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US4789596A Expired / Lapsed US ⏱️ 0.0 years remaining

Dopant coated bead-like silicon particles

Assignee: Albemarle Corp
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Filing: 1987-11-27
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Granted: 1988-12-06
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Expires: 2007-11-27
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Abstract

Abstract Particles of silicon and a p or n carrier substance which are in spherical or spheroidal form, and suitable for use in the preparation of doped semiconductor devices, can be prepared by a fluidized bed technique for chemical vapor deposition of a carrier substance (B, P, As or Sb). The prepared products have a kernel of high purity polysilicon and a layer of silicon/dopant alloy upon the kernel. Optionally, the particles have a thin outer layer of silicon.

Inventors

  • 👤 Robert H. Allen
  • 👤 Jameel Ibrahim

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 22:39
CPC Classifications
C; C01; C01B; C01B33/00; C01B33/02; C23; C23C; C23C16/00; C23C16/22; C23C16/24; B; B01; B01J; B01J2/00; B01J2/003; B01J2/16; C23C16/44; C23C16/442; C30; C30B; C30B29/00; C30B29/02; C30B29/06; Y; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12181; Y10T428/12493; Y10T428/12674; Y10T428/29; Y10T428/2982; Y10T428/2991; Y10T428/2993

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 37 words
A silicon composition in bead or bead-like particulate form characterized by having (i) a center portion of high purity silicon and (ii) a layer on said center portion, said layer having a p or n carrier substance.
Claim 2
Dependent Claim 37 words
A silicon composition in bead or bead-like particulate form characterized by having (i) a center portion of high purity silicon and (ii) a layer on said center portion, said layer having a p or n carrier substance.
Claim 3
Dependent Claim 28 words
The composition of claim 1 wherein said layer is an alloy of silicon in predominantly major proportion with a minor amount of said p or n carrier substance.
Claim 4
Dependent Claim 40 words
The composition of claim 1 being further characterized in that the beads or bead-like particles of said composition are relatively uniform in size and substantially free of planar surfaces and surface boundaries of the type obtained by comminuting larger particles.
Claim 5
Dependent Claim 85 words
A dopant alloy composition in free flowing particulate form consisting essentially of spherical or substantially spherical particles of a narrow size distribution and characterized by: (a) being comprised of, (b) an inner nucleus of essentially pure silicon, and (c) a relatively thin layer around said nucleus, and composed of high purity silicon alloyed with a p or n carrier type element selected from B, P, As, or Sb, said dopant alloy being suitable for batch or continuous Czochralski processes for preparing doped, single crystalline silicon.
Claim 6
Dependent Claim 85 words
A dopant alloy composition in free flowing particulate form consisting essentially of spherical or substantially spherical particles of a narrow size distribution and characterized by: (a) being comprised of, (b) an inner nucleus of essentially pure silicon, and (c) a relatively thin layer around said nucleus, and composed of high purity silicon alloyed with a p or n carrier type element selected from B, P, As, or Sb, said dopant alloy being suitable for batch or continuous Czochralski processes for preparing doped, single crystalline silicon.
Claim 7
Dependent Claim 87 words
A silicon composition in bead or bead-like form and characterized by having (i) a center portion of high purity silicon encapsulated within (ii) a relatively thin layer of an alloy of silicon with a p or n carrier element, and (iii) an outer coat of essentially pure silicon, said outer coat being substantially thinner than said thin layer of silicon alloy, said composition being further characterized by being suitable for use as a dopant alloy for batch or continuous Czochralski processes for preparing doped, single crystalline silicon.
Claim 8
Dependent Claim 87 words
A silicon composition in bead or bead-like form and characterized by having (i) a center portion of high purity silicon encapsulated within (ii) a relatively thin layer of an alloy of silicon with a p or n carrier element, and (iii) an outer coat of essentially pure silicon, said outer coat being substantially thinner than said thin layer of silicon alloy, said composition being further characterized by being suitable for use as a dopant alloy for batch or continuous Czochralski processes for preparing doped, single crystalline silicon.
Claim 9
Dependent Claim 34 words
The silicon composition of claim 5 composed of bead or bead-like particles having a size range of from about 100 to about 2000 microns and a size distribution range of less than 150 microns.
Claim 10
Dependent Claim 23 words
The silicon composition of claim 5 wherein said thin layer of an alloy of silicon is from 50 to about 100 microns thick.
Claim 11
Dependent Claim 20 words
The silicon composition of claim 7 wherein said silicon outer coat is from about 1 to about 10 microns thick.
Claim 12
Dependent Claim 24 words
The silicon composition of claim 8 wherein the composition of said carrier element in said particle is from about 10 to about 3000 ppma.
Claim 13
Dependent Claim 12 words
A silicon composition of claim 9 wherein said carrier element is boron.
Claim 14
Dependent Claim 12 words
A silicon composition of claim 9, wherein said carrier element is phosphorus.

References Cited (Backward Citations)

US3012861A Cited
US3480474A Cited
GB1140656A Cited
FR94593E Cited
US3708728A Cited
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US4249988A Cited
FR2479276A1 Cited
DD153705A1 Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-12-06 1992-06-06 1992-12-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-12-06 1996-06-06 1996-12-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-12-06 2000-06-06 2000-12-06 $7700.00 Window Closed / Lapsed

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