US4808295A
Expired / Lapsed
US
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Two stage process for the production of a high benzene aromatic product
Assignee: Mobil Oil AS
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Filing: 1987-12-16
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Granted: 1989-02-28
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Expires: 2007-12-16
Abstract
Abstract A process is provided for converting a feedstock comprising a preponderant amount of C2-C10 aliphatic compounds to a product having a high proportion of benzene in a two stage process, with the effluent from the first stage passing directly to the second stage, i.e., with no intermediate processing such as purification or separation. In the first stage, the feedstock is contacted under suitable conversion conditions with a catalyst comprising an aluminosilicate zeolite having a Constraint Index in the approximate range of 1 to 12 and a degree of acidity indicated by an alpha value of at least about 3. The effluent from the first stage is then passed directly to a second stage where it is contacted under conversion conditions with a catalyst comprising platinum and a zeolite which either has a Constraint Index of approximately 1 to 12 or is a potassium zeolite L in which the number of protonic acid sites have been reduced by exchange with barium, strontium or calcium, the second stage zeolite being substantially non- or low-acid as indicated by an alpha value no higher than about 1.
Inventors
- 👤 Margaret Nemet-Mavrodin
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 05:52
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/40; B01J29/42; B01J29/44; B01J29/405; C; C07; C07C; C07C2/00; B01J2229/00; B01J2229/10; B01J2229/26; B01J2229/30; B01J2229/42; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/40; C07C2529/65; C07C2529/70; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/52
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
170 words
A process for producing aromatic compounds containing a high proportion of benzene which comprises passing a feed containing at least 50 weight percent of C 2 to C 10 aliphatic hydrocarbons to a first stage reaction zone where it is contacted under conversion conditions with a catalyst comprising an aluminosilicate zeolite characterized by a Constraint Index within the approximate range of 1 to 12 and a degree of acidity indicated by an alpha value of at least 3, and passing the effluent from the first stage reaction zone directly to a second stage reaction zone where it is contacted under conversion conditions with a catalyst comprising platinum and either a zeolite having a Constraint Index in the approximate range of 1 to 12, or a potassium form of zeolite L in which the number of protonic acid sites have been reduced by exchange with barium, strontium or calcium, said second stage catalyst having a low degree of acidity as indicated by an alpha value of no higher than about 1.
Claim 2
Dependent Claim
170 words
A process for producing aromatic compounds containing a high proportion of benzene which comprises passing a feed containing at least 50 weight percent of C 2 to C 10 aliphatic hydrocarbons to a first stage reaction zone where it is contacted under conversion conditions with a catalyst comprising an aluminosilicate zeolite characterized by a Constraint Index within the approximate range of 1 to 12 and a degree of acidity indicated by an alpha value of at least 3, and passing the effluent from the first stage reaction zone directly to a second stage reaction zone where it is contacted under conversion conditions with a catalyst comprising platinum and either a zeolite having a Constraint Index in the approximate range of 1 to 12, or a potassium form of zeolite L in which the number of protonic acid sites have been reduced by exchange with barium, strontium or calcium, said second stage catalyst having a low degree of acidity as indicated by an alpha value of no higher than about 1.
Claim 3
Dependent Claim
16 words
The process of claim 1 wherein the zeolite of said first stage catalyst is a ZSM-5.
Claim 4
Dependent Claim
19 words
The process of claim 2 wherein said ZSM-5 has an as synthesized silica/alumina ratio of about 25 to 1000.
Claim 5
Dependent Claim
27 words
The process of claim 3 wherein said ZSM-5 has gallium loaded therein in an amount of about 0.5 to 5% based on the weight of the catalyst.
Claim 6
Dependent Claim
21 words
The process of claim 4 wherein said gallium loaded ZSM-5 is calcined at a temperature of at least about 700° C.
Claim 7
Dependent Claim
29 words
The process of claim 5 wherein said calcining is carried out at a temperature of about 800° to 825° C. for a period of about 1 to 1.5 hours.
Claim 8
Dependent Claim
51 words
The process of claim 1 wherein said second stage catalyst comprises a zeolite having a Constraint Index in the approximate range of about 1 to 12, and an as synthesized silica/alumina ratio of at least about 25, and about 0.1 to 1.0% of platinum, based on the weight of the catalyst.
Claim 9
Dependent Claim
47 words
The process of claim 1 wherein said second stage catalyst comprises a potassium form of zeolite L in which the number of protonic acid sites has been reduced by exchange with barium ions, and about 0.1 to 1.0% of platinum based on the weight of the catalyst.
Claim 10
Dependent Claim
83 words
The process of claim 1 wherein the conversion conditions of said first stage reaction zone include a temperature of from about 450° C. to about 700° C., a pressure of from about one atmosphere to about 1000 psig, and a EHSV of from about 0.1 to about 50, and the conversion conditions of said second stage reaction zone include a temperature of about 450° to 595° C., a pressure of about one to 30 atmospheres, and a WHSV of about 1 to 50.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-02-28 | 1992-08-29 | 1993-02-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-02-28 | 1996-08-29 | 1997-02-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-02-28 | 2000-08-29 | 2001-02-28 | $7700.00 | Window Closed / Lapsed |