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US4789508A Expired / Lapsed US ⏱️ 0.0 years remaining

Mixtures comprising a nematic liquid crystal and a non-mesomorphic compound

Assignee: Commissariat à l'Énergie Atomique et Aux Énergies Alternatives
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Filing: 1986-09-24
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Granted: 1988-12-06
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Expires: 2006-09-24
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Abstract

Abstract The invention relates to a mixture comprising a nematic liquid crystal and a non-mesomorphous compound. The non-mesomorphous compound makes it possible to improve the elastic behavior of the nematic liquid crystal by increasing the value of the ratio K33/K11, in which K33 represents the elastic bending constant and K11 the elastic fanning constant of the liquid crystal. The non-mesomorphous compound can be in accordance with the formula: <IMAGE> (I) in which R1 and R2, which can be the same or different, represent a hydrogen atom or an alkyl radical having 1 to 12 carbon atoms and n is an integer between 2 and 16 and can be associated with liquid crystals or liquid crystal mixtures containing a 1-(alkylcyclohexyl)-2-(alkylfluorobiphenylyl)-ethane. These mixtures can be used as a liquid crystal in a display device.

Inventors

  • 👤 Francoise Vinet
  • 👤 Claude Vauchier

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 11:15
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/52; C09K19/54; C09K19/02; C09K19/0216; C09K19/04; C09K19/06; C09K19/08; C09K19/30; C09K19/3001; C09K19/3066; C09K19/3068

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 127 words
A mixture having the properties of a nematic liquid crystal comprising at least one nematic liquid crystal with negative dielectric anisotropy and at least one non-mesomorphic compound able to improve the elastic behaviour of the nematic liquid crystal by increasing the value of the ratio K 33 /K 11 , in which K 33 represents the elastic bending constant and K 11 the elastic fanning constant of the liquid crystal, said non-mesomorphic compound being of formula: ##STR35## in which R 1 and R 2 , which can be the same or different, represent a hydrogen atom or an alkyl radical having 1 to 12 carbon atoms and n is an integer between 2 and 16, said non-mesomorphic compound comprising 0.5 to 10% by weight of the mixture.
Claim 2
Dependent Claim 127 words
A mixture having the properties of a nematic liquid crystal comprising at least one nematic liquid crystal with negative dielectric anisotropy and at least one non-mesomorphic compound able to improve the elastic behaviour of the nematic liquid crystal by increasing the value of the ratio K 33 /K 11 , in which K 33 represents the elastic bending constant and K 11 the elastic fanning constant of the liquid crystal, said non-mesomorphic compound being of formula: ##STR35## in which R 1 and R 2 , which can be the same or different, represent a hydrogen atom or an alkyl radical having 1 to 12 carbon atoms and n is an integer between 2 and 16, said non-mesomorphic compound comprising 0.5 to 10% by weight of the mixture.
Claim 3
Dependent Claim 16 words
A mixture according to claim 1, wherein the non-mesomorphous compound is in accordance with formula: ##STR36##
Claim 4
Dependent Claim 45 words
A mixture according to claim 1, wherein said at least one nematic liquid crystal is a 1-(alkylcyclohexyl)-2-(alkylfluorobiphenylyl)-ethane of formula: ##STR37## in which R 3 and R 4 , which can be the same or different and are alkyl radicals with 1 to 7 carbon atoms.
Claim 5
Dependent Claim 16 words
A mixture according to claim 2, wherein the nematic liquid crystal is 1-(trans-4-n-ethylcyclohexyl)-2-2'-fluoro-4'-(2-ethyl)-4-biphenylyl-ethane of formula: ##STR38##
Claim 6
Dependent Claim 232 words
A mixture according to claim 1, including a mixture of said liquid crystals comprising at least one 1-(alkylcyclohexyl)-2-(alkylfluorobiphenylyl)-ethane of formula: ##STR39## in which R 3 and R 4 , which can be the same or different, are alkyl radicals with 1 to 7 carbon atoms, and at least one compound selected from the group consisting of: (a) the alkyl fluorophenyl alkyl bicyclooctane carboxylates of formula: ##STR40## in which R 5 and R 6 , which can be the same or different, are alkyl radicals with 1 to 7 carbon atoms, (b) biphenylbicyclohexyl dialkyl of formula: ##STR41## in which R 7 and R 8 are alkyl radicals with 1 to 7 carbon atoms, (c) the dicyanoalkoxyphenyl alkylcyclohexyl carboxylates of formula: ##STR42## in which R 9 and R 10 , which can be the same or different, are alkyl radicals with 1 to 7 carbon atoms, and (d) alkyl alkylene or dialkyl bicyclohexylcarbonitrile of formula: ##STR43## in which R 11 and R 12 , which can be the same or different, are alkyl or alkylene radicals with 1 to 7 carbon atoms; said mixture comprising: 60to 90% by weight in all of 1-(alkylcyclohexyl)-2-(alkylfluorobiphenylyl)-ethane, 0 to 15% in all of the alkylfluorophenyl alkyl bicyclooctane carboxylates, 0 to 12% in all of biphenylbicyclohexyl dialkyl, 0 to 12% in all of dicyanoalkoxyphenyl alkyl cyclohexyl carboxylates, and 0 to 40% in all of alkyl alkylene or dialkyl bicyclohexylcarbonitrile.
Claim 7
Dependent Claim 24 words
A liquid crystal display device using the electrically controlled birefringence effect, wherein the screen of said device comprises a mixture according to claim 1.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-12-06 1992-06-06 1992-12-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-12-06 1996-06-06 1996-12-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-12-06 2000-06-06 2000-12-06 $7700.00 Window Closed / Lapsed

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