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US4818250A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing fuel from plant sources and fuel blends containing same

Assignee: LEMCO ENERGY Inc A CORP OF SOUTH CAROLINA
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Filing: 1987-10-21
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Granted: 1989-04-04
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Expires: 2007-10-21
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Abstract

Abstract A plant source fuel is disclosed per se and as a blend constituent for conventional petroleum fuels along with a process for producing same. Limonene obtained from citrus and other plants when distilled and treated to avoid formation of gums is blendable with conventional petroleum fuels up to about 20 volume percent to form blends that meet the standards for such fuels.

Inventors

  • 👤 Robert D. Whitworth

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 21:21
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/04; C10L1/06; C10L1/10; C10L1/14; C10L1/16; C10L1/1616

Claims Analysis

Total Claims: 32
Claim 1
Independent Claim 61 words
A process for producing a fuel from plant sources comprising the steps of: (a) providing a supply of limonene; (b) distilling the limonene and removing the distillate fraction in a temperature range of from about 346° F. to about 382° F.; (c) removing water from the distilled limonene; and (d) treating the distilled limonene to preclude the formation of gums therefrom.
Claim 2
Dependent Claim 61 words
A process for producing a fuel from plant sources comprising the steps of: (a) providing a supply of limonene; (b) distilling the limonene and removing the distillate fraction in a temperature range of from about 346° F. to about 382° F.; (c) removing water from the distilled limonene; and (d) treating the distilled limonene to preclude the formation of gums therefrom.
Claim 3
Dependent Claim 18 words
A process as defined in claim 1 wherein the limone supplied is food grade d-limonene from citrus plants.
Claim 4
Dependent Claim 22 words
A process as defined in claim 1 wherein water is removed from the distilled limonene by passing same through through a dessicant.
Claim 5
Dependent Claim 13 words
A process as defined in claim 3 wherein the dessicant is silica gel.
Claim 6
Dependent Claim 20 words
A process as defined in claim 1 wherein an antioxidant is added to the distilled limonene to inhibit gum formation.
Claim 7
Dependent Claim 26 words
A process as defined in claim 1 wherein the distilled limonene is hydrogenated to convert the limonene to a saturated paraffin whereby gum formation is precluded.
Claim 8
Dependent Claim 74 words
A process for producing a fuel from plant sources comprising the steps of: (a) supplying a quantity of limonene; (b) distilling the limonene and recovering the distillate fraction in a temperature range equivalent to from about 346° F. to about 382° F. based on atmospheric distillation; and (c) treating the distilled limonene to at least reduce the formation of gum therefrom, whereby the fuel generally meets ASTM standards for petroleum fuels when blended therewith.
Claim 9
Dependent Claim 74 words
A process for producing a fuel from plant sources comprising the steps of: (a) supplying a quantity of limonene; (b) distilling the limonene and recovering the distillate fraction in a temperature range equivalent to from about 346° F. to about 382° F. based on atmospheric distillation; and (c) treating the distilled limonene to at least reduce the formation of gum therefrom, whereby the fuel generally meets ASTM standards for petroleum fuels when blended therewith.
Claim 10
Dependent Claim 22 words
A process as defined in claim 7 wherein further the distilled limonene is subjected to a drying agent to remove water therefrom.
Claim 11
Dependent Claim 15 words
A process as defined in claim 7 wherein the limonene is distilled at atmospheric pressure.
Claim 12
Dependent Claim 21 words
A process as defined in claim 7 wherein the distilled limonene is hydrogenated to convert the limonene to a saturated paraffin.
Claim 13
Dependent Claim 20 words
A process as defined in claim 7 wherein an antioxidant is added to the distilled limonene to inhibit gum formation.
Claim 14
Dependent Claim 13 words
A process as defined in claim 11 where the antioxidant is a phenylenediamene.
Claim 15
Dependent Claim 16 words
A process as defined in claim 12 wherein the phenylenediamene is N, N' disecondary butyl paraphenylenediamene
Claim 16
Dependent Claim 14 words
A process as defined in claim 8 wherein the drying agent is silica gel.
Claim 17
Dependent Claim 54 words
An improved plant source fuel comprising a distilled limonene, said limonene having a purity of at least about 95 volume percent, a water level of no greater than about 0.1 weight percent, an octane number of less than about 90 and being characterized by the absence of available olefinic bonds for formation of gums.
Claim 18
Dependent Claim 54 words
An improved plant source fuel comprising a distilled limonene, said limonene having a purity of at least about 95 volume percent, a water level of no greater than about 0.1 weight percent, an octane number of less than about 90 and being characterized by the absence of available olefinic bonds for formation of gums.
Claim 19
Dependent Claim 20 words
An improved plant source fuel as defined in claim 15 wherein an antioxidant is present to inhibit formation of gums.
Claim 20
Dependent Claim 15 words
An improved plant source fuel as defined in claim 15 wherein the limonene is hydrogenated.
Claim 21
Dependent Claim 19 words
An improved plant source fuel as defined in claim 15 wherein the water content is about 0.01 weight percent.
Claim 22
Dependent Claim 61 words
An improved fuel blend comprising: (a) a conventional petroleum fuel; and (b) up to about 20 volume percent of a distilled limonene, said limonene having a purity of at least about 95 volume percent and being characterized by the absence of available olefinic bonds for formation of gums; said blend having a vapor pressure less than that of the petroleum fuel.
Claim 23
Dependent Claim 61 words
An improved fuel blend comprising: (a) a conventional petroleum fuel; and (b) up to about 20 volume percent of a distilled limonene, said limonene having a purity of at least about 95 volume percent and being characterized by the absence of available olefinic bonds for formation of gums; said blend having a vapor pressure less than that of the petroleum fuel.
Claim 24
Dependent Claim 21 words
A fuel blend as defined in claim 19 wherein the limonene is present in an amount of about 10 volume percent.
Claim 25
Dependent Claim 13 words
A fuel blend as defined in claim 19 wherein the limonene is hydrogenated.
Claim 26
Dependent Claim 14 words
A fuel blend as defined in claim 19 wherein the limonene contains an antioxidant.
Claim 27
Dependent Claim 23 words
A fuel blend as defined in claim 19 wherein the limonene has a water content of no greater than about 0.1 weight percent.
Claim 28
Dependent Claim 17 words
A fuel blend as defined in claim 23 wherein the water content is about 0.01 weight percent.
Claim 29
Dependent Claim 17 words
An improved fuel blend as defined in claim 19 wherein the petroleum fuel is an unleaded gasoline.
Claim 30
Dependent Claim 17 words
An improved fuel blend as defined in claim 19 wherein the petroleum fuel is a diesel fuel.
Claim 31
Dependent Claim 17 words
An improved fuel blend as defined in claim 19 wherein the petroleum fuel is an aviation fuel.
Claim 32
Dependent Claim 17 words
An improved fuel blend as defined in claim 19 wherein the petroleum fuel is a jet fuel.

References Cited (Backward Citations)

JPS5896689A Cited
US4617025A Cited
US4533487A Cited
US4620855A Cited
US4623363A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-04-03 1992-10-03 1993-04-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-04-03 1996-10-03 1997-04-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-04-03 2000-10-03 2001-04-04 $7700.00 Window Closed / Lapsed

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