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US4795847A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of 2,6-dialkyl-naphthalenes

Assignee: Rain Carbon Germany GmbH
•
Filing: 1988-02-02
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Granted: 1989-01-03
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Expires: 2008-02-02
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Abstract

Abstract A process for the preparation of 2,6-dialkyl-naphthalenes comprising selectively alkylating naphthalene or 2-alkyl-naphthalene with alkylating agent in the presence of a zeolite catalyst at 250° to 345° C. which dialkyl-naphthalenes are useful for the preparation of naphthalene 2,6-dicarboxylic acid used to produce high-quality polyesters or polyamides.

Inventors

  • 👤 Jens Weitkamp
  • 👤 Marita Neuber
  • 👤 Wilhelm Holtmann
  • 👤 Gerd Collin
  • 👤 Hans Spengler

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 09:31
CPC Classifications
C; C07; C07C; C07C2/00; C07C2/54; C07C2/64; C07C2/66; B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/40; C07C2/86; C07C2/862; C07C2/864; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/40

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 37 words
A process for the preparation of 2,6-dialkyl-naphthalenes comprising selectively alkylating naphthalene or 2-alkyl-naphthalene with a lower alcohol, dialkyl ether or alkyl halide as alkylating agent in the presence of a zeolite catalyst at 300° to 320° C.
Claim 2
Dependent Claim 37 words
A process for the preparation of 2,6-dialkyl-naphthalenes comprising selectively alkylating naphthalene or 2-alkyl-naphthalene with a lower alcohol, dialkyl ether or alkyl halide as alkylating agent in the presence of a zeolite catalyst at 300° to 320° C.
Claim 3
Dependent Claim 13 words
The process of claim 1 wherein the alkylating agent is a methylating agent.
Claim 4
Dependent Claim 9 words
The process of claim 2 wherein 2-methyl-naphthalene is reacted.
Claim 5
Dependent Claim 11 words
The process of claim 1 wherein mixtures of methyl-naphthalenes are reacted.
Claim 6
Dependent Claim 16 words
The process of claim 1 wherein the zeolite has a spaciousness index of 1 to 12.
Claim 7
Dependent Claim 11 words
The process of claim 2 wherein the catalyst is ZSM-5 zeolite.
Claim 8
Dependent Claim 17 words
The method of claim 1 wherein the crystalline size of the zeolite is 0.01 to 20 μm.
Claim 9
Dependent Claim 17 words
The method of claim 1 wherein the crystalline size of the zeolite is 0.05 to 5 μm.

References Cited (Backward Citations)

US3525775A Cited
EP0012514A1 Cited
US4375573A Cited
US4482774A Cited
US4508836A Cited
EP0202752A1 Cited
JPH1036232A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-01-03 1992-07-04 1993-01-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-01-03 1996-07-04 1997-01-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-01-03 2000-07-04 2001-01-03 $7700.00 Window Closed / Lapsed

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