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US4792576A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of polyurethane moldings by the reaction injection molding process

Assignee: Bayer Corp
•
Filing: 1987-07-23
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Granted: 1988-12-20
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Expires: 2007-07-23
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Abstract

Abstract The present invention is directed to a process for the production of polyurethane moldings by reacting a reaction mixture comprising (a) an organic polyisocyanate (b) a compatible polyol blend comprising (i) at least one polyether polyol having an hydroxyl functionality of from 2 to 8, and a molecular weight of from 350 to below 1800, and (ii) at least one hydroxyl functional organic material containing from 2 to 8 hydroxyl groups and having a molecular weight below 350, components (i) and (ii) being used in a weight ratio of component (b)(i) to (b)(ii) of from about 10:1 to about 1:10, and (iii) no more than 45% by weight based on the weight of component (b) of an active hydrogen containing compound having a molecular weight of 1800 or more, said reaction mixture being processed as a one-shot system by the RIM process at an isocyanate index of from about 70 to about 130.

Inventors

  • 👤 Neil H. Nodelman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 09:20
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/65; C08G18/66; C08G18/6666; C08G18/30; C08G18/38; C08G18/3819; C08G18/3823; C08G18/667; C08G18/6674; C08G2120/00; C08G2130/00; Y; Y10; Y10S; Y10S264/00; Y10S264/83

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 149 words
A process for the production of polyurethane moldings by reacting a reaction mixture comprising (a) an organic polyisocyanate (b) a compatible polyol blend comprising (i) at least one polyether polyol having an hydroxyl functionality of from 2 to 8, and a molecular weight of from 350 to below 1800, and (ii) at least one hydroxyl functional organic material containing from 2 to 8 hydroxyl groups and having a molecular weight below 350, components (i) and (ii) being used in a weight ratio of component (b) (i) to (b) (ii) of from about 10:1 to about 1:10, and (iii) no more than 45% by weight based on the weight of component (b) of an active hydrogen containing compound having a molecular weight of 1800 or more, said reaction mixture being processed as a one-shot system by the RIM process at an isocyanate index of from about 70 to about 130.
Claim 2
Dependent Claim 149 words
A process for the production of polyurethane moldings by reacting a reaction mixture comprising (a) an organic polyisocyanate (b) a compatible polyol blend comprising (i) at least one polyether polyol having an hydroxyl functionality of from 2 to 8, and a molecular weight of from 350 to below 1800, and (ii) at least one hydroxyl functional organic material containing from 2 to 8 hydroxyl groups and having a molecular weight below 350, components (i) and (ii) being used in a weight ratio of component (b) (i) to (b) (ii) of from about 10:1 to about 1:10, and (iii) no more than 45% by weight based on the weight of component (b) of an active hydrogen containing compound having a molecular weight of 1800 or more, said reaction mixture being processed as a one-shot system by the RIM process at an isocyanate index of from about 70 to about 130.
Claim 3
Dependent Claim 24 words
The process of claim 1 wherein said organic polyisocyanate is selected from the group consisting of 4,4'-diisocyanatodiphenylmethane, polyisocyanates based on 4,4'-diisocyanatodiphenylmethane, or mixtures thereof.
Claim 4
Dependent Claim 26 words
The process of claim 1, further comprising the step of placing a reinforcing fiber mat in the mold cavity prior to introduction of the reaction mixture.
Claim 5
Dependent Claim 50 words
The process of claim 3, wherein component (a) is a polyphenylpolymethylene polyisocyanate obtained by the phosgenation of an aniline/formaldehyde condensate, said polyisocyanate having a viscosity at 25° C. of 200 mPa.s or less, and wherein the viscosity of said compatible polyol blend is 200 mPa.s or less at 25° C.
Claim 6
Dependent Claim 13 words
The process of claim 1 wherein said reaction mixture contains a blowing agent.
Claim 7
Dependent Claim 26 words
The process of claim 1 wherein component (b)(i) has a hydroxy functionality of from 2 to 4 and a molecular weight of from 350 to 1100.
Claim 8
Dependent Claim 15 words
The process of claim 6 wherein said organic material contains 2 or 3 hydroxyl groups.
Claim 9
Dependent Claim 20 words
The process of claim 1 wherein component (b)(iii) is present in an amount of no more than 15% by weight.
Claim 10
Dependent Claim 10 words
The process of claim 8 wherein component (b)(iii) is excluded.
Claim 11
Dependent Claim 13 words
The process of claim 1 wherein said reaction mixture contains a release agent.
Claim 12
Dependent Claim 11 words
A polyurethane molding made according to the process of claim 1.

References Cited (Backward Citations)

US3726952A Cited
US4065410A Cited
US4218543A Cited
US4341875A Cited
US4269945A Cited
US4435349A Cited
US4442235A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-12-20 1992-06-20 1992-12-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-12-20 1996-06-20 1996-12-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-12-20 2000-06-20 2000-12-20 $7700.00 Window Closed / Lapsed

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