 1 wherein R is phenylene.
Claim 15
Dependent Claim 12 words
An imaging member in accordance with claim 1 wherein R is tolylene.
Claim 16
Dependent Claim 25 words
An imaging member in accordance with claim 1 wherein the bivalent group A' contains heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur.
Claim 17
Dependent Claim 20 words
An imaging member in accordance with claim 1 wherein A' is --CH 2 CH 2 OCH 2 CH 2 --.
Claim 18
Dependent Claim 24 words
An imaging member in accordance with claim 1 wherein A' is --CH 2 CH 2 OCH 2 CH 2 OCH 2 CH 2 --.
Claim 19
Dependent Claim 24 words
An imaging member in accordance with claim 1 wherein A' is --CH 2 CH 2 N(t-C 4 H 9 )CH 2 CH 2 --.
Claim 20
Dependent Claim 20 words
An imaging member in accordance with claim 1 wherein A' is --CH 2 CH 2 SCH 2 CH 2 --.
Claim 21
Dependent Claim 24 words
An imaging member in accordance with claim 1 wherein the bivalent group A' is an alkylene of from 2 to about 20 carbon atoms.
Claim 22
Dependent Claim 28 words
An imaging member in accordance with claim 1 wherein A' is --(CH 2 ) n -- wherein n is a number of from about 2 to about 20.
Claim 23
Dependent Claim 20 words
An imaging member in accordance with claim 1 wherein A' is --CH 2 C(CH 3 ) 2 CH 2 --.
Claim 24
Dependent Claim 20 words
An imaging member in accordance with claim 1 wherein A' is --CH 2 C 6 H 10 CH 2 --.
Claim 25
Dependent Claim 36 words
An imaging member in accordance with claim 1 wherein the copolyurethane is selected from the group consisting of those represented by the formulas of FIGS. 1, 2, 3, 4, 5, 6, 7, 8, 9, and 10.
Claim 26
Dependent Claim 12 words
An imaging member in accordance with claim 1 containing a supporting substrate.
Claim 27
Dependent Claim 37 words
An imaging member comprised of supporting substrate, a photogenerating layer comprised of a photogenerating pigment optionally dispersed in a resinous binder, an aryl amine hole transport layer, and as a protective overcoating the copolyurethanes of claim 1.
Claim 28
Dependent Claim 25 words
An imaging member in accordance with claim 26 wherein the photogenerating pigment is selected from the group consisting of metal phthalocyanines and metal free phthalocyanines.
Claim 29
Dependent Claim 28 words
An imaging member in accordance with claim 26 wherein the hole transporting layer contains molecules of the formula ##STR10## wherein X is an alkyl group, or halogen atom.
Claim 30
Dependent Claim 18 words
An imaging member in accordance with claim 26 wherein the overcoating is the copolyurethanes represented by FIG. 1.
Claim 31
Dependent Claim 18 words
An imaging member in accordance with claim 26 wherein the overcoating is the copolyurethane represented by FIG. 3.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-04-10 1992-10-10 1993-04-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-04-10 1996-10-10 1997-04-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-04-10 2000-10-10 2001-04-11 $7700.00 Window Closed / Lapsed

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