US4788227A
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Contact lens formed from a hydrogel fundamental material
Assignee: Tomei Sangyo KK
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Filing: 1987-03-18
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Granted: 1988-11-29
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Expires: 2007-03-18
Abstract
Abstract An optically transparent hydrogen forming material comprising a copolymer of an optically transparent polyester having a molecular weight of 1,000 to 100,000 and at least one of polymerizable group in its molecule and N-vinyllactam. The hydrogel forming material has an excellent optical property, high gas-permeability and excellent mechanical property.
Inventors
- 👤 Yasukichi Yanagihara
- 👤 Takuo Kato
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 09:54
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/52; C08G63/56; C08G63/58; C08F; C08F299/00; C08F299/02; C08F299/026; C08F299/04; C08F299/0478; G; G02; G02B; G02B1/00; G02B1/04; G02B1/041; G02B1/043
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
53 words
A contact lens prepared from a hydrogel forming material comprising a copolymer a (A) an optically transparent polyester having a number average molecular weight of 1,000 to 100,000 obtained by reacting an epoxy compound and a cyclic acid anhydride and having at least one polymerizable group in the molecule and (B) an N-vinyllactam.
Claim 2
Dependent Claim
53 words
A contact lens prepared from a hydrogel forming material comprising a copolymer a (A) an optically transparent polyester having a number average molecular weight of 1,000 to 100,000 obtained by reacting an epoxy compound and a cyclic acid anhydride and having at least one polymerizable group in the molecule and (B) an N-vinyllactam.
Claim 3
Dependent Claim
397 words
A contact lens according to claim 1, wherein said polyester is formed by polymerizing (1) 30 to 95 mole percent, based on total epoxy compounds, of an epoxy compound selected from the group consisting of cyclohexene oxide represented by the formula (I): ##STR19## styrene oxide represented by the formula (II): ##STR20## an epoxy compound represented by the formula (III): ##STR21## wherein R 1 is hydrogen atom or an alkyl group having 1 to 6 carbon atoms; and an epoxy compound represented by the formula (IV): ##STR22## wherein R 2 is an alkyl group having 1 to 6 carbon atoms or a phenyl group; (2) 5 to 50 mole percent of an epoxy compound selected from the group consisting of an epoxy compound represented by the formula (V): ##STR23## wherein R 3 is a member selected from the group consisting of vinyl group, allyl group, acryloyl group, methacryloyl group, a group having the formula (1): CH.sub.2 ═CH--OC.sub.2 H.sub.4).sub.n ( 1) wherein n is an integer of 2 to 50, a group having the formula (2): CH.sub.2 ═CH--OC.sub.3 H.sub.6).sub.m ( 2) wherein m is an integer of 2 to 50 and a group having the formula (3): CH.sub.2 ═CHOC.sub.l H.sub.2l -- (3) wherein l is an integer of 1 to 50, and an epoxy compound represented by the formula (VI): ##STR24## wherein k is 0 or an integer of 1 to 50; and (3) 0 to 30 mole percent of an epoxy compound selected from the group consisting of an epoxy compound represented by the formula (VII): ##STR25## wherein R 4 is an alkyl group having 7 to 20 carbon atoms and an epoxy compound represented by the formula (VIII): ##STR26## wherein R 5 is a member selected from the group consisting of an alkyl group having 7 to 20 carbon atoms, a group having the formula (4): R.sup.6 --OC.sub.2 H.sub.4).sub.a ( 4) wherein R 6 is a member selected from the group consisting of an alkyl group having 1 to 20 of carbon atoms and a phenyl group and a is an integer of 5 to 50 and a group having the formula (5) R.sup.7 --OC.sub.3 H.sub.6).sub.b ( 5) wherein R 7 is a member selected from the group consisting of an alkyl group having 1 to 20 carbon atoms and a phenyl group and b is an integer of 5 to 50; with a cyclic acid anhydride.
Claim 4
Dependent Claim
20 words
A contact lens according to claim 1, wherein said polyester has a number average molecular weight of 4,000 to 40,000.
Claim 5
Dependent Claim
14 words
A contact lens according to claim 1, wherein said polyester is a grafted polyester.
Claim 6
Dependent Claim
21 words
A contact lens according to claim 1, wherein said cyclic acid anhydride is phthalic anhydride, tetrahydrophthalic anhydride or the derivative thereof.
Claim 7
Dependent Claim
16 words
A contact lens according to claim 1, wherein said N-vinyllactam is N-vinylpyrrolidone, N-vinyl piperidone or N-vinylcaprolactam.
Claim 8
Dependent Claim
129 words
A contact lens according to claim 1, wherein said epoxy compound comprises a member selected from the group consisting of an epoxy compound represented by the formula (V): ##STR27## wherein R 3 is a member selected from the group consisting of vinyl group, allyl group, acryloyl group, methacryloyl group, a group having the formula (1): CH.sub.2 ═CH--OC.sub.2 H.sub.4).sub.n ( 1) wherein n is an integer of 2 to 50, a group having the formula (2): CH.sub.2 ═CH--CO.sub.3 H.sub.6).sub.m ( 2) wherein m is an integer of 2 to 50 and a group having the formula (3): CH.sub.2 ═CHOC.sub.l H.sub.2l -- (3) wherein is an integer 1 to 50, and an epoxy compound represented by the formula (VI): ##STR28## wherein k is 0 or an integer of 1 to 50.
Claim 9
Dependent Claim
87 words
A contact lens according to claim 6, wherein said epoxy compound further comprises a member selected from the group consisting of cyclohexene oxide represented by the formula (I): ##STR29## styrene oxide represented by the formula (II): ##STR30## an epoxy compound represented by the formula (III): ##STR31## wherein R 1 is hydrogen atom or alkyl group having 1 to 6 carbon atoms; and an epoxy compound represented by the formula (IV): ##STR32## wherein R 2 is an alkyl group having 1 to 6 carbon atoms or phenyl group.
Claim 10
Dependent Claim
166 words
A contact lens according to claim 6, wherein said epoxy compound further comprises a member selected from the group consisting of an epoxy compound represented by the formula (VII): ##STR33## wherein R 4 is an alkyl group having 7 to 20 carbon atoms and an epoxy compound represented by the formula (VIII): ##STR34## wherein R 5 is a member selected from the vgroup consisting of an alkyl group having 7 to 20 carbon atoms, a group having the formula (4): R.sup.6 --OC.sub.2 H.sub.4).sub.a ( 4) wherein R 6 is a member selected from the group consisting of an alkyl group having 1 to 20 of carbon atoms and a phenyl group and a is an integer of 5 to 50 and a group having the formula (5): R.sup.7 --OC.sub.3 H.sub.6).sub.b ( 5) wherein R 7 is a member selected from the group consisting of an alkyl group having 1 to 20 carbon atoms and a phenyl group and b is an integer of 5 to 50.
Claim 11
Dependent Claim
166 words
A contact lens according to claim 5, wherein said epoxy compound further comprising an epoxy compound selected from the group consisting of an epoxy compound represented by the formula (VII): ##STR35## wherein R 4 is an alkyl group having 7 to 20 carbon atoms and an epoxy compound represented by the formula (VIII): ##STR36## wherein R 5 is a member selected from the group consisting of an alkyl group having 7 to 20 carbon atoms, a group having the formula (4): R.sup.6 --OC.sub.2 H.sub.4).sub.a ( 4) wherein R 6 is a member selected from the group consisting of an alkyl group having 1 to 20 carbon atoms and a phenyl group and a is an integer of 5 to 50 and a group having the formula (5): R.sup.7 --OC.sub.3 H.sub.6).sub.b ( 5) wherein R 7 is a member selected from the group consisting of an alkyl group having 1 to 20 carbon atoms and a phenyl group and b is an integer of 5 to 50.
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GB1511563A
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US4002700A
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GB2055860A
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US4450262A
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JPS59219319A
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1991-11-29 | 1992-05-30 | 1992-11-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-11-29 | 1996-05-30 | 1996-11-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-11-29 | 2000-05-30 | 2000-11-29 | $7700.00 | Window Closed / Lapsed |