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US4818807A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid-crystalline polymer

Assignee: Idemitsu Kosan Co Ltd
•
Filing: 1987-09-03
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Granted: 1989-04-04
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Expires: 2007-09-03
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Abstract

Abstract A liquid-crystalline polymer comprising repeating units of the following general formula <IMAGE> wherein: R1 is -H, -CH3 or -C2H5, 1 is an integer having a value of 1 to 20, k is an integer having a value of 1 to 30, A is -O- (oxygen) or -COO-, m is 0 or 1, and R2 is <IMAGE> <IMAGE> <IMAGE> +TR <IMAGE> wherein Y is -COO- or -OCO-, and R3 is -COOR4, -OCOR4, -OR4, -COR4 or -R4 where R4 is <IMAGE> R5 being -CH3, -CN or a halogen radical, n and p being independently an integer having a value of 0 to 10 with the proviso that if R5 is -CH3, p is not 0, X being a halogen radical, q being 0 or 1, and C* being an asymmetric carbon atom. The liquid-crystalline polymer not only exhibits liquid-crystalline properties and transfers to ferroelectric chiral smectic C phase at temperatures of a wide range including the vicinity of room temperature but also has a high speed in responding to external factors enabling to display motion pictures, and can be advantageously used as display elements of large size screens and curved screens.

Inventors

  • 👤 Kazuharu Morita
  • 👤 Shunji Uchida
  • 👤 Satoshi Hachiya

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 20:02
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/04; C09K19/38; C09K19/3833; C09K19/3838; C08; C08G; C08G63/00; C08G63/02; C08G63/60

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 149 words
A liquid-crystalline polymer comprising repeating units of the following general formula ##STR126## wherein: R 1 is --H, --CH 3 or --C 2 H 5 , l is an integer having a value of 1 to 20, k is an integer having a value of 1 to 30, A is --O-- (oxygen) or --COO--, m is 0 or 1, and R 2 is ##STR127## wherein Y is --COO-- or --OCO--, and R 3 is --COOR 4 , --OCOR 4 , --OR 4 , --COR 4 or --R 4 where R 4 is ##STR128## R 5 being --CH 3 , --CN or a halogen radical, n and p being independently an integer having a value of 0 to 10 with the proviso that if R 5 is --CH 3 , p is not 0, X being a halogen radical, q being 0 or 1, and C* being an asymmetric carbon atom.
Claim 2
Dependent Claim 149 words
A liquid-crystalline polymer comprising repeating units of the following general formula ##STR126## wherein: R 1 is --H, --CH 3 or --C 2 H 5 , l is an integer having a value of 1 to 20, k is an integer having a value of 1 to 30, A is --O-- (oxygen) or --COO--, m is 0 or 1, and R 2 is ##STR127## wherein Y is --COO-- or --OCO--, and R 3 is --COOR 4 , --OCOR 4 , --OR 4 , --COR 4 or --R 4 where R 4 is ##STR128## R 5 being --CH 3 , --CN or a halogen radical, n and p being independently an integer having a value of 0 to 10 with the proviso that if R 5 is --CH 3 , p is not 0, X being a halogen radical, q being 0 or 1, and C* being an asymmetric carbon atom.
Claim 3
Dependent Claim 21 words
The liquid crystalline polymer of claim 1 wherein R 5 is --CH 3 , --Cl or --CN, and q is 0.
Claim 4
Dependent Claim 39 words
The liquid crystalline polymer of claim 1 wherein R 5 --CH 3 , n is an integer having a value of 0 to 5, q is 1, and p is an integer having a value of 1 to 5.
Claim 5
Dependent Claim 16 words
The liquid-crystalline polymer of claim 1, wherein the number average molecular weight is 3,000 to 200,000.
Claim 6
Dependent Claim 30 words
The liquid-crystalline polymer of claim 1, wherein l is an integer having a value of 1 to 3, and k is an integer having a value of 10 to 12.
Claim 7
Dependent Claim 16 words
The liquid-crystalline polymer of claim 5, wherein A is --O-- (oxygen), and R 2 is ##STR129##
Claim 8
Dependent Claim 11 words
The liquid-crystalline polymer of claim 6, wherein R 4 is ##STR130##
Claim 9
Dependent Claim 11 words
The liquid-crystalline polymer of claim 6, wherein R 4 is ##STR131##
Claim 10
Dependent Claim 11 words
The liquid-crystalline polymer of claim 6, wherein R 4 is ##STR132##
Claim 11
Dependent Claim 11 words
The liquid-crystalline polymer of claim 6, wherein R 4 is ##STR133##
Claim 12
Dependent Claim 11 words
The liquid-crystalline polymer of claim 6, wherein R 4 is ##STR134##
Claim 13
Dependent Claim 11 words
The liquid-crystalline polymer of claim 6, wherein R 4 is ##STR135##
Claim 14
Dependent Claim 10 words
The liquid-crystalline polymer of claim 6, wherein R4 is ##STR136##
Claim 15
Dependent Claim 11 words
The liquid-crystalline polymer of claim 6, wherein R 4 is ##STR137##

References Cited (Backward Citations)

US4338431A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-04-03 1992-10-03 1993-04-04 $2000.00 Window Closed / Lapsed
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