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US4803243A
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Block-graft copolymer
Assignee: Shin-Etsu Chemical Co Ltd
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Filing: 1987-03-25
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Granted: 1989-02-07
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Expires: 2007-03-25
Abstract
Abstract Disclosed are a block-graft copolymer comprising a polymer block having a repeating unit represented by General Formula (I): ##STR1## wherein A is a side chain and represents an organopolisiloxane chain, a polyacrylate chain, a polymethacrylate chain, polydiene chain, etc. and a process for producing the same. This block-graft copolymer can have various performances such as oxygen enrichment performance, biocompatibility, depending on the kind of side chains.
Inventors
- 👤 Teruo Fujimoto
- 👤 Mikio Shiono
- 👤 Osamu Watanabe
- 👤 Koichi Ito
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 20:53
CPC Classifications
C; C08; C08F; C08F297/00; C08F297/02; C08G; C08G77/00; C08G77/42; C08G77/442; C08G81/00; C08G81/02; C08G81/024
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
265 words
A block-graft copolymer comprising: a polymer block having a repeating unit represented by General Formula (I): ##STR13## wherein R 1 represents a hydrogen atom, methyl group or ethyl group; R 2 and R 3 may be the same or different and each represent an alkyl group having 1 to 3 carbon atoms or phenyl group; m represents an integer of 0 to 4; and A represents any one of polymer residual groups represented by General Formulas (II) to (IV) shown below, ##STR14## wherein R 4 may be the same or different and each represent methyl group, ethyl group or phenyl group; R 5 is as defined for R 4 or represents a group represented by the formula --Si(R 4 ) 3 ; and n is an integer of 1 to 1,000, ##STR15## wherein R 6 represents a hydrogen atom or methyl group; and B represents a group represented by the formula --COOR 2 , where R 2 is as defined above, ##STR16## --CH═CH 2 or --C(CH 3 )═CH 2 ; Y represents cumyl group, n-butyl group, s-butyl group or benzophenone residual group; and n is as defined above, ##STR17## wherein Y represents cumyl group, n-butyl group or s-butyl group, and n is as defined above, and at least one of polymer blocks having a repeating unit represented by General Formula (V): ##STR18## wherein R 7 represents a hydrogen atom, methyl group or ethyl group; M represents at least one selected from a group represented by the formula --CH═CH 2 , --C(CH 3 )═CH 2 , --COOCH 3 or --COOC 2 H 5 and phenyl group.
Claim 2
Dependent Claim
265 words
A block-graft copolymer comprising: a polymer block having a repeating unit represented by General Formula (I): ##STR13## wherein R 1 represents a hydrogen atom, methyl group or ethyl group; R 2 and R 3 may be the same or different and each represent an alkyl group having 1 to 3 carbon atoms or phenyl group; m represents an integer of 0 to 4; and A represents any one of polymer residual groups represented by General Formulas (II) to (IV) shown below, ##STR14## wherein R 4 may be the same or different and each represent methyl group, ethyl group or phenyl group; R 5 is as defined for R 4 or represents a group represented by the formula --Si(R 4 ) 3 ; and n is an integer of 1 to 1,000, ##STR15## wherein R 6 represents a hydrogen atom or methyl group; and B represents a group represented by the formula --COOR 2 , where R 2 is as defined above, ##STR16## --CH═CH 2 or --C(CH 3 )═CH 2 ; Y represents cumyl group, n-butyl group, s-butyl group or benzophenone residual group; and n is as defined above, ##STR17## wherein Y represents cumyl group, n-butyl group or s-butyl group, and n is as defined above, and at least one of polymer blocks having a repeating unit represented by General Formula (V): ##STR18## wherein R 7 represents a hydrogen atom, methyl group or ethyl group; M represents at least one selected from a group represented by the formula --CH═CH 2 , --C(CH 3 )═CH 2 , --COOCH 3 or --COOC 2 H 5 and phenyl group.
Claim 3
Dependent Claim
29 words
A block-graft copolymer as claimed in claim 1, wherein the polymer block having a repeating unit represented by General Formula I has a polymerization degree of at least 10.
Claim 4
Dependent Claim
29 words
A block-graft copolymer as claimed in claim 1, wherein the polymer block having a repeating unit represented by General Formula V has a polymerization degree of at least 300.
Claim 5
Dependent Claim
29 words
A block-graft copolymer as claimed in claim 2, wherein the polymer block having a repeating unit represented by General Formula V has a polymerization degree of at least 300.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-02-07 | 1992-08-08 | 1993-02-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-02-07 | 1996-08-08 | 1997-02-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-02-07 | 2000-08-08 | 2001-02-07 | $7700.00 | Window Closed / Lapsed |