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US4803254A Expired / Lapsed US ⏱️ 0.0 years remaining

Vinylsilylalkoxy arylbenzotriazole compounds and UV absorbing compositions made therefrom

Assignee: Iolab Corp
•
Filing: 1987-03-11
•
Granted: 1989-02-07
•
Expires: 2007-03-11
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Abstract

Abstract Vinylsilylalkoxy arylbenzotriazol monomers such as 2-[3'-t-butyl-5'-(3-"-dimethylvinylsilylpropoxy)-2'-hydroxy-phenyl]-5-methoxybenzotriazole are disclosed. These monomers can be incorporated in optically clear silicone polymers to form intraocular lenses, contact lenses, and the like, which have UV absorbing properties.

Inventors

  • 👤 Gary B. Dunks
  • 👤 Akira Yamada
  • 👤 Namassivaya Doddi
  • 👤 Charles D. Beard

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 11:03
CPC Classifications
C; C07; C07D; C07D249/00; C07D249/02; C07D249/04; C07D249/06; C08; C08G; C08G77/00; C08G77/04; C08G77/38; C08G77/382; C08G77/388; A; A61; A61F; A61F2/00; A61F2/02; A61F2/14; A61F2/16; A61L; A61L27/00; A61L27/14; A61L27/18; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/0803; C07F7/081; C07F7/0812; G; G02; G02B; G02B1/00; G02B1/04; G02B1/041; G02B1/043; A61F2002/16965

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 91 words
A vinylsilylalkoxy arylbenzotriazole compound of the formula: ##STR4## wherein R 1 and R 3 individually represent hydrogen, halo, alkoxy of up to 6 carbon atoms, or X, wherein R 2 represents hydrogen or alkyl of up to six carbon atoms, and wherein X represents a group of the formula: --O--R'Si(R").sub.2 CH═CH.sub.2 wherein R' represents alkylene of from 1 to 10 carbon atoms, and wherein each R" individually represents alkyl of up to 4 carbon atoms or aryl, provided that one, and only one, of R 1 or R 3 represents X.
Claim 2
Dependent Claim 91 words
A vinylsilylalkoxy arylbenzotriazole compound of the formula: ##STR4## wherein R 1 and R 3 individually represent hydrogen, halo, alkoxy of up to 6 carbon atoms, or X, wherein R 2 represents hydrogen or alkyl of up to six carbon atoms, and wherein X represents a group of the formula: --O--R'Si(R").sub.2 CH═CH.sub.2 wherein R' represents alkylene of from 1 to 10 carbon atoms, and wherein each R" individually represents alkyl of up to 4 carbon atoms or aryl, provided that one, and only one, of R 1 or R 3 represents X.
Claim 3
Dependent Claim 10 words
The compound of claim 1 wherein said compound is 2-[3'-t-butyl-5'-(3"-dimethylvinylsilylpropoxy)-2'-hydroxyphenyl]-5-methoxybenzotriazole.
Claim 4
Dependent Claim 10 words
The compound of claim 1 wherein siad compound is 2-[3'-t-butyl-5'-(3"-dimethylvinylsilylpropoxy)-2'-hydroxyphenyl]-5-chlorobenzotriazole.
Claim 5
Dependent Claim 10 words
The compound of claim 1 wherein said compound is 2-(3'-t-butyl-2'-hydroxy-5'-methoxyphenyl)-5-(3"-dimethylvinylsilylpropoxy)benzotriazole.
Claim 6
Dependent Claim 21 words
An optically clear siloxane polymer having ultraviolet light absorbing properties, said polymer having covalently bonded therein the compound of claim 1.
Claim 7
Dependent Claim 21 words
An optically clear siloxane polymer having ultraviolet light absorbing properties, said polymer having covalently bonded therein the compound of claim 2.
Claim 8
Dependent Claim 21 words
An optically clear siloxane polymer having ultraviolet light absorbing properties, said polymer having covalently bonded therein the compound of claim 3.
Claim 9
Dependent Claim 21 words
An optically clear siloxane polymer having ultraviolet light absorbing properties, said polymer having covalently bonded therein the compound of claim 4.
Claim 10
Dependent Claim 14 words
The optically clear polymer of claim 5 in the form of an intraocular lens.
Claim 11
Dependent Claim 14 words
The optically clear polymer of claim 6 in the form of an intraocular lens.
Claim 12
Dependent Claim 14 words
The optically clear polymer of claim 7 in the form of an intraocular lens.
Claim 13
Dependent Claim 14 words
The optically clear polymer of claim 8 in the form of an intraocular lens.

References Cited (Backward Citations)

US4528311A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-02-07 1992-08-08 1993-02-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-02-07 1996-08-08 1997-02-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-02-07 2000-08-08 2001-02-07 $7700.00 Window Closed / Lapsed

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