Room-temperature-curable resin composition

Claim 2

A room temperature-curable resin composition consisting essentially of (A) an organic solvent solution of a vinyl polymer containing a basic nitrogen atom and having at least one reactive group selected from the group consisting of amine groups, carboxyl groups, phosphate ester bonds and mixtures thereof and (B) a compound containing both an epoxy group and a hydrolyzable silyl group in each molecule, said vinyl polymer (A) being a polymer obtained by polymerizing (a-1) at least one vinyl monomer containing at least one tertiary amino group with or without (a-2) another copolymerizable monomer, or a polymer obtained by reacting (a-3 a vinyl polymer containing a carboxylic anhydride group with (a-4) a compound containing both at least one group capable of reacting with the carboxylic anhydride group and at least one tertiary amino group in each molecule, said components (A) and (B) being mixed in such proportions that the proportion of the epoxy group in the component (B) is about 0.2 to 5 equivalents per equivalent of said reactive groups in the component (A).

Claim 3

A room temperature-curable resin composition consisting essentially of (A) an organic solvent solution of a vinyl polymer containing a basic nitrogen atom and having at least one reactive group selected from the group consisting of amine groups, carboxyl groups, phosphate ester bonds and mixtures thereof, (B) a compound containing both an epoxy group and a hydrolyzable silyl group in each molecule, and (C) a compound (c-1) containing a silanol group and/or a compound (c-2) containing a hydrolyzable silyl group other than the compound (B), said vinyl polymer being a polymer (A) obtained by polymerizing (a-1) at least one vinyl monomer Containing at least one tertiary amino group, with or without (a-2) another copolymerizable monomer, or a polymer obtained by reacting (a-3) a vinyl polymer containing a carboxylic anhydride group with (a-4) a compound containing both at least one group capable of reacting with the carboxylic anhydride group and at least one tertiary amino group in each molecule, said components (A), (B) and (C) being mixed in such proportions that the proportion of the epoxy group in the component (B) is about 0.2 to 5 equivalents per equivalent of said reactive groups in the component (A), and the weight ratio of component (C) to total solids of component (A) and component (B) is 1 to 1,000:100.

Claim 4

A room temperature-curable resin composition consisting essentially of (A) an organic solvent solution of a vinyl polymer containing a basic nitrogen atom and having at least one reactive group selected from the group consisting of amine groups, carboxyl groups, phosphate ester bonds and mixtures thereof, (B) a compound containing both an epoxy group and a hydrolyzable silyl group in each molecule, and (C) a compound (c-1) containing a silanol group and/or a compound (c-2) containing a hydrolyzable silyl group other than the compound (B), said vinyl polymer being a polymer (A) obtained by polymerizing (a-1) at least one vinyl monomer Containing at least one tertiary amino group, with or without (a-2) another copolymerizable monomer, or a polymer obtained by reacting (a-3) a vinyl polymer containing a carboxylic anhydride group with (a-4) a compound containing both at least one group capable of reacting with the carboxylic anhydride group and at least one tertiary amino group in each molecule, said components (A), (B) and (C) being mixed in such proportions that the proportion of the epoxy group in the component (B) is about 0.2 to 5 equivalents per equivalent of said reactive groups in the component (A), and the weight ratio of component (C) to total solids of component (A) and component (B) is 1 to 1,000:100.

Claim 5

A room temperature-curable resin composition consisting essentially of (A) an organic solvent solution of a vinyl polymer containing a basic nitrogen atom and having at least one reactive group selected from the group consisting of amine groups, carboxyl groups, phosphate ester bonds and mixtures thereof, (B) a compound containing both an epoxy group and a hydrolyzable silyl group in each molecule, (C) a compound (c-1) containing a silanol group and/or a compound (c-2) containing a hydrolyzable silyl group other than the compound (B), and (D) a catalyst for hydrolysis and condensation of the hydrolyzable silyl group, said vinyl polymer (A) being a polymer obtained by polymerizing (a-1) at least one vinyl monomer containing at least one teritiary amino group, with or without (a-2) another copolymerizable monomer, or a polymer obtained by reacting (a-3) a vinyl polymer containing a carboxylic anhydride group with (a-4) a compound containing both at least one group capable of reacting with the carboxylic anhydride group and at least one tertiary amino group in each molecule, said components (A), (B), (C) and (D) being mixed in such proportions that the proportion of the epoxy group in the component (B) is about 0.2 to 5 equivalents per equivalent of said reactive groups in the component (A): the weight ratio of component (C) to total solids of the component (A) and (B) is 1 to 1,000:100; and the content of a component (D) is 0.001 to 10% by weight based on the total amount of the components (A), (B) and (C).

Claim 6

A room temperature-curable resin composition consisting essentially of (A) an organic solvent solution of a vinyl polymer containing a basic nitrogen atom and having at least one reactive group selected from the group consisting of amine groups, carboxyl groups, phosphate ester bonds and mixtures thereof, (B) a compound containing both an epoxy group and a hydrolyzable silyl group in each molecule, (C) a compound (c-1) containing a silanol group and/or a compound (c-2) containing a hydrolyzable silyl group other than the compound (B), and (D) a catalyst for hydrolysis and condensation of the hydrolyzable silyl group, said vinyl polymer (A) being a polymer obtained by polymerizing (a-1) at least one vinyl monomer containing at least one teritiary amino group, with or without (a-2) another copolymerizable monomer, or a polymer obtained by reacting (a-3) a vinyl polymer containing a carboxylic anhydride group with (a-4) a compound containing both at least one group capable of reacting with the carboxylic anhydride group and at least one tertiary amino group in each molecule, said components (A), (B), (C) and (D) being mixed in such proportions that the proportion of the epoxy group in the component (B) is about 0.2 to 5 equivalents per equivalent of said reactive groups in the component (A): the weight ratio of component (C) to total solids of the component (A) and (B) is 1 to 1,000:100; and the content of a component (D) is 0.001 to 10% by weight based on the total amount of the components (A), (B) and (C).

Claim 7

The composition of any one of claims 1 to 3 wherein the vinyl polymer (A) is a polymer obtained by copolymerizing (a-1) at least one vinyl monomer containing at least one tertiary amino group selected from the group consisting of dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, N-dialkylaminoalkylacrylamides and N-dialkylaminoalkyl methacrylamides, with (a-2) another vinyl monomer copolymerizable with the monomer (a-1).

Claim 8

The composition of any one of claims 1 to 3 wherein the vinyl polymer (A) is a polymer containing a tertiary amino group obtained by reacting (a-3) a vinyl polymer containing a carboxylic anhydride group with (a-4) a compound containing both at least one tertiary amino group and at least one group having active hydrogen capable of reacting with the carboxylic anhydride group in each molecule.

Claim 9

The composition of any one of claim 1 to 3 wherein the vinyl polymer (A) is a polymer containing a basic nitrogen atom and a carboxyl group and/or a phosphate ester bond.

Claim 10

The composition of any one of claims 1 to 3 wherein the compound (B) containing both an epoxy group and a hydrolyzable silyl group is a vinyl polymer containing both an epoxy group and a hydrolyzable silyl group at a terminal position of the main polymer chain and/or a side chain.

Claim 11

The composition of any one of claims 1 to 3 wherein the compound (B) containing both an epoxy group and a hydrolyzable silyl group is at least one compound selected from the group consisting of gamma-glycidoxypropyltrialkoxysilane and gamma-glycidoxypropyltriisopropenyloxysilane.

Claim 12

The composition of claim 2 or 3 wherein the compound (C-2) containing a hydrolyzable silyl group other than the compound (B) is at least one compound selected from the group consisting of alkoxysilanes, partial hydrolyzation and condensation products of alkoxysilanes, alkenyloxysilanes, partial hydrolysis and condensation products of alkenyloxysilanes, alkoxysilanemodified resins obtained by reacting compounds containing at least two alkoxysilyl groups per molecule with polyhydric alcohols, vinyl polymers having a hydrolyzable silyl group at a terminal position of the main polymer chain and/or a side chain, alkyd resins containing a hydrolyzable silyl group and polyester resins containing a hydrolyzable silyl group.

Claim 13

The room temperature-curable resin composition of any of claims 1 to 3 wherein the vinyl monomer containing at least one tertiary amino group (a-1) is selected from the group consisting of dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, N-dialkylaminoalkyl acrylamides, N-dialkylaminoalkyl methacrylamides, aziridinylethyl acrylate, aziridinylethyl methacrylate, pyrrolidinylethyl acrylate, pyrrolidinylethyl methacrylate, piperidinylethyl acrylate and piperidinylethyl methacrylate.

Claim 14

The composition of any one of claims 1 to 3 wherein the vinyl polymer (A) is obtained by copolymerizing from 1 to 70% by weight of the tertiary amino group-containing vinyl monomer (a-1) with from 99 to 30% by weight of the copolymerizable vinyl monomer (a-2).

Claim 15

The composition of claim 5 wherein the vinyl polymer containing a carboxylic anhydride group (a-3) is obtained by polymerizing from 0.5 to 50% by weight of a monomer containing an acid anhydride group with from 99.5 to 50% by weight of a monomer free from a hydroxyl group and copolymerizable with the monomer containing the acid anhydride group; and wherein the vinyl polymer (A) is obtained by reacting the vinyl polymer (a-3) and the compound (a-4) in such proportions that the proportion of the active hydrogen-containing group in the compound (a-4) is about 0.5 to 3 equivalents per equivalent of the acid anhydride group of the polymer (a-3).