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US4796671A Expired / Lapsed US ⏱️ 0.0 years remaining

Protective tube for thermocouple and method of producing same

Assignee: Proterial Ltd
•
Filing: 1987-03-17
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Granted: 1989-01-10
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Expires: 2007-03-17
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Abstract

Abstract A protective tube for a thermocouple for measuring the temperature of molten metal, comprising two layers, an inner layer being made of a silicon nitride or sialon ceramic having a bending strength of 50 kg/mm 2 or more, a density of 90% or more based on a theoretical density and a thermal shock temperature ΔT of 400° C. or more, and an outer layer being formed on the silicon nitride or sialon ceramic and containing BN and SiO 2 . The silicon nitride of sialon ceramic comprises 70 weight % or more of Si 3 N 4 having 65 weight % or more of an α-phase content, 20 weight % or less of one or more oxides of elements of Group IIIa of the Periodic Table, 20 weight % or less of Al 2 O 3 , and optionally 15 weight % or less of AlN or AlN solid solution, and the outer layer is composed mainly of BN-SiO 2 -Al 2 O 3 -Y 2 O 3 . This protective tube is produced by coating ceramic powder comprising BN and SiO 2 before sintering. This protective tube can enjoy an extremely long life.

Inventors

  • 👤 Kiyoshi Furushima
  • 👤 Kazunori Haratoh
  • 👤 Hideshige Matsuo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 11:44
CPC Classifications
C; C04; C04B; C04B41/00; C04B41/009; C04B35/00; C04B35/515; C04B35/58; C04B35/584; C04B35/597; C04B41/45; C04B41/50; C04B41/5053; C04B41/5062; C04B41/80; C04B41/81; C04B41/85; C04B41/87; G; G01; G01K; G01K1/00; G01K1/08; G01K1/10; G01K1/105; C04B2111/00; C04B2111/00474; C04B2111/0087; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/131; Y10T428/1317

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 90 words
A protective tube for a thermocouple for measuring the temperature of molten metal, comprising two layers, an inner layer being made of a material selected from the group consisting of silicon nitride and sialon ceramic, said inner layer having a bending strength of 50 kg/mm 2 or more, a density of 90% or more based on a theoretical density and a thermal shock temperature ΔT of 400° C. or more, and protective means including an outer layer being formed on said inner layer and containing BN and SiO 2 .
Claim 2
Dependent Claim 90 words
A protective tube for a thermocouple for measuring the temperature of molten metal, comprising two layers, an inner layer being made of a material selected from the group consisting of silicon nitride and sialon ceramic, said inner layer having a bending strength of 50 kg/mm 2 or more, a density of 90% or more based on a theoretical density and a thermal shock temperature ΔT of 400° C. or more, and protective means including an outer layer being formed on said inner layer and containing BN and SiO 2 .
Claim 3
Dependent Claim 66 words
The protective tube for a thermocouple according to claim 1, wherein said inner layer comprises 70 weight % or more of Si 3 N 4 having 65 weight % or more of an a-phase content, 20 weight % or less of one or more oxides of elements of Group IIIa of the Periodic Table, and 20 weight % or less of Al 2 O 3 .
Claim 4
Dependent Claim 29 words
The protective tube for a thermocouple according to claim 2, wherein said outer layer is composed mainly of BN-SiO 2 -Al 2 O 3 -Y 2 O 3 .
Claim 5
Dependent Claim 27 words
The protective tube for a thermocouple according to claim 2, wherein said inner layer further comprises 15 weight % or less of AlN or its solid solution.
Claim 6
Dependent Claim 29 words
The protective tube for a thermocouple according to claim 4, wherein said outer layer is composed mainly of BN-SiO 2 -Al 2 O 3 -Y 2 O 3 .
Claim 7
Dependent Claim 19 words
The protective tube for a thermocouple according to claim 1, wherein said outer layer is about 5-50 μm thick.

References Cited (Backward Citations)

US4430518A Cited
DE3148993A1 Cited
US4568516A Cited
US4558018A Cited
US4547470A Cited
US4699890A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-01-10 1992-07-11 1993-01-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-01-10 1996-07-11 1997-01-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-01-10 2000-07-11 2001-01-10 $7700.00 Window Closed / Lapsed

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