US4812543A
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Co-polymer-bound amine antioxidants
Assignee: Metton America Inc
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Filing: 1988-03-01
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Granted: 1989-03-14
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Expires: 2008-03-01
Abstract
Abstract A novel metathesis catalyst polymerizable composition is provided which comprises at least one ring-opening metathesis catalyst polymerizable norbornene-type monomer and at least one ring-opening metathesis catalyst polymerizable amine antioxidant comonomer.
Inventors
- 👤 Albert S. Matlack
- 👤 Martin J. Paisner
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 18:12
CPC Classifications
C; C09; C09K; C09K15/00; C09K15/04; C09K15/16; C09K15/18; C08; C08G; C08G61/00; C08G61/02; C08G61/04; C08G61/06; C08G61/08
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
189 words
A ring-opening metathesis catalyst polymerizable composition comprising: (a) at least one ring-opening metathesis catalyst polymerizable norbornene-type monomer, and (b) at least one ring-opening metathesis catalyst polymerizable amine antioxidant comonomer having the general formula: ##STR16## in which R represents hydrogen or a haloalkyl, and where X represents a direct bond or a multivalent organic radical selected from a straight-chain or branched C 1 to C 20 -alkyl, C 2 to C 20 -alkenyl, C 7 to C 20 -aralkyl, C 7 to C 20 -aralkenyl group, or --OR'--, ##STR17## --NH 2 --, --R'--NH--, --Ph--R'--NH--, --Ph--R'--O--, --SO 2 --, --SO 2 --R'--O--, --SO 2 R'NH--, groups in which R' represents a straight chain or branched C 1 to C 20 -alkyl, C 2 to C 20 -alkenyl, C 7 to C 20 -aralkyl, or C 7 to C 20 -aralkenyl group, and where q is a positive integer or zero, and t is a positive integer from 1 to 2, wherein the amount of amine antioxidant comonomer from part (b) ranges from about 0.005 parts by weight to about 20 parts by weight per 100 parts polymerizable monomer from part (a).
Claim 2
Dependent Claim
189 words
A ring-opening metathesis catalyst polymerizable composition comprising: (a) at least one ring-opening metathesis catalyst polymerizable norbornene-type monomer, and (b) at least one ring-opening metathesis catalyst polymerizable amine antioxidant comonomer having the general formula: ##STR16## in which R represents hydrogen or a haloalkyl, and where X represents a direct bond or a multivalent organic radical selected from a straight-chain or branched C 1 to C 20 -alkyl, C 2 to C 20 -alkenyl, C 7 to C 20 -aralkyl, C 7 to C 20 -aralkenyl group, or --OR'--, ##STR17## --NH 2 --, --R'--NH--, --Ph--R'--NH--, --Ph--R'--O--, --SO 2 --, --SO 2 --R'--O--, --SO 2 R'NH--, groups in which R' represents a straight chain or branched C 1 to C 20 -alkyl, C 2 to C 20 -alkenyl, C 7 to C 20 -aralkyl, or C 7 to C 20 -aralkenyl group, and where q is a positive integer or zero, and t is a positive integer from 1 to 2, wherein the amount of amine antioxidant comonomer from part (b) ranges from about 0.005 parts by weight to about 20 parts by weight per 100 parts polymerizable monomer from part (a).
Claim 3
Dependent Claim
67 words
The composition as claimed in claim 1 wherein the monomer in part (a) is selected from dicyclopentadiene, trimers and higher oligomers of dicyclopentadiene, norbornene, norbornadiene, and unsubstituted and substituted alkyl derivatives of tetracyclododecene and tetracyclododecadiene, and the amine antioxidant comonomer in part (b) is selected from N-(norborn-5-en-2-ylmethyl)-N'-phenyl 1,4-phenylethylenediamine, 4-(norborn-5-en-2-ylmethoxy)diphenylamine, 4-(3-chloromethyl-norborn-5-en-2-ylmethoxy)diphenylamine, 4-anilinophenyl norborn-5-en-2-carboxylate, 4-(9-(norborn-5-en-2-yl)nonyloxy)-diphenylamine, 11-(4-anilinophenoxy)undecyl norborn-5-en-2-carboxylate, 4-anilinophenoxy-ethyl norborn-5-en-2-yl sulfone, 4-anilinophenyl 4-(5-norborn-2-yl)benzyl ether, 4-(4-anilino)anilino)phenyl norborn-5-en-2-carboxylate, and 4-((4-anilino)anilino)phenyl norborn-5-en-2-ylmethyl ether.
Claim 4
Dependent Claim
171 words
A polymeric composition of matter comprising a reaction product obtained by ring-opening metathesis catalyst polymerization of a norbornene-type monomer and from about 0.005 parts by weight to about 20 parts by weight per 100 parts norbornene-type monomer of an amine antioxidant comonomer having the general formula: ##STR18## in which R represents hydrogen or a haloalkyl, and where X represents a direct bond or a multivalent organic radical selected from a straight-chain or branched C 1 to C 20 -alkyl, C 2 to C 20 -alkenyl, C 7 to C 20 -aralkyl, C 7 to C 20 -aralkenyl group or --OR'--, ##STR19## --NH 2 --, --R'--NH--, --Ph--R'--NH--, --Ph--R'--O--, --SO 2 --, --SO 2 --R'--O--, --SO 2 R'NH--, groups in which R' represents a straight chain or branched C 1 to C 20 -alkyl, C 2 to C 20 -alkenyl, C 7 to C 20 -aralkyl, or C 7 to C 20 -aralkenyl group, and where q is a positive integer or zero, and t is a positive integer from 1 to 2.
Claim 5
Dependent Claim
171 words
A polymeric composition of matter comprising a reaction product obtained by ring-opening metathesis catalyst polymerization of a norbornene-type monomer and from about 0.005 parts by weight to about 20 parts by weight per 100 parts norbornene-type monomer of an amine antioxidant comonomer having the general formula: ##STR18## in which R represents hydrogen or a haloalkyl, and where X represents a direct bond or a multivalent organic radical selected from a straight-chain or branched C 1 to C 20 -alkyl, C 2 to C 20 -alkenyl, C 7 to C 20 -aralkyl, C 7 to C 20 -aralkenyl group or --OR'--, ##STR19## --NH 2 --, --R'--NH--, --Ph--R'--NH--, --Ph--R'--O--, --SO 2 --, --SO 2 --R'--O--, --SO 2 R'NH--, groups in which R' represents a straight chain or branched C 1 to C 20 -alkyl, C 2 to C 20 -alkenyl, C 7 to C 20 -aralkyl, or C 7 to C 20 -aralkenyl group, and where q is a positive integer or zero, and t is a positive integer from 1 to 2.
Claim 6
Dependent Claim
137 words
A ring-opening metathesis catalyst polymerizable amine antioxidant comonomer having the general formula: ##STR20## in which R represents hydrogen or a haloalkyl, and where X represents a direct bond or a multivalent organic radical selected from a straight-chain or branched C 1 to C 20 -alkyl, C 2 to C 20 -alkenyl, C 7 to C 20 -aralkyl, C 7 to C 20 -aralkenyl group or --OR'--, ##STR21## --NH 2 --, --R'--NH--, --Ph--R'--NH--, --Ph--R'--O--, --SO 2 --, --SO 2 --R'--O--, --SO 2 R'NH--, groups in which R' represents a straight chain or branched C 1 to C 20 -alkyl, C 2 to C 20 -alkenyl, C 7 to C 20 -aralkyl, or C 7 to C 20 -aralkenyl group, and where q is a positive integer or zero, and t is a positive integer from 1 to 2.
Claim 7
Dependent Claim
137 words
A ring-opening metathesis catalyst polymerizable amine antioxidant comonomer having the general formula: ##STR20## in which R represents hydrogen or a haloalkyl, and where X represents a direct bond or a multivalent organic radical selected from a straight-chain or branched C 1 to C 20 -alkyl, C 2 to C 20 -alkenyl, C 7 to C 20 -aralkyl, C 7 to C 20 -aralkenyl group or --OR'--, ##STR21## --NH 2 --, --R'--NH--, --Ph--R'--NH--, --Ph--R'--O--, --SO 2 --, --SO 2 --R'--O--, --SO 2 R'NH--, groups in which R' represents a straight chain or branched C 1 to C 20 -alkyl, C 2 to C 20 -alkenyl, C 7 to C 20 -aralkyl, or C 7 to C 20 -aralkenyl group, and where q is a positive integer or zero, and t is a positive integer from 1 to 2.
References Cited (Backward Citations)
No citation records indexed.
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