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US4789712A Expired / Lapsed US ⏱️ 0.0 years remaining

Stable dispersions of polymers in polyepoxides

Assignee: Dow Chemical Co
•
Filing: 1987-08-10
•
Granted: 1988-12-06
•
Expires: 2007-08-10
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Abstract

Abstract Dispersions of polymers and optional dispersion stabilizers in a polyepoxide resin continuous phase is characterized in that the dispersion remains stable above 60° C. The compositions are curable and are useful as coatings, in preparing laminates and reinforced plastics, and as adhesives. The compositions exhibit properties which are superior to compositions containing reactive liquid polymers.

Inventors

  • 👤 Dwight K. Hoffman
  • 👤 Charles B. Arends

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 18:23
CPC Classifications
C; C08; C08F; C08F299/00; C08F299/02; C08F299/026; C08F283/00; C08F283/10; Y; Y10; Y10S; Y10S525/00; Y10S525/922

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 82 words
A process for preparing a stable polymer-in-polyepoxide dispersion wherein a small amount of an unsaturated compound having an oxirane-reactive functionality is reacted with an excess of a polyepoxide at a temperature above the softening point of the polyepoxide to form a blend of polyepoxide and a dispersion stabilizer-precursor having free oxirane groups, adding ethylenically unsaturated monomer thereto which is then polymerized at a temperature above the softening point of the polyepoxide without curing said oxirane groups to form a stable polymer-in-polyepoxide dispersion.
Claim 2
Dependent Claim 82 words
A process for preparing a stable polymer-in-polyepoxide dispersion wherein a small amount of an unsaturated compound having an oxirane-reactive functionality is reacted with an excess of a polyepoxide at a temperature above the softening point of the polyepoxide to form a blend of polyepoxide and a dispersion stabilizer-precursor having free oxirane groups, adding ethylenically unsaturated monomer thereto which is then polymerized at a temperature above the softening point of the polyepoxide without curing said oxirane groups to form a stable polymer-in-polyepoxide dispersion.
Claim 3
Dependent Claim 12 words
The method of claim 1 wherein said polyepoxide is a liquid polyepoxide.
Claim 4
Dependent Claim 14 words
The method of claim 1 wherein said ethylenically unsaturated monomer is an alkyl acrylate.
Claim 5
Dependent Claim 12 words
The method of claim 3 wherein said alkyl acrylate is 2-ethylically acrylate.
Claim 6
Dependent Claim 21 words
The method of claim 1 wherein the dispersion stabilizer-precursor is the reaction product of an unsaturated carboxylic acid and a polyepoxide.
Claim 7
Dependent Claim 20 words
The method of claim 1 wherein the dispersion stabilizer-precursor is the reaction product of an unsaturated isocyanate and a polyepoxide.
Claim 8
Dependent Claim 21 words
The method of claim 1 wherein the dipersion stabilizer-precursor is the reaction product of an alkenyl substituted phenol and a polyepoxide.
Claim 9
Dependent Claim 15 words
The method of claim 1 wherein additional polyepoxide is added with the ethylenically unsautrated monomer.

References Cited (Backward Citations)

US4098841A Cited
GB1073906A Cited
JPS49106586A Cited
US4221697A Cited
JPS5518401A Cited
US4221892A Cited
US4482671A Cited
US4443568A Cited
US4444923A Cited
WO1985000610A1 Cited
US4524181A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-12-06 1992-06-06 1992-12-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-12-06 1996-06-06 1996-12-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-12-06 2000-06-06 2000-12-06 $7700.00 Window Closed / Lapsed

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